Unlock instant, AI-driven research and patent intelligence for your innovation.

A kind of battery separator material, material preparation method and battery separator

A diaphragm and vanadium battery technology, applied in the field of materials, can solve problems such as poor barrier capacity, short service life of vanadium batteries, and greater impact on battery service life, and achieve good hydrophilicity, improved service life, and improved ion selectivity Effect

Active Publication Date: 2022-07-08
SHENZHEN INST OF ADVANCED TECH
View PDF14 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the battery, the performance of the diaphragm material has a great influence on the service life of the battery. For example, in the current vanadium battery, the service life of the vanadium battery is relatively short due to the relatively poor barrier ability of the diaphragm material to vanadium ions.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of battery separator material, material preparation method and battery separator
  • A kind of battery separator material, material preparation method and battery separator
  • A kind of battery separator material, material preparation method and battery separator

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0037] The above is a specific introduction to the materials provided in the embodiments of the present application. The following can further provide a preparation method of a material, which can be used to prepare the material by dispersing the silicon carbide nanowires in the perfluorosulfonic acid solution, like figure 1 Shown is the specific flow chart of the preparation method, including the following steps:

[0038] Step S101: Dissolving the perfluorosulfonic acid resin in a mixed solution to obtain a perfluorosulfonic acid solution, the mixed solution is prepared by water and propanol in a volume ratio of 1:1.

[0039]First, the mixed solution can be prepared by using water and propanol (volume ratio of 1:1), wherein the propanol here can be n-propanol or isopropanol. After the mixed solution is prepared, the perfluorosulfonic acid resin can be put into the mixed solution, wherein the mass (unit: g) of the added perfluorosulfonic acid resin can be 0.01-0.1 of the volu...

Embodiment 1

[0054] 1.1. Functionalization of SiC nanowires

[0055] The unfunctionalized silicon carbide nanowires were put into a mixed solution of sulfuric acid and methanol with a concentration of 1 mol / L, wherein the mass of the silicon carbide nanowires put in was 0.02 times the volume of the mixed solution of sulfuric acid and methanol. The reaction was then refluxed for 24 hours under the conditions of 110 degrees Celsius and a stirring speed of 1000 rpm. After the reflux reaction, the reaction product was washed with deionized water until the pH value was neutral, and then the reaction product was dried in an oven at 100 degrees Celsius for 24 hours, and the obtained gray-black powder was functionalized silicon carbide nanowires.

[0056] 1.2. Preparation of perfluorosulfonic acid solution

[0057] Prepare a mixed solution of deionized water and n-propanol in a volume ratio of 1:1, and then add a perfluorosulfonic acid resin to the mixed solution, wherein the mass of the added pe...

Embodiment 2

[0066] In this Example 2, the functionalization of the silicon carbide nanowires and the preparation of the perfluorosulfonic acid solution are the same as those in the Example 1, and the difference lies in the material preparation and the preparation steps of the battery separator.

[0067] In the preparation steps of the material preparation and battery separator of this embodiment 2:

[0068] According to the mass ratio of silicon carbide nanowires to perfluorosulfonic acid is 1:200, weigh the above-mentioned functionalized silicon carbide nanowires and perfluorosulfonic acid solution, and weigh the functionalized silicon carbide nanowires. line, added to the weighed perfluorosulfonic acid solution, and then dispersed by ultrasonic vibration, thereby obtaining the material 2 provided by the embodiment of the application;

[0069] The above-mentioned material 2 is evenly coated on a clean polyimide film substrate, and then the coating of the above-mentioned material 2 is cov...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
diameteraaaaaaaaaa
thicknessaaaaaaaaaa
thicknessaaaaaaaaaa
Login to View More

Abstract

The present application discloses a material for a battery separator, a material preparation method and a battery separator. The material for the battery separator includes silicon carbide nanowires and perfluorosulfonic acid, wherein the mass ratio of the silicon carbide nanowires and the perfluorosulfonic acid is 1:5 to 1:200. Because silicon carbide nanowires have the advantages of high dispersibility, good hydrophilicity, etc., and the surface of functionalized silicon carbide nanowires contains active groups such as sulfonic acid groups and hydroxyl groups, and has high proton conductivity, it can be used on the molecular scale. The size of the proton transfer channel is regulated, so that while realizing the rapid conduction of protons, it can also block the conduction of relatively large vanadium ions and other metal ions, thereby improving the service life of the battery.

Description

technical field [0001] The present application relates to the technical field of materials, and in particular, to a material for a battery separator, a material preparation method and a battery separator. Background technique [0002] With the continuous development of science and technology, more and more devices need to be powered by batteries, so higher requirements are placed on the service life of batteries. In the battery, the performance of the separator material has a great influence on the service life of the battery. For example, in the current vanadium battery, the service life of the vanadium battery is short due to the relatively poor barrier ability of the separator material to vanadium ions. SUMMARY OF THE INVENTION [0003] The embodiments of the present application provide a material for a battery separator, a method for preparing the material, and a battery separator, which are used to solve the problems in the prior art. [0004] The embodiment of the p...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): H01M8/0226H01M8/18B82Y30/00B82Y40/00
CPCH01M8/0226H01M8/188B82Y30/00B82Y40/00Y02E60/50Y02E60/10
Inventor 叶家业郑春花李慧云张翼滉刘艳琳
Owner SHENZHEN INST OF ADVANCED TECH