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Modified fly ash support body, modification method of fly ash support body, fly ash ceramic membrane preparation method and application thereof

A technology of fly ash and support body is applied in the field of ceramic membrane to achieve the effect of high porosity

Active Publication Date: 2021-04-16
CHNA ENERGY INVESTMENT CORP LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to provide a modified fly ash support body and a method for modifying the fly ash support body and the powdered coal Gray ceramic membrane and its preparation method and application, the surface of the fly ash ceramic membrane prepared by using the modified fly ash support provided by the invention does not produce cracks and pinholes, and solves the problem of membrane layer particles penetrating into the support Pore ​​blocking problem, so that the prepared ceramic membrane has high porosity, bending strength, pure water flux and acid and alkali resistance

Method used

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  • Modified fly ash support body, modification method of fly ash support body, fly ash ceramic membrane preparation method and application thereof
  • Modified fly ash support body, modification method of fly ash support body, fly ash ceramic membrane preparation method and application thereof

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preparation example Construction

[0023] Wherein, the preparation method of the fly ash support includes: mixing the composition for preparing the fly ash support with water, molding, and then roasting;

[0024] Wherein, the composition for preparing the fly ash support includes the first fly ash, the first organic molding agent and the first plasticizer, so that the total weight of the composition for preparing the fly ash support is Standard, the content of the first fly ash is 85-97% by weight, the content of the first organic molding agent is 0.9-7% by weight, and the content of the first plasticizer is 1.6-9% by weight;

[0025] Wherein, the first fly ash contains component M, and the component M is selected from TiO 2 , CaO and MgO, and based on the total weight of fly ash, the content of component M is 1-8% by weight.

[0026] In the present invention, based on the total weight of the solution containing the polysaccharide matrix and / or derivatives thereof, the content of the polysaccharide matrix and / ...

Embodiment approach

[0034] According to a preferred embodiment of the present invention, based on the total weight of the composition, the content of the first fly ash is 87-95% by weight, the content of the first organic molding agent is 2-6% by weight, the first plasticizer The content of the agent is 2-7% by weight.

[0035] According to a more preferred embodiment of the present invention, based on the total weight of the composition, the content of the first fly ash is 89-93% by weight, the content of the first organic molding agent is 3-5% by weight, and the first increase The content of the plasticizer is 3-6% by weight.

[0036] In the present invention, there is no need to add inorganic forming agents in the composition, such as kaolinite, illite, montmorillonite, vermiculite, sepiolite, etc., and in the present invention, there is no need to add pore-forming agents in the composition. Agents, such as commonly used carbon black, starch powder, calcium carbonate, polystyrene particles. ...

Embodiment 1

[0094] (1) The composition (wherein the composition of the first fly ash is as shown in S1 in Table 1, and the amount of each component in the composition is as shown in Table 2) for producing the fly ash support body is carried out with water Mixing, the weight ratio of the composition to water is 1:0.2 to obtain the mixed raw material;

[0095] Wherein, the spherical particle content in the fly ash in the composition is 70%, the organic molding agent is methyl cellulose, and the plasticizer is glycerol;

[0096] (2) After aging the mixed raw material obtained in step (1) at 25°C for 36 hours, perform mechanical vacuum slime refining to obtain a wet mud mud section, and then put the wet mud mud section into an extruder for extrusion molding to obtain Tubular body, the inner diameter is 4mm, the outer diameter is 30mm, the number of channels is 19, the same below;

[0097] (3) Dry the green body obtained in step (2) at 120°C for 4 hours, then raise the temperature to 1400°C a...

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Abstract

The invention relates to the technical field of ceramic membranes, and discloses a modified fly ash support body, a modification method of the fly ash support body, a fly ash ceramic membrane, a preparation method and application thereof. The modification method of the fly ash support body comprises the following steps: performing first contact on a fly ash support body and a solution containing a polysaccharide matrix and / or a derivative thereof so as to form the polysaccharide matrix and / or derivative layer thereof on the surface of the fly ash support body to obtain the modified fly ash support body, wherein the composition for preparing the fly ash support body comprises first coal ash, a first organic forming agent and a first plasticizer, the fly ash comprises a component M, and the component M is selected from at least one of TiO2, CaO and MgO. According to the invention, the surface of the fly ash ceramic membrane prepared from the modified fly ash support body provided by the invention does not generate cracks and pinholes, and the problem of hole blockage caused by penetration of membrane layer particles into the support body is solved, so that the fly ash ceramic membrane has relatively high porosity, bending strength, pure water flux and acid and alkali resistance.

Description

technical field [0001] The invention relates to the technical field of ceramic membranes, in particular to a modified fly ash support body, a modification method of the fly ash support body, a fly ash ceramic membrane, a preparation method and application thereof. Background technique [0002] Fly ash is a kind of industrial waste with abundant reserves, cheap and easy to get. Its main components are silica and alumina, and the content of the two reaches more than 70%, which is similar to the clay composition in the raw materials of traditional ceramics. In addition, fly ash itself has a large number of micropores and a high specific surface area. Utilizing this industrial waste can not only reduce environmental pollution, but also develop and produce low-cost ceramics with high added value. [0003] CN106669440A discloses a method for modification and modification of ceramic membranes, which includes the following steps: Step 1, surface-treating the ceramic membranes to ob...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B33/135C04B38/00C04B38/08C02F1/44B01D46/54
CPCY02P40/60
Inventor 马宁丁书强董阳卓锦德王珂
Owner CHNA ENERGY INVESTMENT CORP LTD