Unlock instant, AI-driven research and patent intelligence for your innovation.

A kind of preparation method of high light flame retardant polypropylene material

A technology of flame-retardant polypropylene and polypropylene grafting, which is applied in the field of preparation of high-performance polymer materials, can solve the problems of poor gloss and easy burning of polypropylene, and achieve the effect of improving gloss

Active Publication Date: 2021-11-12
VIEW ELECTRONICS
View PDF5 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Aiming at the problems of easy burning and poor gloss of polypropylene, the invention provides a preparation method of high-gloss flame-retardant polypropylene material

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] (1) Add 1 g of glycidol to 200 mL of N,N-dimethylformamide, stir magnetically at room temperature for 20 min, then raise the temperature to 80 °C, then add 3 g of 9,10-dihydro-9- Oxa-10-phosphaphenanthrene-10-oxide, continue magnetic stirring until 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide is fully dissolved, continue magnetic stirring for 12 h , pour the reaction solution into a large amount of water, filter the precipitated solid, wash and dry to prepare 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide grafted glycidol.

[0018] (2) 10 parts of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide grafted glycidol, 0.05 parts of 1,3:2,4-di-p-methylbenzylidene sorbyl Alcohol, 5 parts of polypropylene grafted maleic anhydride, 0.5 parts of antioxidant and 100 parts of polypropylene were mixed with a high-speed mixer for 10 minutes, and the initial mixture was melt-blended through a twin-screw extruder at a melting temperature of 200 °C. The rotation speed of th...

Embodiment 2

[0022] (1) Add 1.5 g of glycidol to 350 mL of N,N-dimethylformamide, stir magnetically at room temperature for 40 minutes, then raise the temperature to 100 °C, then add 8 g of 9,10-dihydro-9-oxo hetero-10-phosphaphenanthrene-10-oxide, continue magnetic stirring until 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide is fully dissolved, continue magnetic stirring for 9 h, Pour the reaction solution into a large amount of water, filter the precipitated solid, wash and dry to prepare 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide grafted glycidol.

[0023] (2) 15 parts of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide grafted glycidol, 0.2 parts of 1,3:2,4-di-p-methylbenzylidene sorbyl Alcohol, 7 parts of polypropylene grafted maleic anhydride, 0.7 parts of antioxidant and 100 parts of polypropylene were mixed with a high-speed mixer for 20 minutes, and the initial mixture was melt-blended through a twin-screw extruder at a melting temperature of 230 °C. The rotation s...

Embodiment 3

[0027] (1) Add 2 g of glycidol to 500 mL of N,N-dimethylformamide, stir magnetically at room temperature for 60 min, then raise the temperature to 120 °C, then add 12 g of 9,10-dihydro-9- Oxa-10-phosphaphenanthrene-10-oxide, continue magnetic stirring until 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide is fully dissolved, continue magnetic stirring for 6 h , pour the reaction solution into a large amount of water, filter the precipitated solid, wash and dry to prepare 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide grafted glycidol.

[0028] (2) 20 parts of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide grafted glycidol, 0.4 parts of 1,3:2,4-di-p-methylbenzylidene sorbic acid Alcohol, 10 parts of polypropylene grafted maleic anhydride, 1 part of antioxidant and 100 parts of polypropylene were mixed with a high-speed mixer for 30 minutes, and the initial mixture was melt-blended through a twin-screw extruder at a melting temperature of 260 °C. The rotation speed of...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
tensile strengthaaaaaaaaaa
impact strengthaaaaaaaaaa
tensile strengthaaaaaaaaaa
Login to View More

Abstract

The invention discloses a preparation method of a high-light flame-retardant polypropylene material, which belongs to the technical field of preparation of high-performance polymer materials. The high-light flame-retardant polypropylene material is 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and glycidol, which are prepared by first reacting 9,10-dihydro-9-oxygen hetero‑10‑phosphaphenanthrene‑10‑oxide grafted glycidol, 1,3:2,4‑di-p-methylbenzylidene sorbitol, polypropylene grafted maleic anhydride, antioxidant and polypropylene After mixing, it is prepared by melt blending, extrusion and granulation. The polypropylene material prepared by the present invention has excellent flame retardancy, high gloss, good mechanical properties and strong resistance to heat and oxygen aging, and has wide application prospects in the field of electrical casings, and has high Economic value and social benefits.

Description

technical field [0001] The invention belongs to the technical field of preparation of high-performance polymer materials, and in particular relates to a preparation method of a high-light flame-retardant polypropylene material. Background technique [0002] Polypropylene is a semi-crystalline linear high polymer with a regular molecular chain structure and a crystallinity of up to 60%. It is a thermoplastic general-purpose plastic with the lowest density among existing synthetic resins. Polypropylene has good heat resistance and corrosion resistance, and the chemical composition and aggregated structure of polypropylene make it have good mechanical properties and insulation properties. The excellent properties of polypropylene make it widely used in the fields of equipment manufacturing, packaging and household appliances. However, polypropylene is a compound composed of hydrocarbon elements. The oxygen index is generally 17-18%. It is extremely flammable, and it is accompa...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/12C08L51/06C08K5/5313C08K5/053
CPCC08L23/12C08L2201/02C08L2201/22C08L2201/08C08L2203/20C08L51/06C08K5/5313C08K5/053
Inventor 蒋高建邹建康秦鹏伟
Owner VIEW ELECTRONICS