Unlock instant, AI-driven research and patent intelligence for your innovation.

Method for pretreating ardealite, ardealite crude product and recycled product

A phosphogypsum and pretreatment technology, applied in chemical instruments and methods, inorganic chemistry, calcium/strontium/barium sulfate, etc., can solve the problems of high energy consumption, high cost, unfriendly environment, etc., and achieve low energy consumption, The effect of low cost and low labor cost

Active Publication Date: 2022-04-22
中国建筑材料工业规划研究院
View PDF4 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The object of the present invention is to overcome the problems of high cost, high energy consumption and unfriendly environment in the existing phosphogypsum pretreatment method, and provide a pretreatment Process for phosphogypsum and crude and recycled products of phosphogypsum obtained after this pretreatment

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] Place 1 ton of phosphogypsum in the drying room, continuously heat the phosphogypsum, and monitor the temperature, humidity and vapor pressure in the environment to perform the following process:

[0056] (1) Initial stage: In a closed environment, during the process of gradually rising temperature, the water in phosphogypsum enters the air, the ambient humidity increases, and the vapor pressure increases; the vapor pressure gradually reaches saturation, and the temperature of the system is 71°C. Humidity is 89%, reach the first condition, after maintaining for 5 minutes, proceed to the next step;

[0057] (2) The second dynamic environment stage: the airtight environment is released, the steam is discharged through the pipeline and condensed and collected, the steam pressure in the drying chamber drops, and the humidity drops; when the temperature is 90°C and the humidity reaches 71%, it is determined that the second condition is met ;Proceed to the next step;

[0058...

Embodiment 2

[0063] Place 1 ton of phosphogypsum in the drying room, continuously heat the phosphogypsum, and monitor the temperature, humidity and vapor pressure in the drying room at the same time, and perform the following process:

[0064] (1) Initial stage: In a closed environment, in the process of gradually rising temperature, the water in phosphogypsum enters the air, the ambient humidity increases, and the vapor pressure increases; the vapor pressure gradually reaches saturation, and the temperature of the system is 68°C. Humidity is 92%, reach the first condition, after maintaining for 7 minutes, proceed to the next step;

[0065] (2) The second dynamic environment stage: the airtight environment is released, the steam is discharged through the pipeline and condensed and collected, the steam pressure in the drying chamber drops, and the humidity drops; when the temperature is 88°C and the humidity reaches 72%, it is determined that the second condition is met ;Proceed to the next...

Embodiment 3

[0071] According to the method of Example 1, the difference is that in the first dynamic environment stage, instead of maintaining a period of time under the saturated vapor pressure environment, it will be exposed to a closed environment once the saturated vapor pressure is reached.

[0072] Other operations were the same as in Example 1, and after about 1h5min, the crude phosphogypsum and condensed water were finally obtained.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to the field of industrial pretreatment, in particular to a method for pretreating ardealite, a crude ardealite product and a recycled ardealite product. The pretreatment method comprises the steps that phosphogypsum is placed in a first dynamic environment and a second dynamic environment which alternately occur, the first dynamic environment is carried out in a closed environment, and switching is carried out when a first condition is met or after the first condition is maintained for a period of time; the second dynamic environment is carried out in a non-closed environment, and switching is carried out when a second condition is met; the first condition comprises that the first temperature is 60-80 DEG C, and the first humidity is 80%-98%; the second condition comprises that the second temperature is 80-98 DEG C, and the second humidity is 60-80%; the difference between the first temperature and the second temperature is not less than 10 DEG C, and the difference between the first humidity and the second humidity is not less than 10%. According to the invention, impurities and free water in phosphogypsum can be effectively removed and can be recycled, so that energy conservation and environmental protection are realized; and fresh phosphogypsum can be directly treated.

Description

technical field [0001] The invention relates to the field of industrial pretreatment, in particular to a method for pretreatment of phosphogypsum and crude phosphogypsum and recycled products obtained after the pretreatment. Background technique [0002] Phosphogypsum is a solid waste discharged during the production of phosphate fertilizer and phosphoric acid. About 4.5-5t of phosphogypsum is produced for every 1t of phosphoric acid produced. In addition to the main component calcium sulfate, phosphogypsum also contains impurities such as phosphoric acid, silicon, magnesium, iron, aluminum, and organic impurities. [0003] As for the resource utilization of phosphogypsum, neither domestic nor foreign is satisfactory. An important reason for limiting the resource utilization of phosphogypsum is that there is no cost-effective way to deal with the large amount of free water and impurities contained in phosphogypsum. The methods commonly used in the prior art to pretreat pho...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C04B11/26C04B11/032C01F11/46
CPCC04B11/26C04B11/032C01F11/468C01P2006/80
Inventor 石存兰索也兵张彦林高宁魏泽林陈蛟龙杜程李恒赵旭东罗翊伦
Owner 中国建筑材料工业规划研究院