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Electrochemical device and electronic device comprising same

An electrochemical and electrode assembly technology, applied in the field of electrochemistry, can solve problems such as unfavorable energy density of lithium-ion batteries, safety risks of lithium-ion batteries, and corrosion reactions, so as to reduce the risk of corrosion reactions, improve anti-corrosion performance, and improve The effect of energy density

Pending Publication Date: 2021-11-26
NINGDE AMPEREX TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, when the case is exposed to the electrolyte environment and contacts the negative electrode tab inside the lithium-ion battery, a corrosion reaction occurs, which in turn leads to a risk of liquid leakage from the case
Moreover, Al enters the inside of the electrode assembly and deposits between the positive and negative plates and the separator, which can easily lead to safety risks for lithium-ion batteries.
[0003] In order to prevent the above problems from occurring, in the prior art, the distance between the negative pole piece and the casing is generally designed to be relatively far away at the position where the lithium-ion battery structure may have a corrosion risk, and an insulator is provided on the casing or outside the electrode assembly. Protection, which is not conducive to the improvement of the energy density of lithium-ion batteries

Method used

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Examples

Experimental program
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preparation example Construction

[0096] The present application has no special limitation on the preparation process of the electrochemical device, as long as the purpose of the present application can be achieved. For example, an electrochemical device can be prepared by the following process: overlap the positive pole piece and the negative pole piece through a separator, and put it into the casing after winding or folding as required, inject the electrolyte into the casing and seal it; Alternatively, the negative pole piece and the positive pole piece are stacked through separators to form a stack, and then the four corners of the entire stack structure are fixed with adhesive tape, placed in an aluminum shell, and the electrolyte is injected into the shell and sealed to obtain electrochemical device. In addition, anti-overcurrent elements, guide plates, etc. can also be placed in the casing as needed, so as to prevent pressure rise and overcharge and discharge inside the electrochemical device.

[0097] ...

Embodiment 1

[0114]

[0115] Mix the first negative electrode active material, conductive carbon black (Super P), and styrene-butadiene rubber (SBR) in a weight ratio of 96:1.5:2.5, and then add deionized water as a solvent to prepare the first negative electrode active material with a solid content of 70%. paste, and stir well. The second negative electrode active material, Super P, and SBR were mixed according to a weight ratio of 96:1.5:2.5, and then deionized water was added as a solvent to prepare a second slurry with a solid content of 70%, and stirred evenly. The first slurry is evenly coated on the first coating area of ​​the negative electrode current collector copper foil with a thickness of 8 μm, the second slurry is evenly coated on the second coating area, and dried at 110 ° C to obtain A negative electrode sheet coated with a negative active material on one side with a coating thickness of 130 μm. After the above steps are completed, the single-side coating of the negative...

Embodiment 16

[0125]

[0126] Except that the negative electrode sheet was cut into a specification of 41 mm×61 mm, the rest was the same as that of Example 1.

[0127]

[0128] Except that the positive pole piece was cut into a specification of 38 mm×58 mm, the rest was the same as that of the embodiment 1.

[0129] and are the same as in Example 1.

[0130]

[0131] Stack the positive pole piece, separator, and negative pole piece prepared above to form a laminate, so that the separator is in the middle of the positive pole piece and the negative pole piece to play the role of isolation, and then use tape to fix the four corners of the entire laminated structure. Get the electrode assembly. Put the electrode assembly into the aluminum-plastic film casing, remove the moisture at 80°C, inject the prepared electrolyte, and obtain the lithium-ion battery through the processes of vacuum packaging, standing, forming, and shaping.

[0132] Example 2 to Example 15, Comparative Example 1...

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Abstract

According to an electrochemical device and an electronic device comprising the electrochemical device provided by the embodiment of the invention, in the electrochemical device, a first negative electrode active material is coated on the part, possibly in contact with a shell and corroded, in a negative electrode current collector, so that the risk of lithium intercalation corrosion reaction caused by contact between the shell and the negative electrode pole piece can be reduced; therefore, the anti-corrosion performance of the electrochemical device is effectively improved, and the safety performance is improved. Due to the existence of the first coating area, the risk of corrosion reaction caused by contact between the shell and the negative pole piece is reduced, on one hand, the use of an insulating part can be omitted, and on the other hand, the distance between the shell and the negative pole piece can be reduced, so that the volume of the electrochemical device is reduced; therefore, the energy density of the electrochemical device is improved, and the production cost of the electrochemical device is reduced.

Description

technical field [0001] The present application relates to the field of electrochemistry, in particular to an electrochemical device and an electronic device including the electrochemical device. Background technique [0002] Aluminum element (Al) has the advantages of high ductility, easy processing, and low cost. Large-sized lithium-ion batteries usually use a material containing a large amount of Al compound as the shell. However, when the casing is exposed to the electrolyte environment and contacts the negative electrode tab inside the lithium-ion battery, a corrosion reaction will occur, which in turn leads to the risk of leakage of the casing. Moreover, Al enters the interior of the electrode assembly and deposits between the positive and negative electrodes and the separator, which can easily lead to safety risks for lithium-ion batteries. [0003] In order to prevent the above problems from occurring, in the prior art, the distance between the negative pole piece an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M50/145H01M4/64H01M4/36H01M10/0525
CPCH01M50/145H01M4/36H01M4/64H01M2004/027H01M10/0525Y02E60/10
Inventor 闫东阳
Owner NINGDE AMPEREX TECH