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Electroplating grade lcp composite material and its preparation method and antenna

A composite material and electroplating-grade technology, which is applied in the field of electroplating-grade LCP composite materials and its preparation, can solve the problems of high dielectric loss of LCP materials and relatively large types of thermoplastic elastomers, and achieve high bonding strength and meet the use in harsh environments Requirements, the effect of simple operation

Active Publication Date: 2022-04-22
JIANGMEN DENGZHONGTAI ENG PLASTICS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the better fluidity of LCP itself, the types of thermoplastic elastomers added are limited, and the dielectric loss of LCP materials is relatively high

Method used

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  • Electroplating grade lcp composite material and its preparation method and antenna

Examples

Experimental program
Comparison scheme
Effect test

Embodiment approach

[0063] As an optional embodiment of the present invention, the preparation method of LCP composite resin comprises the following steps:

[0064] The LCP matrix raw material and the high polymer gel are mixed, and the polymerization reaction is carried out to obtain the LCP composite resin.

[0065] It can be understood that the LCP composite resin uses LCP resin as the main resin, and polymer gel is added in the process of forming (polymerizing) the LCP resin from the LCP matrix raw material. There is no limitation as to whether the high polymer gel is added at the initial stage of formation (initial stage of polymerization reaction) or at the end stage of formation (final stage of polymerization reaction).

[0066] It should be noted that the high polymer gel is added during the polymerization reaction, not after the polymerization reaction is completed. The timing of adding a specific polymer gel is selected to ensure that the polymer gel is uniformly dispersed in the LCP r...

Embodiment 1

[0101] The present embodiment provides a kind of electroplating grade LCP composite material, comprises the raw material of following mass fraction:

[0102] LCP composite resin 79%, reinforcing filler 20% and coupling agent 1%.

[0103] Among them, the LCP composite resin uses the LCP resin formed by the LCP matrix raw material as the main resin, and the high polymer gel is uniformly dispersed in the LCP resin; the repeating units included in the LCP resin include p-hydroxybenzoic acid, 4,4-biphenol, Terephthalic acid and isophthalic acid, the polymer gel is polyphenylene ether resin (the number average molecular weight is 10000, the terminal hydroxyl content is 900), with LCP composite resin as a whole, the combination of LCP resin and polymer gel The mass ratio is 90%:10%; the reinforcing filler is quartz fiber; the coupling agent is titanate coupling agent (Nanjing Shuguang Chemical Group, model: SG-TnBT).

[0104] The preparation method of LCP composite resin comprises t...

Embodiment 2

[0112] This example provides an electroplating-grade LCP composite material, except that the polymer gel in the LCP composite resin is replaced by a polyphenylene ether resin with a number average molecular weight of 10,000 and a terminal hydroxyl content of 900 with a number average For the polyphenylene ether resin with a hydroxyl content of 300, the rest of the raw materials and dosage are the same as in Example 1.

[0113] After testing, the initial flow temperature of the LCP composite resin is 320°C, the dielectric constant is 2.8, and the dielectric loss is 0.0011.

[0114] The preparation method of the electroplating-grade LCP composite material provided in this example is the same as that in Example 1.

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Abstract

The invention provides an electroplating grade LCP composite material, a preparation method thereof and an antenna, and relates to the technical field of polymer materials. The electroplating-grade LCP composite material is mainly made of LCP composite resin, reinforcing filler and coupling agent. Among them, the LCP composite resin is made of LCP matrix raw materials and specific types of polymer gels. The formed LCP composite resin has high The polymer gel is uniformly dispersed in the LCP resin structure formed by the LCP matrix raw material. By using the LCP composite resin with the above-mentioned specific composition and structure to be combined with reinforcing fillers and coupling agents, the electroplating-grade LCP composite material has low dielectric loss and high tensile strength, and can be used for electroplating treatment. Using this electroplating The base material formed by the grade LCP composite material has a high bonding force with the metal plating layer, so that it can be used in the manufacture of communication antennas. The present invention also provides a preparation method of the above-mentioned electroplating grade LCP composite material.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to an electroplating grade LCP composite material, a preparation method thereof and an antenna. Background technique [0002] With the advent of the 5G era, the frequency of signal transmission in the communication industry is getting higher and higher, so the dielectric loss of materials is required to be as low as possible to reduce signal attenuation and energy consumption. Liquid crystal polymer (LCP) has low dielectric loss and stable characteristics in a wide frequency range, so it is very suitable for the performance requirements of the communication industry in the future. In the field of communication, antennas used to receive signals generally require electroplating metal plating. However, due to the high chemical resistance of LCP, there is no way to directly perform water plating. However, the metal coating of products made of universal plating has poor bondi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/00C08L71/02C08L25/06C08K9/04C08K9/06C08K7/10C08K7/28H01Q1/36H01Q1/38
CPCC08L67/00H01Q1/36H01Q1/38C08L2205/03C08L2205/025C08L71/12C08K9/04C08K7/10C08L25/06C08K9/06C08K7/28
Inventor 梁永华黄贤智郑红专金良文
Owner JIANGMEN DENGZHONGTAI ENG PLASTICS CO LTD