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Adhesive with high electrical and thermal conductivity and preparation method thereof

A technology of conductive adhesive and conductive filler, used in conductive adhesives, adhesives, polymer adhesive additives, etc., can solve the problems of long production process, complex process, low efficiency, etc., to reduce system viscosity, improve electrical conductivity and thermal conductivity. performance, the effect of improving colloid compactness

Inactive Publication Date: 2021-08-17
北京中天鹏宇科技发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the thermal conductivity of the existing conductive adhesives on the market is generally below 5W / m·k, and the volume resistivity is 5×10 -4 Ω·cm, which still cannot meet the requirements of some high-power devices
[0004] Moreover, most of the high thermal and conductive adhesives on the market use nano-silver wires or chemically prepared reduced silver and micro-silver powder as conductive fillers. The process is relatively complicated and the cost is high, resulting in a long production process and low efficiency.

Method used

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  • Adhesive with high electrical and thermal conductivity and preparation method thereof

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preparation example Construction

[0026] According to another aspect of the present invention, a method for preparing the above-mentioned conductive adhesive is provided. The preparation method comprises the following steps: uniformly dispersing epoxy resin, toughening agent, curing agent, curing accelerator, coupling agent, thixotropic agent, solvent and conductive filler to prepare conductive adhesive; preferably, the preparation method It also includes the step of adding a silver powder surface treatment agent.

[0027] According to yet another aspect of the present invention, an application of the above-mentioned conductive adhesive in electronic packaging is provided.

Embodiment 1

[0030] First, pre-mix the resin matrix, take 2.7g bisphenol A epoxy resin, add 0.3g polyether polyol, and carry out polyether toughening modification. Add 0.75g multifunctional epoxy resin (trimethylolethane triglycidyl ether), 0.75g core-shell toughening agent carries out toughening modification to epoxy resin, obtains the evenly dispersed resin matrix after grinding for 10 minutes, and then Add 3g acid anhydride curing agent (phenylone tetra-acid dianhydride), 0.04g imidazole accelerator (2-ethyl 4-methylimidazole), coupling agent 0.02g (KH560) and thixotropic agent 0.04g (fumed silica ) after grinding for 10 minutes, carry out ultrasonic dispersion to mix the auxiliary agent and resin evenly, then mechanically evacuate and defoam for 30 minutes, take out the cuvette to obtain the organic mixture, add 30g of flake silver powder with an average particle size of 3 μm and a tap density of 6g / cc, 6g flake silver powder with an average particle size of 10μm and a tap density of 3...

Embodiment 2

[0032]First, pre-mix the resin matrix, take 0.9g novolak epoxy resin, 1.8g bisphenol A epoxy resin, add 0.3g polyether polyol, and carry out polyether toughening modification. Add 0.75g multifunctional epoxy resin (cyclohexyl dimethanol diglycidyl ether), 0.75g core-shell toughening agent to toughen and modify the epoxy resin, and grind for 10 minutes to obtain a uniformly dispersed resin matrix, then add 3g Anhydride curing agent (tetrahydrophthalic anhydride), 0.4g imidazole accelerator (2-methylimidazole), 0.2g coupling agent (KH550) and 0.04g thixotropic agent (organic bentonite) were ground for 10 minutes and then ultrasonically Disperse to mix the additives and resin evenly, then mechanically vacuumize and defoam for 30 minutes, take out the cuvette to obtain the organic mixture, add 42g of spherical silver powder with an average particle size of 2μm and a tap density of 6g / cc, with an average particle size of 6μm and a tap density of 6g Flake silver powder with a densit...

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Abstract

The invention discloses an adhesive with high electrical and thermal conductivity and a preparation method thereof. The conductive adhesive comprises the following components in parts by weight: 5-10 parts of epoxy resin, 0.5-2 parts of a toughening agent, 3-5 parts of a curing agent, 0.03-0.06 part of a curing accelerator, 0.05-0.2 part of a coupling agent, 0.1-0.5 part of a thixotropic agent, 3-8 parts of a solvent and 82-96 parts of a conductive filler, the conductive filler is silver powder, the tap density is 3-6g / cc, and the average particle size is 2-5 microns. According to the technical scheme, the formula is based on epoxy resin, silver powder with different particle sizes is used as conductive filler to prepare the high-thermal-conductivity and high-electric-conductivity adhesive, and meanwhile, the high-thermal-conductivity and high-electric-conductivity adhesive has good electric conductivity and mechanical property; the heat conductivity is greater than 10W / m.k, and the heat conductivity coefficient is more than four times that of the conventional conductive adhesive; the volume resistivity is lower than 9 * 10 <-5 > omega.cm; and the shearing force is greater than 10Kgf.

Description

technical field [0001] The invention relates to the technical field of adhesives, in particular to an adhesive with high electrical and thermal conductivity and a preparation method thereof. Background technique [0002] Conductive adhesive is an adhesive that has both conductive and adhesive functions, and is widely used in the bonding of chips, integrated circuits, high-power LEDs, and electronic components. Compared with traditional Sn / Pb solder, conductive adhesive has simple preparation process, low curing temperature, good mechanical properties, and environmental friendliness. It has become a trend to use conductive adhesive instead of traditional Sn / Pb solder, and it has also become a trend in the field of electronic packaging. The key material is more and more widely recognized. [0003] At present, the thermal conductivity of the existing conductive adhesives on the market is generally below 5W / m·k, and the volume resistivity is 5×10 -4 Ω·cm or so, which still can...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J9/02C09J163/00C09J163/02C09J163/04C09J11/08
CPCC09J9/02C09J163/00C09J163/04C09J11/08C08K2003/0806C08K2201/001C08K2201/005C08K2201/014C08L2207/53C08L2205/035C08L2205/02
Inventor 刘昊崔志远夏华凤周傲松
Owner 北京中天鹏宇科技发展有限公司
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