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Method for removing sludge odor through cooperation of metal salt and tannin extract, deodorized sludge and application of deodorized sludge

A metal salt and sludge technology, applied in water/sludge/sewage treatment, sludge treatment, chemical instruments and methods, etc., can solve problems such as ignorance of tannin extract, improve dehydration and drying performance, and reduce biological Utilization, the effect of avoiding secondary pollution

Active Publication Date: 2021-09-14
FUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The above invention patents only focus on the role of tannin extract in improving the dewatering performance of sludge, but do not realize that tannin extract with polyphenolic hydroxyl structure can inhibit the formation of malodorous substances in sludge, and has a certain potential for deodorization of sludge
On the other hand, ammonia, hydrogen sulfide, methyl mercaptan, methyl sulfide, carbon disulfide and other odors will still appear in the sludge treated by the technical method of the above-mentioned invention patent application in the subsequent resource utilization process such as incineration, pyrolysis or carbonization. The problem of toxic and harmful substances such as odor gas and dioxin needs to be properly resolved

Method used

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  • Method for removing sludge odor through cooperation of metal salt and tannin extract, deodorized sludge and application of deodorized sludge
  • Method for removing sludge odor through cooperation of metal salt and tannin extract, deodorized sludge and application of deodorized sludge
  • Method for removing sludge odor through cooperation of metal salt and tannin extract, deodorized sludge and application of deodorized sludge

Examples

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Effect test

Embodiment 1

[0038] This embodiment provides a method for metal salts to cooperate with tannin extract to remove sludge odor, which includes the following specific steps:

[0039] First, put 9320 parts of deodorized sludge from domestic sewage into the stirring device, control the reaction temperature at 25°C, then add 100 parts of metal salt treatment solution, turn on the stirrer and stir for 1 hour at a speed of 120r / min to make it well mixed. Then mix 500 parts of tannin extract treatment solution with 80 parts of pH regulator and add it into the stirring device, control the pH to 6.2 and stir at a speed of 120r / min for 3 hours, and after standing for 12 hours, the odor in the sludge can be effectively removed . In this embodiment, the metal salt treatment solution is an aqueous solution of ferrous sulfate with a mass percentage of 2.5%, the tannin extract treatment solution is an aqueous solution of bayberry extract with a mass percentage of 50%, and the pH regulator is a mass percen...

Embodiment 2

[0041] This embodiment provides a method for metal salts to cooperate with tannin extract to remove sludge odor, which includes the following specific steps:

[0042] First, put 9910 parts of deodorized sludge from industrial wastewater into the stirring device, control the reaction temperature at 60°C, then add 20 parts of metal salt treatment solution, turn on the stirrer and stir at a speed of 15r / min for 1h to make it well mixed. Then mix 50 parts of tannin extract treatment solution with 20 parts of pH regulator and add it into the stirring device, control the pH to 7.5 and stir at a speed of 15r / min for 2 hours, after standing for 12 hours, the odor in the sludge can be effectively removed . In this embodiment, the metal salt treatment solution is an aqueous aluminum sulfate solution with a mass percentage of 0.5%, the tannin extract treatment solution is an aqueous solution of bayberry extract with a mass percentage of 5%, and the pH regulator is a mass percentage of ...

Embodiment 3

[0044] This embodiment provides a method for metal salts to cooperate with tannin extract to remove sludge odor, which includes the following specific steps:

[0045] First put 9780 parts of deodorized sludge from urban sewage treatment plants into the stirring device, control the reaction temperature at 40°C, then add 100 parts of metal salt treatment solution, turn on the stirrer and stir at a speed of 90r / min for 1h, Mix it well. Then mix 100 parts of tannin extract treatment solution with 20 parts of pH regulator and add it into the stirring device, control the pH to 7.5 and stir at a speed of 90r / min for 2 hours, after standing for 12 hours, the odor in the sludge can be effectively removed . In this embodiment, the metal salt treatment solution is an aqueous solution of ferrous sulfate with a mass percentage of 2.5%, the tannin extract treatment solution is an aqueous solution of bayberry extract with a mass percentage of 10%, and the pH regulator is a mass percent It ...

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Abstract

The invention belongs to the technical field of sludge treatment, and particularly relates to a method for removing sludge odor through cooperation of metal salt and tannin extract, deodorized sludge and application of the deodorized sludge. The invention provides a sludge deodorization technology which is high in treatment efficiency, environment-friendly, low in investment cost and capable of meeting the harmless requirements of resource utilization such as subsequent incineration, pyrolysis or carbonization. The tannin extract is used as a multi-group ligand to be subjected to complex reaction with metal ions by utilizing the characteristic that the tannin extract contains rich phenolic hydroxyl groups, so that the bioavailability of protein and other macromolecules is reduced, the generation of low-volatility sulfides is effectively inhibited, and the stink generated in the two processes of sludge standing and combustion is remarkably removed. The whole deodorization process flow is simple and feasible, the operation is flexible, complicated and harsh reaction conditions and expensive instruments and equipment are not needed, the operation cost is low, and the method can be used as a matched pretreatment technology for resource utilization such as sludge incineration, pyrolysis or carbonization and the like.

Description

technical field [0001] The invention belongs to the technical field of sludge treatment, and more specifically relates to a method for deodorizing sludge with metal salt and tannin extract, deodorized sludge and application thereof. Background technique [0002] Sludge is an inevitable product of sewage treatment plants in the process of treating domestic and industrial wastewater. It is characterized by a large amount of production and complex components, containing a large number of pathogenic microorganisms, heavy metals and organic substances, and is easy to rot and smell. Sludge that has not been properly and safely treated will easily cause harm to the soil, water sources, and even the human body through the food chain after it re-enters the environment. Moreover, proper and reasonable treatment and utilization of sludge can make it "turn waste into treasure" and generate huge Ecological, economical and social benefits. At present, the use of concentration, digestion,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F11/00C02F11/147
CPCC02F11/00C02F11/147C02F2303/02Y02A50/20C02F11/148
Inventor 刘明华林剑涛姜疏雨杨宇川周郁欣刘以凡
Owner FUZHOU UNIV
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