Floating fiber-free flame-retardant PC/ABS composite material
A composite material, no floating fiber technology, applied in the field of flame retardant materials, can solve the problems of notch sensitivity, poor processing fluidity, poor dimensional stability, etc., and achieve the effects of improving flow performance, improving flame retardant performance, and light weight
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preparation example 1
[0046] Weigh octacarboxyphenylsilsesquioxane (POSS) (T 8 COOH), dissolved in dichloromethane with PCL-1000, T 8 The mass ratio of COOH to PCL-1000 is 1:5, add the catalyst stannous octoate, stir evenly, raise the temperature to 200°C, react for 1 hour, remove the solvent, and dry in a vacuum oven at 45°C for 12 hours to obtain POSS graft PCL-1000, denoted as POSS-PCL 1000 ,spare.
[0047] The molecular weight of the product is tested by GPC, using THF as the eluent, PS as the standard sample, elution rate: 1mL / min, test temperature: 40°C, POSS-PCL 1000 Mn=5956 g / mol, molecular weight distribution PDI=1.46.
preparation example 2
[0049] Weigh T 8 COOH, dissolved in dichloromethane with PCL-2000, T 8 The mass ratio of COOH to PCL-2000 is 1:12, add the catalyst stannous octoate, stir evenly, raise the temperature to 200°C, react for 1 hour, remove the solvent, dry in a vacuum oven at 45°C for 12 hours, and obtain POSS graft PCL-2000, denoted as POSS-PCL 2000 ,spare.
[0050] GPC test showed that POSS-PCL 2000 Mn=13950 g / mol, molecular weight distribution PDI=1.24.
preparation example 3
[0052] Weigh T 8 COOH, dissolved in dichloromethane with PCL-3000, T 8 The mass ratio of COOH to PCL-3000 is 1:20, add the catalyst stannous octoate, stir evenly, raise the temperature to 200°C, react for 1 hour, remove the solvent, and dry in a vacuum oven at 45°C for 12 hours to obtain POSS graft PCL-3000, denoted as POSS-PCL 3000 ,spare.
[0053] GPC test showed that POSS-PCL 3000 Mn=21048g / mol, molecular weight distribution PDI=1.20.
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