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Flexible stretchable electrode and preparation method and application thereof

An electrode and flexible technology, applied in the field of flexible stretchable electrodes and their preparation, can solve problems such as changes in the electrical conductivity of flexible electrodes, and achieve the effect of maintaining stable electrical conductivity and maintaining integrity

Pending Publication Date: 2022-01-28
SHENZHEN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] In view of the above deficiencies in the prior art, the purpose of the present invention is to provide a flexible stretchable electrode and its preparation method and application, aiming to solve the problem that the electrical conductivity of the existing flexible electrode will change greatly during the stretching process

Method used

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  • Flexible stretchable electrode and preparation method and application thereof
  • Flexible stretchable electrode and preparation method and application thereof
  • Flexible stretchable electrode and preparation method and application thereof

Examples

Experimental program
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Embodiment approach

[0043] In one embodiment, the material of the organic polymer layer is selected from the group consisting of styrene-ethylene-butylene-styrene block copolymer, polyimide, polydimethylsiloxane, polyvinylidene fluoride, poly One or more of tetrafluoroethylene, but not limited thereto.

[0044] In one embodiment, the conductive nanosheet is a single-sheet structure or a multi-sheet structure, and the single-sheet area of ​​the conductive nanosheet is 10 4 -10 7 nm 2 , the monolithic thickness is 10-100nm.

[0045] In one embodiment, the metal nanowires have a diameter of 50-100 nm and a length of 10-30 μm.

[0046] In one embodiment, the conductive nanosheet is a single-sheet structure or a multi-sheet structure, and the single-sheet area of ​​the conductive nanosheet is 10 4 -10 7 nm 2 , the thickness of a single sheet is 10-100nm, the diameter of the metal nanowire is 50-100nm, and the length is 10-30μm. This embodiment can make the conductive nodes in the three-dimensio...

Embodiment 1

[0101] (1) Preparation of flexible and stretchable electrodes

[0102] Silicon wafer cleaning: Scrub a 15mm×14mm silicon wafer with absolute ethanol, then put it into deionized water for ultrasonic cleaning for 10 minutes, then blow dry the residual ethanol on the silicon wafer with nitrogen, and then put it in acetone After performing ultrasonic cleaning for 10 minutes, dry the residual acetone on the silicon wafer with nitrogen gas. Finally, put it into isopropanol for ultrasonic cleaning for 10 min, and then use nitrogen gas to dry the residual isopropanol on the silicon wafer.

[0103] The preparation of mixed solution: with 4mg graphite powder nanosheet (its SEM picture is as follows image 3 As shown, it can be seen that it has a lamellar structure) was added to 4mL of deionized water, and the first ultrasonic crushing and the second ultrasonic crushing were carried out successively with a power of 400W in the ultrasonic cell pulverizer, and the first ultrasonic pulveriz...

Embodiment 2

[0112] (1) Preparation of flexible and stretchable electrodes

[0113] Different from Example 1, the concentration ratio of graphite powder nanosheets and silver nanowires in the mixed solution is 1:0.8, that is, the addition of graphite powder nanosheets is 4mg, the addition of silver nanowires is 3.2mg, and the rest Step is identical with embodiment 1.

[0114] (2) Stress tensile performance test

[0115] The stress-stretching performance of the flexible stretchable electrode was tested by using a precision electric translation stage and a two-phase stepping motor controller, and the resistance change of the flexible stretchable electrode was measured by a digital power meter. The resistance change diagram of the flexible stretchable electrode electrode under 0%-40% stress stretching is as follows Figure 7 As shown, the horizontal axis is the stress stretching Strain, ranging from 0% to 40%, and the vertical axis is the resistance value Resistance of the flexible stretcha...

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Abstract

The invention discloses a flexible stretchable electrode and a preparation method and application thereof, the flexible stretchable electrode comprises an organic polymer layer, conductive nanosheets and metal nanowires, the conductive nanosheets and the metal nanowires are dispersed in a surface layer of the organic polymer layer, and the conductive nanosheets and the metal nanowires form a three-dimensional interpenetrating network structure. The flexible stretchable electrode provided by the invention has the characteristics of flexibility, high conductivity and high tensile property at the same time, and can still keep high conductivity without obvious change in conductivity in a tensile state. The flexible stretchable electrode provided by the invention not only can be used for preparing a high-conductivity and high-stretching electrode of a wearable flexible electronic circuit, but also can be used for preparing various physiological electric signal acquisition electrodes.

Description

technical field [0001] The invention relates to the field of electrode materials, in particular to a flexible and stretchable electrode and its preparation method and application. Background technique [0002] In the field of electrode materials, electrodes with flexible and stretchable properties are an important driving force for the development of wearable and flexible electronics, and are favored in the application of various flexible wearable devices. important part of. In wearable flexible electronic circuit systems, flexible and stretchable electrodes can meet the needs of high conductivity in the circuit, and the flexible and stretchable electrodes will stretch as the skin stretches, and the flexible and stretchable electrodes maintain conductivity during the stretching process Stable, to achieve continuous and stable work of wearable electronic devices in the state of tissue movement; in the monitoring and collection of physiological electrical signals, flexible an...

Claims

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Application Information

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IPC IPC(8): H01B5/14H01B1/22H01B1/24H01B13/00H01B13/30A61B5/00A61B5/256
CPCH01B5/14H01B1/22H01B1/24H01B13/0026H01B13/0016H01B13/30A61B5/6802A61B5/256
Inventor 徐海华胡斌来金春阳刘国铿张利华曾国正
Owner SHENZHEN UNIV