The invention discloses an arsenic-free glass bottle, which solves the problems that the conventional food packing glass is not favorable for human health and environmental protection and cannot meet the national specified standards due to higher arsenic and antimony dissolution. The arsenic-free glass bottle is prepared from raw materials in part by weight: 100 parts of quartz sand, 6 to 18 parts of lithium (or sodium or potassium) feldspar, 24 to 38 parts of calcite, 0 to 40 parts of dolomite, 2 to 6 parts of sodium nitrate, 0 to 4.4 parts of fluorite, 0 to 6 parts of sodium fluosilicate, 30 to 40 parts of soda ash, 0.2 to 0.4 part of sodium sulfate, 0.6 to 1.0 part of calcium sulfate and 0.2 to 0.4 part of cerium oxide. The components are mixed uniformly, melted, shaped and annealed to form the arsenic-free glass bottle according to a conventional glass bottle manufacturing method. The arsenic content of the glass bottle is far lower than the national specified dissolution admitted amount, has no toxic or side effect on the human body, and does not produce environmental pollution; and at the same melting temperature, the settling time is shortened to half of time used by using arsenic and antimony oxides, and the production capacity is improved by about 10 percent.