Preparation method of self-bonding and pre-decomposing glass batch

A glass batching and pre-decomposition technology, applied in glass production and other directions, can solve the problems of ineffective utilization of resources, increase energy consumption, waste resources, etc. Effect

Inactive Publication Date: 2013-05-15
YANSHAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

There are many disadvantages in this process, for example: (1) The materials are piled up in the kiln, the heat transfer area is very small, and the heat transfer coefficient is not high
(2) Dust flying in the kiln causes the kiln body to erode and block the regenerator
(3) Stratification (or segregation) is prone to occur in the process of transportation, storage and unloading, which will destroy the mixing uniformity
(5) A large number of resources are not effectively used
In order to prevent flying materials after entering the kiln, stricter requirements are put forward for the particle size composition of raw materials. The content of particles smaller than 0.1mm in quartz sand cannot exceed 5%, which means that more than 30% of fine powder has to be separated out, resulting in waste of resources
(5) The decomposition of carbonate is carried out in the furnace, resulting in high energy consumption
Although this method is also decomposed outside the kiln, the disadvantage is that, first, preheating all raw materials at the same time is not conducive to energy saving
The proportion of carbonate minerals in the glass batch is only about 20%. Decomposing them outside the kiln together with other silicate minerals that do not undergo decomposition reactions will increase unnecessary energy consumption
The second is that the pre-pressed balls will make the carbonate particles wrapped in it, and the heat transfer area is limited, which seriously restricts the heat transfer and mass transfer.
According to the traditional method of feeding into the melting furnace in bulk, the content of fine powder in glass raw materials needs to be strictly controlled, so that about 30% of the resources are not used, which not only wastes resources, but also creates new environmental pollution.

Method used

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  • Preparation method of self-bonding and pre-decomposing glass batch

Examples

Experimental program
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Effect test

Embodiment 1

[0034] Quartz sand, feldspar, limestone, dolomite, light soda ash, and Glauber's salt are mixed according to the ingredients in Table 1; then the calcium carbonate and magnesium carbonate in it are calcined in advance to form hydrated lime and periclase; hydrated lime and periclase are formed by adding water Ca(OH) 2 and Mg(OH) 2 ; The powdered Ca(OH) that has been obtained 2 and Mg(OH) 2 Mix with quartz sand, feldspar, dolomite, soda ash, and thenardite in a forced mixer for 15 minutes, add 10wt% water during the mixing process; spray the final powder with water and press it into a Φ32mm×16mm block. After testing, after being placed for 3 days, the compressive strength reaches 17.3MPa, which can meet the requirements of feeding. After X-ray diffraction analysis, it was proved that calcium silicate hydrate and calcium hydroxide appeared. The pressed blocks were melted and observed with a high-temperature microscope, which proved that the temperature at which the liquid pha...

Embodiment 2

[0038] On the rolling glass production line with a daily melting capacity of 150 tons, the ingredients are prepared according to the design composition in Table 2. The raw materials used are quartz sand, feldspar, limestone, dolomite, light soda ash, and Glauber's salt. The particle size of the raw material is less than 1mm, and there is no requirement for the lower limit of the particle size. According to the amount of molten glass per ton (dry basis), weigh 696.2kg of quartz sand, 45.1kg of feldspar, 46.1kg of limestone, 184.9kg of dolomite, 3.53kg of soda ash, 11.04kg of mirabilite, and 0.45kg of carbon powder. The limestone and dolomite are crushed and ball-milled to 80μm, and then fed into the suspension preheater and precalciner for predecomposition to become slaked lime and periclase. The temperature of the precalcining kiln is 900°C.

[0039] Table 2 Design composition of glass (wt%)

[0040] chemical components SiO 2 Al 2 o 3 Fe 2 o 3 K 2 o...

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Abstract

The invention provides a preparation method of a self-bonding and pre-decomposing glass batch. The method comprises the following steps of: pre-decomposing carbonate out of a kiln so as to obtain slaked lime and periclase, then mixing with other glass batch in a proper proportion in a mixing machinery, adding 8-20wt% of water during the mixing process, then pelletizing the mixed batch, standing for more than 72hours, and hardening by hydration to finally obtain the pelletized glass batch with a certain strength. According to the preparation method, the decomposing process of the carbonate is finished out of the kiln, thus the heat consumption can be greatly reduced; the lower limit of the grain size of the raw material is not required, and thus the resource can be used furthest; the cost of the raw material is reduced by adopting the light soda ash; and the pelletizing of the glass batch can be achieved without using an external bonding agent. Therefore, the preparation method has the advantages that the melting rate is improved, the melting temperature is reduced, the melting efficiency is high, and the like.

Description

technical field [0001] The invention relates to a method for preparing a glass batch material, in particular to a method for preparing a self-adhesive and pre-decomposed glass batch material. Background technique [0002] Traditional glass batch materials are in bulk form, that is, quartz sand, feldspar, dolomite, limestone, soda ash, Glauber's salt and other raw materials with a certain particle size are mixed in proportion and then fed into the melting furnace in a loose state. Melting job. There are many disadvantages in this process, for example: (1) The materials are piled up in the kiln, the heat transfer area is very small, and the heat transfer coefficient is not high. (2) Dust flying in the kiln causes the kiln body to erode and block the regenerator. (3) Stratification (or segregation) is prone to occur in the process of transportation, storage, and unloading to destroy the uniformity of mixing. (4) A large amount of air is brought in to produce microbubbles tha...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03B1/02
CPCY02P40/52Y02P40/57Y02P40/50
Inventor 赵洪力
Owner YANSHAN UNIV
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