Silicon carbide crystal, seed crystal used by silicon carbide crystal and preparation method of seed crystal

A technology of silicon carbide seeds and silicon carbide single crystals, which is applied in chemical instruments and methods, crystal growth, and from chemically reactive gases, etc., can solve the problem of difficulty in obtaining high-quality seed wafers, long cycle times, and difficulty in ensuring silicon carbide crystals Quality and other issues

Active Publication Date: 2021-09-14
SICC CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the unbalanced ratio of growth materials in the above-mentioned seed crystal, it is difficult to obtain high-quality seed crystal wafers without macroscopic defects, and the efficiency is low. Each crystal ingot can only obtain one seed crystal; Optimizing the seed crystal growth on the a-plane, the cycle is very long and there are too many coupling factors in the growth process, so it is difficult to obtain high-quality seed crystals
[0005] In addition, due to the uncontrollable atomic step density of traditional seed crystals, defects such as polymorphism and dislocations are prone to occur during the growth process, and it is difficult to guarantee the quality of the subsequent growth of silicon carbide crystals

Method used

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  • Silicon carbide crystal, seed crystal used by silicon carbide crystal and preparation method of seed crystal
  • Silicon carbide crystal, seed crystal used by silicon carbide crystal and preparation method of seed crystal
  • Silicon carbide crystal, seed crystal used by silicon carbide crystal and preparation method of seed crystal

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0086] refer to figure 1 , the present embodiment provides a preparation device for improving the quality of seed crystals, which includes: a processing chamber 11, a heating unit 12 and a loading unit; wherein, a crucible 13 is provided in the processing chamber 11, and the crucible 13 is used to hold raw materials The heating unit 12 is arranged on the periphery of the crucible 13, and is used to melt the raw material into a molten state component 14 and sublimate to the seed crystal 1, so as to repair or reconstruct the atomic steps of the seed crystal growth surface; the upper edge of the heating unit 12 does not exceed the melting The liquid level of the component 14 in the molten state; By arranging the upper edge of the heating unit 12 not to exceed the liquid level of the molten component 14, it is avoided that the heating unit 12 heats the area between the liquid level of the molten component 14 and the seed crystal 1, thereby ensuring the liquid level of the molten c...

Embodiment 2

[0133] The preparation of embodiment 2 seed crystals

[0134] refer to Figure 1~3 According to an embodiment of the present application, a method for preparing a seed crystal 1 using the device of Example 1 includes the following steps:

[0135] 1) Loading: fix the seed crystal to be processed above the crucible, fill the crucible with raw materials, and place the seed crystal 1 and the crucible in the crystal processing chamber;

[0136] 2) Impurity removal: pump the pressure in the crystal processing chamber to 10 -6 Below mbar, pass inert gas to 300~500mbar, repeat this process at least twice;

[0137] 3) Preheating the seed crystal: pump the pressure in the crystal processing chamber to 10 -6 Below mbar, heat the raw materials in the crucible to melt the raw materials to form molten components, adjust the distance between the growth surface of the seed crystal and the liquid surface of the molten components to 10-100 mm, and preheat for 30-120 minutes;

[0138] 4) Ste...

Embodiment 3

[0146] The characterization of embodiment 3 seed crystal

[0147] The seed crystal prepared in Example 2 was characterized, and its scratch condition, step state, doping element doping concentration, TTV value, BOW value, Warp value and defect density were tested. The test results are shown in Table 2, wherein the doping The elements are reactive elements other than carbon and silicon.

[0148] Table 2

[0149]

[0150]

[0151]

[0152] It can be seen from the above table that through the adjustment and combination of various conditions in this embodiment, the repair and reconstruction of the atomic steps on the growth surface of the silicon carbide seed crystal can be realized, and the state of the steps can be freely controlled; in addition, the surface of the seed crystal can also be controlled The scratch has a slight repairing effect; therefore, compared with the traditional seed crystal, the step information of the seed crystal of the present application is comp...

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Abstract

The invention discloses a silicon carbide crystal, a seed crystal used by the silicon carbide crystal and a preparation method of the seed crystal, and belongs to the technical field of semiconductor materials. The silicon carbide seed crystal comprises a first surface and a second surface opposite to the first surface, wherein the first surface and / or the second surface are / is provided with a plurality of atomic steps, the width of the atomic steps is 50-1000 nm, the height of the atomic steps is 0.02-0.5 nm, the width difference between the plurality of atomic steps is not greater than 10 nm, and / or the height difference between the plurality of atomic steps is not greater than 0.01 nm. According to the invention, the atomic steps of the silicon carbide seed crystal are uniformly arranged, and the size of each step is uniform, so that a foundation is laid for obtaining ultrahigh-quality crystals through subsequent growth.

Description

technical field [0001] The present application relates to a silicon carbide crystal, a seed crystal used therein and a method for preparing the seed crystal, belonging to the technical field of semiconductor materials. Background technique [0002] As one of the important third-generation semiconductor materials, silicon carbide crystals have excellent performance in high temperature, high frequency, high power, and radiation resistance. Silicon carbide-based devices have been widely used in military, civil, aerospace and other fields. Application is the key field of science and technology research in various countries. [0003] At present, the most widely used method for growing silicon carbide crystals is the physical vapor transport method, followed by the liquid phase method and the chemical vapor transport method. When the above-mentioned growth methods are used to prepare high-quality silicon carbide substrates, high-quality silicon carbide seed crystals are inseparab...

Claims

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Application Information

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IPC IPC(8): C30B29/36C30B23/00C30B25/00
CPCC30B29/36C30B23/00C30B25/00
Inventor 张宁杨晓俐李加林刘星高超方帅石志强刘家朋
Owner SICC CO LTD
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