Selenium-rich foliar fertilizer as well as preparation method and application thereof
A technology of foliar fertilizer and selenium-enriched protein, which is applied in the field of selenium-rich foliar fertilizer and its preparation, can solve the problems of low selenium content, failure to meet the standard, and poor planting effect of foliar fertilizer, so as to improve aroma, The effect of improving stability and improving the ability of anti-oxidation
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Embodiment 1
[0027] The invention relates to a selenium-enriched foliage fertilizer, which comprises the following raw materials: carboxylated hexagonal boron nitride, zinc acetate, β-cyclodextrin, 2-acetyl-1-pyrroline and selenium-enriched protein.
[0028] The preparation method of the above-mentioned selenium-enriched foliar fertilizer comprises the following steps:
[0029] 1) Add 10kg carboxylated hexagonal boron nitride to 100L deionized water, then add 1kg zinc acetate, then stir at 200rpm at 30°C for 2h, centrifuge at 9000g for 20 minutes, collect the precipitate and freeze Dry to obtain carboxyl-containing zinc ion pillared carboxylated hexagonal boron nitride;
[0030] 2) Add 10kg of carboxyl-containing zinc ion pillared carboxylated hexagonal boron nitride to 50L of dichloromethane, and ultrasonically disperse at 20KHz for 20 minutes to obtain a mixed solution; add 10kg of β-cyclodextrin to 50L of dichloromethane (about 8.82mol), then add about 8.82mol of dicyclohexylcarbodiimi...
Embodiment 2
[0034] The invention relates to a selenium-enriched foliage fertilizer, which comprises the following raw materials: carboxylated hexagonal boron nitride, zinc sulfate, alpha-cyclodextrin, 2-acetyl-1-pyrroline and selenium-enriched protein.
[0035] The preparation method of the above-mentioned selenium-enriched foliar fertilizer comprises the following steps:
[0036] 1) Add 10kg carboxylated hexagonal boron nitride to 100L deionized water, then add 2kg zinc sulfate, then stir at 300rpm at 60°C for 3h, centrifuge at 9000g for 25 minutes, collect the precipitate and freeze Dry to obtain carboxyl-containing zinc ion pillared carboxylated hexagonal boron nitride;
[0037] 2) Add 10kg of carboxyl-containing zinc ion pillared carboxylated hexagonal boron nitride to 25L of dichloromethane, and ultrasonically disperse at 50KHz for 10 minutes to obtain a mixed solution; add 10kg of α-cyclodextrin to 25L of dichloromethane (about 8.82 mol), then add about 8.82 mol of dicyclohexylcarb...
Embodiment 3
[0041] The invention relates to a selenium-enriched foliage fertilizer, which comprises the following raw materials: carboxylated hexagonal boron nitride, zinc chloride, gamma-cyclodextrin, 2-acetyl-1-pyrroline and selenium-enriched protein.
[0042] The preparation method of the above-mentioned selenium-enriched foliar fertilizer comprises the following steps:
[0043] 1) Add 10kg carboxylated hexagonal boron nitride to 100L deionized water, then add 1.5kg zinc chloride, then stir at 40°C at a stirring rate of 100rpm for 4h, then centrifuge at a centrifugal force of 9000g for 15 minutes to collect the precipitate Carrying out freeze-drying to obtain carboxyl-containing zinc ion pillared carboxylated hexagonal boron nitride;
[0044] 2) Add 5kg of carboxyl-containing zinc ion pillared carboxylated hexagonal boron nitride to 25L of dichloromethane, and ultrasonically disperse at 20KHz for 20 minutes to obtain a mixed solution; add 10kg of γ-cyclodextrin to 25L of dichloromethane ...
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