Preparation method of super-hydrophobic anti-fouling and anti-drag material

A super-hydrophobic and anti-fouling technology, applied in metal material coating process, liquid chemical plating, superimposed layer plating, etc. State and other problems, to achieve the effect of reducing biological adhesion, reducing the contact area, and broad application prospects

Active Publication Date: 2022-01-21
725TH RES INST OF CHINA SHIPBUILDING INDAL CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006]The above patents all belong to superhydrophobic materials, but the types of materials and preparation methods are very different, and the structure is often relatively simple, so it is difficult to directly use them as antifouling and drag reducing materials. Moreover, it is difficult to maintain the superhydrophobic state for a long time in the underwater environment.

Method used

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  • Preparation method of super-hydrophobic anti-fouling and anti-drag material
  • Preparation method of super-hydrophobic anti-fouling and anti-drag material
  • Preparation method of super-hydrophobic anti-fouling and anti-drag material

Examples

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Effect test

Embodiment 1

[0038] The process of the super-hydrophobic anti-fouling and drag-reducing material involved in the present invention includes three steps of preparing a bionic "claw-shaped" structure substrate, preparing a multi-level structure and preparing a super-hydrophobic anti-fouling and drag-reducing material:

[0039] (1) Preparation of biomimetic "claw" structure matrix

[0040] Using ABS resin as raw material, use a 3D printer to print a number of bionic "claw-shaped" structural substrates that combine microstructure monomers arranged in an equilateral triangular lattice with a base, and the distance between any two adjacent microstructure monomers Both are 3000μm;

[0041] The microstructure monomer is divided into upper and lower parts, the lower part is a cylinder, and the upper part is a "claw-shaped" structure composed of four oblique cylinders with different directions. The bottom of the cylinder is connected to the base. The top is connected to the "claw" structure. The di...

Embodiment 2

[0049] This example relates to the surface wettability test of the super-hydrophobic anti-fouling and drag-reducing material prepared in Example 1. Using running water to wash the surface of the super-hydrophobic, anti-fouling and drag-reducing material, it can be seen that no water drops remain on the surface of the super-hydrophobic, anti-fouling and drag-reducing material , indicating that the super-hydrophobic anti-fouling and drag-reducing material has a small rolling angle and a large water contact angle; when the super-hydrophobic anti-fouling and drag-reducing material is placed in water, the surface of the super-hydrophobic anti-fouling and drag-reducing material can be clearly seen It has a layer of silver-white light film, which is the underwater air layer of the super-hydrophobic anti-fouling and drag-reducing material, which shows that the super-hydrophobic anti-fouling and drag-reducing material itself has super-hydrophobic properties.

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Abstract

The invention belongs to the technical field of marine anti-fouling and anti-drag materials, and relates to a preparation method of a super-hydrophobic anti-fouling and anti-drag material with a bionic multilevel structure. The structure and the size of the super-hydrophobic anti-fouling and anti-drag material are designed by referring to the microstructure of the blade surface of a bionic salvinia natans. The preparation method comprises the following steps of firstly, preparing a bionic claw-shaped structure matrix by adopting a high polymer raw material such as resin or rubber through a method comprising 3D micro-nano printing, template imprinting, precision machining, precision micro-electroforming and precision micro-electrolysis, then metallizing the surface of the matrix by using a chemical plating and electrodeposition combined method and forming a millimeter-micron-nanometer multi-stage structure, and finally, using a long-chain alkanoic acid soaking method to achieve the hydrophobic property. The process is simple, the raw materials are easily available, the material can be used for the outer surfaces of marine hulls, underwater vehicles and the like, and the micro-nano structure and the hydrophobicity of the long-chain alkanoic acid jointly act so as to form the air layer in water, such that the super-hydrophobic effect is achieved, and the anti-fouling and anti-drag functions are further achieved.

Description

Technical field: [0001] The invention belongs to the technical field of marine anti-fouling and drag-reducing materials, and specifically relates to a method for preparing a super-hydrophobic anti-fouling and drag-reducing material with a bionic multi-level structure, and prepares "nano-nano" super-hydrophobic and anti-fouling materials based on the microscopic structure of the leaf surface of the leaf. drag reducing material. Background technique: [0002] Marine ships are faced with the problems of biofouling and underwater frictional resistance. Antifouling and drag reduction treatment on the hull surface is an important measure to avoid biofouling hazards and save fuel consumption. Superhydrophobic materials are an important direction for the development of anti-fouling and drag-reducing materials. In the 1970s, after the self-cleaning superhydrophobic effect on the surface of lotus leaves was discovered, superhydrophobic materials gradually entered the field of vision ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J7/00C08L55/02C23C18/20C23C18/40C23C28/02C25D3/38C25D5/02
CPCC08J7/00C23C18/405C23C18/2086C25D5/02C25D3/38C23C28/023C08J2355/02Y02T70/10
Inventor 郑纪勇杨兴杰蔺存国张金伟邱峥辉孙智勇
Owner 725TH RES INST OF CHINA SHIPBUILDING INDAL CORP
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