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High-temperature-resistant chromium-free passivator for tin and tin alloy

A technology of chromium-free passivation agent and tin alloy, applied in the direction of metal material coating process, etc., can solve the problems of high temperature resistance, affecting electrical conductivity and solderability, etc. Good film appearance

Pending Publication Date: 2022-04-22
SUZHOU HIYIE CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to provide a method for preparing and using a high-temperature-resistant chromium-free passivator for tin and tin alloys, so as to overcome the disadvantages of existing tin-plated and tin-alloy passivators that are not resistant to high temperatures and affect conductivity and solderability. disadvantages

Method used

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  • High-temperature-resistant chromium-free passivator for tin and tin alloy
  • High-temperature-resistant chromium-free passivator for tin and tin alloy
  • High-temperature-resistant chromium-free passivator for tin and tin alloy

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] Example 1: (1) Add 134.75g of pure water into the container, add 8g of butyl glycol ether, and stir mechanically for 20 minutes;

[0052] (2) Add 142.5g of silicone styrene-acrylic emulsion into the container, heat up to 45°C, stir mechanically for 27min and fully cool to room temperature;

[0053] (3) 22.5g of coupling agent KH-551 after hydrolysis, mechanically stirred for 25min;

[0054] (4) Continue to add 42.5g of water-based wax emulsion, heat up to 40°C, stir mechanically for 25min and cool to room temperature;

[0055] (5) Add 10g of water-based nano antimony-doped tin dioxide and stir for 55min;

[0056] (6) Add 1g of triethanolamine, 2.5g of defoamer, 8g of leveling agent, 1.5g of wetting agent and 134.75g of pure water, and fully mechanically stir for 2 hours until the solution is fully mixed and uniform.

[0057] The above-mentioned passivating agent was prepared as a solution with a concentration of 200mL / L, and the tin-plated electronic workpiece at room...

Embodiment 2

[0058] Example 2: (1) Add 123.5g of pure water into the container, add 9g of ethylene glycol butyl ether, and stir mechanically for 20 minutes;

[0059] (2) Slowly add 150g of silicone styrene-acrylic emulsion, heat up to 40°C, stir mechanically for 30min and fully cool to room temperature;

[0060] (3) 24g of coupling agent KH-560 after hydrolysis, mechanically stirred for 25min;

[0061] (4) Continue to add 44g of water-based wax emulsion, heat up to 50°C, stir mechanically for 30min and cool to room temperature;

[0062] (5) Add 11.5g of water-based nano antimony-doped tin dioxide and stir for 55min;

[0063] (6) Add 1.5g of triethanolamine, 3g of defoamer, 8.5g of leveling agent, 1.5g of wetting agent and 123.5g of pure water, and fully mechanically stir for 2.5 hours until the solution is fully mixed and uniform.

[0064] The above-mentioned passivating agent was prepared as a solution with a concentration of 200mL / L, and the tin-plated electronic workpiece at room temp...

Embodiment 3

[0065] Example 3: (1) Add 129.5 g of pure water into the container, add 9 g of propylene glycol methyl ether acetate, and stir mechanically for 20 minutes;

[0066] (2) Slowly add 145g of silicone styrene-acrylic emulsion, heat up to 40°C, stir mechanically for 25min and fully cool to room temperature;

[0067] (3) Add 25g of hydrolyzed silane coupling agent in turn, and stir mechanically for 28min;

[0068] (4) Continue to add 45g of water-based wax emulsion, heat up to 40°C, stir mechanically for 25min and cool to room temperature;

[0069](5) Add 12.5g of water-based nano antimony-doped tin dioxide and stir for 60 minutes;

[0070] (6) Add 1.5g of triethanolamine, 2.5g of defoamer, 8g of leveling agent, 1.5g of wetting agent and 129.5g of pure water, and fully mechanically stir for 3 hours until the solution is fully mixed and uniform.

[0071] The above-mentioned passivating agent was configured into a solution with a concentration of 100mL / L, and the tin-plated electron...

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Abstract

The invention relates to a high-temperature-resistant chromium-free passivator for tin and tin alloy. The high-temperature-resistant chromium-free passivator comprises the following components: organic silicon modified acrylic resin, a coalescing agent, triethanolamine, a flatting agent, a wetting agent, a silane coupling agent, water-based wax emulsion, water-based nano antimony-doped tin dioxide (ATO) slurry, a defoaming agent, water and the like. The high-temperature-resistant chromium-free passivator for the tin and the tin alloy, provided by the invention, has the characteristics of good film forming appearance, high temperature resistance, good conductivity and strong corrosion resistance, and is an environment-friendly and efficient chromium-free passivator for the tin and the tin alloy.

Description

technical field [0001] The invention relates to a high-temperature-resistant chromium-free passivator for tin and tin alloys, which belongs to the field of electroplating surface treatment. Background technique [0002] Based on excellent ductility, corrosion resistance, electrical conductivity and solderability, tin and tin alloy coatings have become the main electroplating coatings for steel plate protection. In the field of electronics industry, taking advantage of the low melting point of tin and tin alloy metals, tin plating is often used instead of silver plating. However, tin and tin alloys are easily oxidized into tin oxide in the high temperature environment of the electronics industry, which becomes a bad conductor and seriously Affect its electrical conductivity and welding performance. [0003] Most of the post-treatment processes of tin and tin alloys use a passivation process to form a conversion film on the tin coating, which can improve the corrosion resista...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C22/68C25D5/48
CPCC23C22/68C25D5/48C23C2222/10
Inventor 徐英君赵东军孙华敏
Owner SUZHOU HIYIE CHEM CO LTD