Preparation method of high-content carbon black master batch

A carbon black masterbatch, high-content technology, applied in chemical instruments and methods, dyeing polymer organic compound treatment, compounds of group 5/15 elements of the periodic table, etc., can solve the problem of low carbon black content, masterbatch flame retardancy Poor effect and aging resistance

Active Publication Date: 2022-02-01
广东九彩新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to provide a method for preparing high-content carbon black master batches, which solves the problem of low carbon black content of carbon black master batches at the present stage and the flame retardant effect of the master batches by modified polystyrene and modified carbon black particles. and the problem of poor aging resistance

Method used

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  • Preparation method of high-content carbon black master batch
  • Preparation method of high-content carbon black master batch
  • Preparation method of high-content carbon black master batch

Examples

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Comparison scheme
Effect test

Embodiment 1

[0044] A kind of preparation method of high-content carbon black masterbatch, specifically comprises the steps:

[0045] Step S1: weighing 100 parts of raw material modified polystyrene, 600 parts of modified carbon black particles, 2 parts of liquid paraffin, 10 parts of graphite, 3 parts of kaolin powder, and 5 parts of sodium dodecylbenzenesulfonate;

[0046] Step S2: Dissolve modified polystyrene in N,N-dimethylformamide, add modified carbon black particles and triethylamine, and carry out the reaction at a speed of 300r / min and a temperature of 80°C After 5h, the solvent was distilled off to obtain the substrate;

[0047] Step S3: After mixing the substrate, liquid paraffin, graphite, kaolin powder, and sodium dodecylbenzenesulfonate evenly, add it to the extruder at the temperature of 190, 205, 215, 220, and 215°C in each section , extruded, cooled and granulated to produce high-content carbon black masterbatches.

[0048] Described modified polystyrene is made by foll...

Embodiment 2

[0058] A kind of preparation method of high-content carbon black masterbatch, specifically comprises the steps:

[0059] Step S1: weighing 130 parts of raw materials modified polystyrene, 700 parts of modified carbon black particles, 3 parts of liquid paraffin, 13 parts of graphite, 5 parts of kaolin powder, and 7 parts of sodium dodecylbenzenesulfonate;

[0060] Step S2: Dissolve the modified polystyrene in N,N-dimethylformamide, add modified carbon black particles and triethylamine, and carry out the reaction at a speed of 400r / min and a temperature of 85°C After 6h, the solvent was distilled off to obtain the substrate;

[0061] Step S3: After mixing the substrate, liquid paraffin, graphite, kaolin powder, and sodium dodecylbenzenesulfonate evenly, add it to the extruder at the temperature of 190, 205, 215, 220, and 215°C in each section , extruded, cooled and granulated to produce high-content carbon black masterbatches.

[0062] Described modified polystyrene is made by...

Embodiment 3

[0072] A kind of preparation method of high-content carbon black masterbatch, specifically comprises the steps:

[0073] Step S1: weighing 150 parts of raw materials modified polystyrene, 800 parts of modified carbon black particles, 5 parts of liquid paraffin, 15 parts of graphite, 8 parts of kaolin powder, and 8 parts of sodium dodecylbenzenesulfonate;

[0074] Step S2: Dissolve the modified polystyrene in N,N-dimethylformamide, add modified carbon black particles and triethylamine, and carry out the reaction at a speed of 500r / min and a temperature of 90°C After 7h, the solvent was removed by distillation to obtain the substrate;

[0075] Step S3: After mixing the substrate, liquid paraffin, graphite, kaolin powder, and sodium dodecylbenzenesulfonate evenly, add it to the extruder at the temperature of 190, 205, 215, 220, and 215°C in each section , extruded, cooled and granulated to produce high-content carbon black masterbatches.

[0076] Described modified polystyrene ...

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Abstract

The invention discloses a preparation method of a high-content carbon black master batch. According to the method, modified polystyrene reacts with modified carbon black particles, and then melting and extruding are conducted with liquid paraffin, graphite, kaolin powder and sodium dodecyl benzene sulfonate; and modified polystyrene is dissolved in N,N-dimethylformamide to react with modified carbon black particles, so that chlorine atom sites on the modified carbon black particles are subjected to cross-linking reaction with the modified polystyrene, thereby ensuring that the modified carbon black particles are stably attached to the modified polystyrene and do not fall off when the content of the carbon black is increased. The surface of the modified carbon black particle is grafted with an oxyacid structure containing phosphorus in molecules, a continuous and compact carbon layer can be formed on the surface when the carbon black master batch is combusted, heat and oxygen can be isolated, smoke and molten drops can be inhibited, and phenothiazine structures in the molecules further improve the anti-aging performance of the carbon black master batch.

Description

technical field [0001] The invention relates to the technical field of polymer material preparation, in particular to a method for preparing a high-content carbon black masterbatch. Background technique [0002] Carbon black is widely used in plastic products due to its good light resistance, heat resistance and antistatic properties. In the application of plastic products, compared with adding carbon black directly, the carbon black masterbatch with plastic as the carrier can be better dispersed in the plastic. The blackness of carbon black masterbatch is directly related to the particle size of carbon black, the smaller the particle size, the larger the specific surface area, and the higher the blackness of carbon black. This is because although the primary particles have been fused into primary aggregates, their specific surface can still function. The finer the primary carbon black particles, the larger the specific surface area of ​​the aggregate, the darker the color,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09C1/56C09C3/06C09C3/10C07F9/6558
CPCC09C1/56C09C3/06C09C3/006C09C3/10C07F9/65583Y02E60/10
Inventor 林文丹曹畅崔永哲
Owner 广东九彩新材料有限公司
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