Unlock instant, AI-driven research and patent intelligence for your innovation.

Modification of ultramicro cracked carbon black for rubber and preparation method of composite rubber

A technology of compounding rubber and pyrolysis carbon is applied in the field of rubber reinforcing filler, which can solve the problems of affecting rubber dispersion and easy agglomeration, and achieve the effect of increasing the number of parts used, low hardness and reducing dust pollution.

Active Publication Date: 2022-05-27
安徽固瑞特新材料科技有限公司
View PDF6 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, cracked carbon black is easier to agglomerate due to its higher fineness after grinding, which will also affect its dispersion in rubber

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Modification of ultramicro cracked carbon black for rubber and preparation method of composite rubber
  • Modification of ultramicro cracked carbon black for rubber and preparation method of composite rubber

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0070] The recovered waste all-steel thermal cracking coke slag is removed by a vibrating screen to remove large impurities, and then sent to the buffer bin for use after passing through the iron removal equipment. The iron-removed slag goes through the vertical mill and then goes into the coarse powder storage silo. The frequency of the vertical mill is 25Hz. The crushed slag is finely pulverized by a stirring mill to obtain ultrafine cracked carbon black, and the frequency of the stirring mill is 45 Hz. The particle size D97 detected by the laser particle size analyzer is 15.8um, and it is transported to the buffer silo. Then, transport 500 kg of ultrafine cracked carbon black into the mixing and modifying machine, the mixing speed of the mixing and modifying machine is 1000r / min, add 270 kg of 25 ℃ process water from the spray pipe, and the flow rate of the spray water is 30kg / min, to obtain a wet material of ultrafine cracked carbon black with a humidity of 35%, and keep...

Embodiment 2

[0075] The recovered waste semi-steel thermal cracking coke slag is removed by a vibrating screen to remove large impurities, and then sent to a buffer bin for standby after passing through the iron removal equipment. The iron-removed slag goes through the jaw crusher before iron removal and enters the coarse powder storage silo. The frequency of the jaw crusher is 35Hz. The crushed slag is finely pulverized by an impact mill to obtain ultrafine cracked carbon black, and the frequency of the impact mill is 40 Hz. The particle size D97 detected by the laser particle size analyzer is 12.6um, and it is transported to the buffer silo. Then, transport 500 kilograms of ultrafine cracked carbon black into the mixing and modifying machine, the stirring speed of the mixing and modifying machine is 1500 r / min, and 290 kilograms of 35 ℃ process water is added to the spray pipe, and the spray flow rate is 20 kg / min, The ultrafine cracked carbon black wet material with a humidity of 37% w...

Embodiment 3

[0080] The recovered waste all-steel and semi-steel thermal cracking coke slag is removed by a vibrating screen to remove large impurities, and then sent to a buffer silo for standby after passing through the iron removal equipment. The iron-removed slag goes through the dry ball mill and then enters the coarse powder storage bin for iron removal. The frequency of the dry ball mill is 30Hz. The crushed slag is finely pulverized by an impact mill to obtain ultrafine cracked carbon black, and the frequency of the impact mill is 45 Hz. The particle size D97 detected by the laser particle size analyzer is 10.8um, and it is transported to the buffer silo. Then, transport 500 kg of ultrafine cracked carbon black (the weight ratio of semi-steel to full steel is 2:8) into the mixing and modifying machine, the stirring speed of the mixing and modifying machine is 800 r / min, and the spray pipe adds 300 kg 45 ℃ of process water, spray flow rate of 30kg / min, to obtain ultrafine cracked c...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a modification method of ultramicro cracked carbon black for rubber and a preparation method of composite rubber, and the modification method comprises the following steps: deironing and deslagging rubber residues pass through an ultramicro pulverizer to obtain ultramicro cracked carbon black powder with the particle size D97 of 5-20 [mu] m, and then the ultramicro cracked carbon black powder is conveyed into a high-speed mixer through conveying equipment; the preparation method comprises the following steps: adding a pre-prepared modifier solution into process water, uniformly stirring, uniformly spraying on the surface of the cracked carbon black by virtue of spraying equipment, and uniformly mixing at a high speed until the mixture is uniformly stirred, so that the water content of the material is about 30-50% at the moment. And after granulating and screening by a granulator, drying, cooling, packaging and warehousing. The modifier solution comprises the following components in parts by weight: 0-3 parts of reinforcing resin, 0-2 parts of a cross-linking agent and 0-5 parts of a dispersing agent. The method has the characteristics of simplicity in operation, controllable cost, ideal properties and the like, and the cracked carbon black particles are obtained after the modified powder carbon black is granulated and dried, so that the mechanical properties are greatly improved, and the dust pollution can be reduced.

Description

technical field [0001] The invention relates to the field of rubber reinforcing fillers, in particular to a modification method of ultrafine cracked carbon black for rubber and a preparation method of composite rubber. Background technique [0002] Pyrolysis (also known as cracking, thermal cracking) refers to a chemical reaction in which organic components in solid waste are thermally degraded by using high temperature in an oxygen-deficient or inert gas atmosphere, volatile products are released, and solid coke is formed. Among them, pyrolysis carbon and pyrolysis oil are the main products of waste tire pyrolysis, and the further recovered steel wire can also be reprocessed and utilized, thus realizing the effective resource reuse of waste tires. However, the carbon black obtained after pyrolysis does not [0003] Comparable to ordinary commercial carbon black, the composition and structure are very different, such as high ash content, few surface active groups, large par...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C09C1/48C09C1/56C09C3/06C09C3/10C09C3/04C08K9/04C08K9/10C08K3/04C08L7/00
CPCC09C1/482C09C1/56C09C3/063C09C3/10C09C3/045C09C3/006C08K9/04C08K9/08C08K9/10C08K3/04C08L7/00Y02W30/62
Inventor 徐磊沈家锋邵进
Owner 安徽固瑞特新材料科技有限公司