Organic compound and organic electroluminescent device containing same
An organic compound, selected technology, applied in the direction of organic chemistry, electrical solid devices, electrical components, etc., to achieve the effects of small molecular force, performance improvement, and excellent thermodynamic stability
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[0050] It should be understood that the specific embodiments described here are only used to illustrate and explain the present invention, and are not intended to limit the present invention.
[0051] Synthesis Example 1: Synthesis of Compound (5)
[0052] S1: In the reactor, put 2-bromo-1,1'-biphenyl (18.65g, 80mmol), according to the weight of 2-bromo-1,1'-biphenyl, add 10 times the volume of tetrahydrofuran to dissolve , pass through nitrogen protection, cool down to -80 °C, add 35.2 mL of 2.5M / L n-butyl solution dropwise, and add 3-chloro-5-fluorobenzophenone (18.77 g, 80 mmol) after constant temperature reaction for 0.5 h , warming up to room temperature and reacting for 0.5h, adding dilute hydrochloric acid to quench the reaction, separating the liquids, extracting the aqueous phase with tetrahydrofuran, combining with the organic phase and concentrating to obtain 24.89g of the intermediate shown in the following formula (5a), with a yield of 80% ;
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