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Floating fiber-free flame-retardant PC/ABS composite material

A composite material, no floating fiber technology, applied in the field of flame retardant materials, can solve the problems of notch sensitivity, poor processing fluidity, poor dimensional stability, etc., and achieve the effects of improving flow performance, improving flame retardant performance, and light weight

Active Publication Date: 2021-03-12
广东中成特殊材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polycarbonate (PC) is a kind of thermoplastic engineering plastic with excellent comprehensive performance, which has the characteristics of outstanding impact resistance, excellent mechanical properties and flame retardancy , but there are also the following disadvantages: high melt viscosity, poor processing fluidity, and sensitivity to notches, poor dimensional stability, and poor solvent resistance
[0008]However, in the above schemes, a large amount of flame retardants and various additives are added, the compatibility between the flame retardants and the matrix is ​​not good, and the dispersion is not uniform. Moreover, the addition of various additives will inevitably affect the flow properties of composite materials.
[0009] Moreover, glass fibers are often added to PC / ABS composite materials, which can greatly improve its mechanical strength, dimensional stability and long-term service temperature while reducing costs. At the same time, it greatly reduces its sensitivity to notch, thereby expanding its scope of application, and can replace wood and metal in many fields. However, due to the uneven dispersion of glass fibers, and in the process of plastic melt flow, glass fibers and resins The fluidity is different, and the mass density is also different, so that the two have a tendency to separate. The glass fiber with low density floats to the surface, and the resin with high density sinks into the inside, thus forming the phenomenon of glass fiber exposure, which limits its appearance. use of software

Method used

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  • Floating fiber-free flame-retardant PC/ABS composite material
  • Floating fiber-free flame-retardant PC/ABS composite material
  • Floating fiber-free flame-retardant PC/ABS composite material

Examples

Experimental program
Comparison scheme
Effect test

preparation example 1

[0046] Weigh octacarboxyphenylsilsesquioxane (POSS) (T 8 COOH), dissolved in dichloromethane with PCL-1000, T 8 The mass ratio of COOH to PCL-1000 is 1:5, add the catalyst stannous octoate, stir evenly, raise the temperature to 200°C, react for 1 hour, remove the solvent, and dry in a vacuum oven at 45°C for 12 hours to obtain POSS graft PCL-1000, denoted as POSS-PCL 1000 ,spare.

[0047] The molecular weight of the product is tested by GPC, using THF as the eluent, PS as the standard sample, elution rate: 1mL / min, test temperature: 40°C, POSS-PCL 1000 Mn=5956 g / mol, molecular weight distribution PDI=1.46.

preparation example 2

[0049] Weigh T 8 COOH, dissolved in dichloromethane with PCL-2000, T 8 The mass ratio of COOH to PCL-2000 is 1:12, add the catalyst stannous octoate, stir evenly, raise the temperature to 200°C, react for 1 hour, remove the solvent, dry in a vacuum oven at 45°C for 12 hours, and obtain POSS graft PCL-2000, denoted as POSS-PCL 2000 ,spare.

[0050] GPC test showed that POSS-PCL 2000 Mn=13950 g / mol, molecular weight distribution PDI=1.24.

preparation example 3

[0052] Weigh T 8 COOH, dissolved in dichloromethane with PCL-3000, T 8 The mass ratio of COOH to PCL-3000 is 1:20, add the catalyst stannous octoate, stir evenly, raise the temperature to 200°C, react for 1 hour, remove the solvent, and dry in a vacuum oven at 45°C for 12 hours to obtain POSS graft PCL-3000, denoted as POSS-PCL 3000 ,spare.

[0053] GPC test showed that POSS-PCL 3000 Mn=21048g / mol, molecular weight distribution PDI=1.20.

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Abstract

The invention provides a floating fiber-free PC / ABS composite material. The floating fiber-free PC / ABS composite material comprises the following components: 50-80 parts of PC; 20-50 parts of ABS; 10-30 parts of glass fibers; 2-10 parts of a flow modifier; 1-10 parts of a flame retardant; 0-0.5 part of an antioxidant; and 0-0.5 part of a weather-resistant agent; the flowing property, flame retardant property and mechanical property of the obtained PC / ABS composite material are improved, and no floating fiber exists on the surface of the material.

Description

technical field [0001] The invention relates to a flame-retardant material, in particular to a flame-retardant PC / ABS composite material without floating fibers. Background technique [0002] Polycarbonate (PC) is a thermoplastic engineering plastic with excellent comprehensive properties. It has outstanding impact resistance, excellent mechanical properties and flame retardancy, but it also has the following disadvantages: high melt viscosity and poor processing fluidity , and sensitive to notch, poor dimensional stability, poor solvent resistance. [0003] ABS resin is a copolymer of three monomers of acrylonitrile (A), butadiene (B) and styrene (S). ABS resin maintains the excellent electrical properties and easy processability of styrene, and increases elasticity, Strength (characteristics of butadiene), heat resistance and corrosion resistance (excellent performance of acrylonitrile), and high surface hardness, good chemical resistance, and by changing the ratio of the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08L55/02C08L83/10C08K7/14C08K3/32C08K13/04C08G77/445
CPCC08L69/00C08G77/445C08L2201/02C08L2205/03C08K2201/003C08K2201/004C08L55/02C08L83/10C08K7/14C08K3/32C08K13/04
Inventor 王雨褚仁凯
Owner 广东中成特殊材料有限公司