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Method for converting byproduct mixed oxygen-containing compound in methanol-to-olefin process

A technology for producing olefins and compounds from methanol, which is applied in the direction of producing hydrocarbons from oxygen-containing organic compounds, carbon compound catalysts, chemical instruments and methods, etc., can solve the problems of unspecified oxygen-rich stream conversion and complicated processes, and avoid Heavy hydrocarbons and phenolic compounds, high conversion rate of oxides, and the effect of avoiding formation

Active Publication Date: 2021-03-26
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Because the method is equipped with two reactors, the process is complicated, and the conversion of the oxygen-rich stream is not given

Method used

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  • Method for converting byproduct mixed oxygen-containing compound in methanol-to-olefin process
  • Method for converting byproduct mixed oxygen-containing compound in methanol-to-olefin process
  • Method for converting byproduct mixed oxygen-containing compound in methanol-to-olefin process

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042]Using SAPO-34 catalyst and fluidized bed reactor with cross feed distributor, including fast bed reactor (1), double dense bed (2), external heat extractor (3), circulating inclined pipe (5) , remove the inclined pipe (6), the regeneration inclined pipe (14), the inclined pipe to be produced (15), the methanol raw material distributor (8), the cross feed distributor (9); the circulation inclined pipe (5) Connect the second dense bed (2) with the fast bed reactor (1); the regeneration inclined pipe (14) is connected with the fast bed reactor (1); the inclined pipe (15) to be born is connected with the second dense bed (2); The downward inclined pipe (6) connects the external heat extractor (3) and the fast bed reactor (1); the methanol raw material distributor (8) and the cross feed distributor (9) are located at the lower part of the fast bed reactor (1) The connecting port of the regeneration inclined pipe (14) and the fast bed reactor (1) is located directly above the ...

Embodiment 2

[0053] Using SAPO-34 catalyst and fluidized bed reactor with cross feed distributor, including fast bed reactor (1), double dense bed (2), external heat extractor (3), circulating inclined pipe (5) , remove the inclined pipe (6), the regeneration inclined pipe (14), the inclined pipe to be produced (15), the methanol raw material distributor (8), the cross feed distributor (9); the circulation inclined pipe (5) Connect the second dense bed (2) with the fast bed reactor (1); the regeneration inclined pipe (14) is connected with the fast bed reactor (1); the inclined pipe (15) to be born is connected with the second dense bed (2); The downward inclined pipe (6) connects the external heat extractor (3) and the fast bed reactor (1); the methanol raw material distributor (8) and the cross feed distributor (9) are located at the lower part of the fast bed reactor (1) The connecting port of the regeneration inclined pipe (14) and the fast bed reactor (1) is located directly above the...

Embodiment 3

[0064] Using SAPO-34 catalyst and fluidized bed reactor with cross feed distributor, including fast bed reactor (1), double dense bed (2), external heat extractor (3), circulating inclined pipe (5) , remove the inclined pipe (6), the regeneration inclined pipe (14), the inclined pipe to be produced (15), the methanol raw material distributor (8), the cross feed distributor (9); the circulation inclined pipe (5) Connect the second dense bed (2) with the fast bed reactor (1); the regeneration inclined pipe (14) is connected with the fast bed reactor (1); the inclined pipe (15) to be born is connected with the second dense bed (2); The downward inclined pipe (6) connects the external heat extractor (3) and the fast bed reactor (1); the methanol raw material distributor (8) and the cross feed distributor (9) are located at the lower part of the fast bed reactor (1) ; The connection port of the regeneration inclined pipe (14) and the fast bed reactor (1) is located directly above t...

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Abstract

The invention provides a method for converting a byproduct mixed oxygen-containing compound in a methanol-to-olefin process, which comprises the following steps that: a byproduct mixed oxygen-containing compound aqueous solution raw material (11) of a methanol-to-olefin separation unit enters a fast bed reactor (1) through a cross type feeding distributor (9) and is in contact reaction with a regenerated catalyst (12) entering through a regenerated inclined pipe (14), and a product generated by the reaction and a coking catalyst ascend. By adopting the method disclosed by the invention, the byproduct mixed oxygen-containing compound can be efficiently converted into low-carbon hydrocarbon, and the generation of heavy hydrocarbon and phenol compounds is avoided.

Description

technical field [0001] The invention belongs to the field of methanol-to-olefins, in particular to a method for converting by-product mixed oxygenates in the methanol-to-olefins process. Background technique [0002] Methanol is used as a chemical raw material, and SAPO-34 and ZSM-5 catalysts are used to react to obtain ethylene, propylene and aromatic products. Ethylene and propylene (light olefins) are used in a variety of processes for making plastics and other chemical compounds. The process of producing methanol from coal or natural gas is very mature and can achieve a production scale of millions of tons. Oxygenates such as ketones, aldehydes, and ethers are by-products in the MTO process. In order to reduce the carbon-based loss of raw materials, the existing technology is to return this part of oxygenates and unconverted methanol directly to the MTO reactor or from the oxygenate conversion reactor. Discharged for downstream product recovery. Such recycling and sub...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C1/20C07C11/04C07C11/06B01J8/24
CPCC07C1/20B01J8/28B01J8/228B01J8/1836B01J8/1809B01J8/0055B01J2208/00911B01J2208/00256C07C11/04C07C11/06Y02P30/20Y02P30/40Y02P20/584
Inventor 李晓红齐国祯王洪涛王莉
Owner CHINA PETROLEUM & CHEM CORP
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