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Application of D-tartaric acid cyclodimethyl sulfate in lithium ion battery electrolyte

A technology of dimethyl cyclic sulfate and lithium-ion batteries, which is applied in the field of application of D-dimethyl cyclic sulfate in lithium-ion batteries, and can solve the problem of narrow liquid temperature window and inability to balance thermal stability and electrochemistry Stability, it is difficult to achieve both high and low temperature issues

Active Publication Date: 2021-04-16
HIGHPOWER TECH HUIZHOU
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  • Summary
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  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

During the use of lithium-ion batteries, it has always been the focus of research by battery scientists to take into account the performance at high and low temperatures. Generally speaking, batteries with good performance at room temperature can only take into account good low-temperature performance or high-temperature performance, which is difficult. Achieve both high and low temperature
The main reason is that the liquid temperature window of the lithium-ion battery electrolyte is narrow, which cannot take into account the thermal stability and electrochemical stability at high and low temperatures. When the temperature rises, the lithium-ion battery shows a higher initial capacity, but the battery The cycle stability of the battery is reduced, and the rate of capacity decay is accelerated. Therefore, the cycle stability of the battery at high temperature is also very important.

Method used

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  • Application of D-tartaric acid cyclodimethyl sulfate in lithium ion battery electrolyte
  • Application of D-tartaric acid cyclodimethyl sulfate in lithium ion battery electrolyte
  • Application of D-tartaric acid cyclodimethyl sulfate in lithium ion battery electrolyte

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Experimental program
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Embodiment 1

[0022] Electrolyte preparation: Mix EC (ethylene carbonate), DEC (diethyl carbonate) and PC (propylene carbonate) in a mass ratio of 1:1:1 to form an organic solvent. Add the additives in Table 1 to the organic solvent, mix well and then add LiPF6 to obtain a mixed solution with a LiPF6 concentration of 1.1mol / L, which is the electrolyte solution L1#~L19#. The content of additives in Table 1 is the mass percentage of the electrolyte, VC is vinylene carbonate, MP is methyl propionate, DTD is vinyl sulfate, and PS is 1,3-propane sultone. Dimethyl D-tartrate cyclic sulfate was purchased from Guangzhou Weber Technology Co., Ltd.

[0023] Table 1 Composition and content of additives in different groups of electrolytes

[0024]

[0025]

[0026] Preparation of battery

[0027] The preparation of the positive electrode sheet: the positive electrode active material lithium cobaltate (LiCoO 2 ), the conductive agent CNT (carbon nanotube), and the binder polyvinylidene fluoride...

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Abstract

The invention discloses an application of D-tartaric acid cyclodimethyl sulfate in a lithium ion battery electrolyte. The structural formula of the D-taric acid cyclodimethyl sulfate is shown as a formula (I) in the specification. The D-taric acid cyclodimethyl sulfate is used as an additive of the lithium ion battery electrolyte, can improve the high-temperature cycle performance and the low-temperature charging performance of the lithium ion battery, and has relatively good application prospects in the technical field of the lithium ion battery.

Description

technical field [0001] The invention relates to the technical field of lithium ion batteries, in particular to the application of a kind of D-tartrate cyclic dimethyl sulfate in lithium ion battery electrolyte. Background technique [0002] Lithium-ion batteries have developed rapidly because of their advantages such as high specific energy, high battery voltage, wide operating temperature range, long storage life, no memory effect, low self-discharge rate, and fast charge and discharge. At present, lithium-ion batteries have been widely used In electronic products such as mobile phones, notebook computers, and digital cameras, they are also used as power batteries in electric bicycles, model airplanes, and electric vehicles. During the use of lithium-ion batteries, it has always been the focus of research by battery scientists to take into account the performance at high and low temperatures. Generally speaking, batteries with good performance at room temperature can only t...

Claims

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Application Information

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IPC IPC(8): H01M10/0567H01M10/058H01M10/0525H01M10/42
CPCY02E60/10Y02P70/50
Inventor 李枫张昌明杜冬冬邓卫龙胡大林
Owner HIGHPOWER TECH HUIZHOU
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