Production of all-polymer self-supporting electrode and application of all-polymer self-supporting electrode in flexible electrochemical sensor

A polymer, self-supporting technology, applied in the direction of electrochemical variables of materials, scientific instruments, instruments, etc., can solve the problems affecting the durability and stability of flexible electrochemical sensors, poor stability of flexible wearable sensors, weak resistance to mechanical deformation, etc. The problem is to overcome the poor mechanical properties, the electrical conductivity and the electrical conductivity are stable.

Pending Publication Date: 2021-03-16
QINGDAO UNIV OF SCI & TECH
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Problems solved by technology

[0004] Aiming at the deficiencies of the prior art, the present invention provides a preparation of an all-polymer self-supporting electrode and its application in flexible electrochemical sensors. The problem of low mechanical strength and poor flexibility
On the other hand, when today's flexible conductive electrodes are applied to flexible electrochemical sensors, there is a significant difference in the m

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  • Production of all-polymer self-supporting electrode and application of all-polymer self-supporting electrode in flexible electrochemical sensor
  • Production of all-polymer self-supporting electrode and application of all-polymer self-supporting electrode in flexible electrochemical sensor
  • Production of all-polymer self-supporting electrode and application of all-polymer self-supporting electrode in flexible electrochemical sensor

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[0032]Next, the technical solutions in the embodiments of the present invention will be apparent from the embodiment of the present invention, and it is clearly described, and it is understood that the described embodiments are merely embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, there are all other embodiments obtained without making creative labor without making creative labor premises.

[0033] Such as Figure 1-10 As shown, the present invention provides a technical solution: a preparation of a total polymer self-supporting electrode, comprising the steps of:

[0034] a) Synthesis PEE-PPY in an organic electrolytic solution in an organic electrolytic solution, and the working electrode has been plated with titanium and platinum, and the electrode used is a stainless steel electrode, and the reference electrode is a silver wire. , Polymerization with constant current, current density is 0.8-1.0mA / cm 2 Under...

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Abstract

The invention discloses production of an all-polymer self-supporting electrode and an application of the all-polymer self-supporting electrode in a flexible electrochemical sensor, and relates to thetechnical field of electrochemical sensors. The production comprises the following steps: a) producing a polypyrrole film with a sandwich structural formula by adopting an electrochemical polymerization method; and synthesizing a pentaerythritol ethoxylate- polypyrrole (PEE-PPy) film by adopting an electrochemical polymerization mode in an organic phase system, namely an organic electrolyte, taking a glass sheet plated with titanium and platinum in sequence as a working electrode, taking a stainless steel electrode as a counter electrode, and taking a silver wire as a reference electrode; According to the production of the all-polymer self-supporting electrode and the application of the all-polymer self-supporting electrode in the flexible electrochemical sensor, the polypyrrole compositefilm with the sandwich structural formula is used as the self-supporting electrode for detecting dopamine by the flexible electrochemical sensor, and the sensor does not need to be assembled by combining an additional current collector, a mechanical substrate, a conductive additive and the like; and dopamine detection sensitivity is high, the stability is high, and the capability of bearing long-term mechanical deformation is realized.

Description

technical field [0001] The invention relates to the technical field of electrochemical sensors, in particular to the preparation of an all-polymer self-supporting electrode and its application in flexible electrochemical sensors. Background technique [0002] In recent years, with the rapid development of mobile Internet and smart terminals, wearable electronic devices have shown a huge market prospect. As one of the core components, flexible wearable electronic sensors, with their wide range, high sensitivity and fast response Features such as time, portability, comfort of use, and multifunctional integration have become the focus of attention, motivating researchers at home and abroad to study and develop flexible and wearable electronic sensors. Flexible electrochemical sensors can realize real-time health monitoring of the human body by converting chemical signals into electrical signals. Current research is mainly to realize the flexibility and wearability of electroch...

Claims

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Application Information

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IPC IPC(8): G01N27/30G01N27/416
CPCG01N27/30G01N27/416
Inventor 高凤仙罗细亮宋璟瑶滕贺许珍颖许梁
Owner QINGDAO UNIV OF SCI & TECH
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