Dyeable graphene-nylon composite material and preparation method thereof

A nylon composite material and composite material technology are applied in the field of graphene-nylon composite material preparation, can solve the problem of polyamide composite material not being dyed, etc., and achieve the effects of being beneficial to industrial application, good mechanical properties, and improving quality

Active Publication Date: 2021-07-16
CHINA PETROLEUM & CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of this invention is to provide a kind of graphene-nylon composite material that can be dyed, by adding additives, the composite material becomes off-white, solves the problem that the polyamide composite material reinforced by carbon materials cannot be dyed, and broadens the graphene-nylon material. Application range

Method used

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  • Dyeable graphene-nylon composite material and preparation method thereof
  • Dyeable graphene-nylon composite material and preparation method thereof
  • Dyeable graphene-nylon composite material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0025] Graphene-nylon composites were prepared by polymerizing 20% ​​sulfonated graphene, 78% nylon 6 and 2% triazine DSD acid additives in dimethyl sulfoxide (DMSO) as a solvent. The reaction steps are as follows:

[0026] (1) Sulfonated graphene (sulfur content is 0.5%) was added to dimethyl sulfoxide (DMSO) solvent, and ultrasonically oscillated for 0.5 h to obtain sulfonated graphene-dimethyl sulfoxide with a mass concentration of 20 mg / mL. Dispersions;

[0027] (2) Add the homogeneous dispersion liquid obtained in step (1), triazine DSD acid additive, nylon 6 and solvent DMSO into the reactor, and react at 160°C for 4 h to obtain a graphene-nylon 6 composite material; figure 1 Shown is the schematic diagram of the graphene-nylon 6 composite material of the present invention, namely the schematic diagram of the graphene-nylon 6 composite material before dyeing;

[0028] (3) Add methylene blue in the obtained off-white graphene-nylon 6 composite material to make blue grap...

Embodiment 2

[0031] Graphene-nylon composites were prepared by polymerization of 25% sulfonated graphene, 72% nylon 66, and 3% triazine DSD acid additives in dimethyl sulfoxide (DMSO) as a solvent. The reaction steps are as follows:

[0032] (1) Sulfonated graphene (sulfur content is 10%) was added to dimethyl sulfoxide (DMSO) solvent, and ultrasonically oscillated for 0.5 h to obtain sulfonated graphene-dimethyl sulfoxide with a mass concentration of 50 mg / mL. Dispersions;

[0033] (2) Add the homogeneous dispersion liquid obtained in step (1), triazine DSD acid additive, nylon 66 and solvent DMSO into the reactor, and react at 160°C for 4 hours to obtain a graphene-nylon 66 composite material;

[0034] (3) add rhodamine B in the obtained off-white graphene-nylon 66 composite material, make pink graphene-nylon composite material; image 3 It is a schematic diagram of graphene-nylon 66 composite material dyed with rhodamine B, and the schematic diagram has been processed in gray;

[003...

Embodiment 3

[0037] Graphene-nylon composites were prepared by polymerizing 35% sulfonated graphene, 60% nylon 610 and 5% stilbene biphenyl additives in dimethyl sulfoxide (DMSO) as a solvent. The reaction steps are as follows:

[0038] (1) Sulfonated graphene (with a sulfur content of 30%) was added to dimethyl sulfoxide (DMSO) solvent, and ultrasonically oscillated for 0.5 h to obtain sulfonated graphene-dimethyl sulfoxide with a mass concentration of 80 mg / mL. Dispersions;

[0039] (2) Add the homogeneous dispersion liquid obtained in step (1), triazine DSD acid additive, nylon 610 and solvent DMSO into the reaction kettle, and react at 160°C for 4 hours to obtain a graphene-nylon 610 composite material;

[0040] (3) Add rhodamine B in the obtained off-white graphene-nylon 610 composite material to make pink graphene-nylon composite material;

[0041] (4) The graphene-nylon 610 composite material is made into a standard sample by an injection molding machine for mechanical performance...

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Abstract

The invention relates to a dyeable graphene-nylon composite material and a preparation method thereof, the graphene-nylon composite material takes dimethyl sulfoxide as a solvent, and is prepared by reaction of 15-35% by mass of sulfonated graphene, 60-80% by mass of nylon and 1-5% by mass of an auxiliary agent. The preparation method comprises the following steps: (1) adding sulfonated graphene into dimethyl sulfoxide to obtain sulfonated graphene-dimethyl sulfoxide uniform dispersion liquid; (2) adding the sulfonated graphene-dimethyl sulfoxide dispersion liquid, an auxiliary agent, nylon and a solvent dimethyl sulfoxide into a reaction kettle, and reacting at 160 DEG C for 4 hours to obtain a graphene-nylon composite material; and (3) adding methylene blue or rhodamine B into the prepared grey white graphene-nylon composite material to prepare the colored graphene-nylon composite material. The problem that the carbon material reinforced polyamide composite material cannot be dyed is solved, the application range of the graphene-nylon material is widened, and the prepared composite material has good mechanical properties.

Description

technical field [0001] The invention belongs to the technical field of polymer composite materials, and relates to a preparation method of a dyeable graphene-nylon composite material. Background technique [0002] Nylon fibers represented by nylon 6 and nylon 66 are widely used in clothing materials and industrial materials due to their excellent mechanical properties, electrical properties, mechanical properties, and good solvent resistance, wear resistance, self-lubrication, and processing and molding properties. are widely used in. Especially because of its good strength, wear resistance, solvent resistance and dyeability, it is widely used in clothing, ropes and net materials. [0003] However, with the advancement of science and technology and the improvement of people's living standards, the requirements for the strength of nylon fibers are getting higher and higher. Therefore, the development of new nylon fiber varieties has become an increasingly important issue. ...

Claims

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Application Information

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IPC IPC(8): C08L77/02C08L77/06C08K3/04C08K5/42C08K5/46C08K5/19
CPCC08K3/042C08K5/42C08K5/46C08K5/19C08L77/02C08L77/06
Inventor 郝振岐徐伟箭陈春凤欧恩才王仲霞雷智友
Owner CHINA PETROLEUM & CHEM CORP
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