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Gold and silver bimetal nanocluster as well as preparation method and application thereof

A bimetallic nano-cluster technology, applied in nanotechnology, nano-optics, nanotechnology, etc., can solve problems such as negative effects on biological growth

Active Publication Date: 2022-05-31
SHANXI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the solubility and stability of nitrophenol in water, it can negatively affect biological growth if discharged into the environment without proper treatment

Method used

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  • Gold and silver bimetal nanocluster as well as preparation method and application thereof
  • Gold and silver bimetal nanocluster as well as preparation method and application thereof
  • Gold and silver bimetal nanocluster as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] The 3 mL 20 mmol / L N-acetyl-L-cysteine solution, 2 mL 10 mmol / L chlorohydranoic acid solution and 2.5 mL 2 mmol / L silver nitrate solution were mixed, the mixture was stirred evenly and the heating temperature was controlled to be reflux at 80 °C for 8 h, and after cooling, the aqueous solution of gold and silver bimetallic nanoclusters was obtained. The fluorescence emission peak of the luminous gold-silver bimetallic nanocluster is about 700 nm, and when viewed on a black background under ultraviolet light, it shows a relatively strong red fluorescence, and the quantum yield is 0.17.

Embodiment 2

[0036] The 3 mL 20 mmol / L N-acetyl-L-cysteine solution, 2 mL 10 mmol / L chloroauric acid solution and 2.5 mL 4 mmol / L silver nitrate solution were mixed, the mixture was stirred evenly and the heating temperature was controlled to be returned at 80 °C for 6 h, and after cooling, it was removed to obtain an aqueous solution of gold and silver bimetallic nanoclusters. The fluorescence emission peak of the luminous gold-silver bimetallic nanocluster is about 700 nm, and when viewed on a black background under ultraviolet light, it shows a relatively strong red fluorescence, and the quantum yield is 0.21.

Embodiment 3

[0038]3 mL 10 mmol / L N-acetyl-L-cysteine solution, 2 mL 10 mmol / L chlorohydranoic acid solution and 2.5 mL 4 mmol / L silver nitrate solution were mixed, the mixture was stirred evenly and the heating temperature was controlled to 80 °C reflux for 12 h, and after cooling, it was removed to obtain an aqueous solution of gold and silver bimetallic nanoclusters. The fluorescence emission peak of the luminous gold-silver bimetallic nanocluster is about 700 nm, and when viewed on a black background under ultraviolet light, it shows a relatively strong red fluorescence, and the quantum yield is 0.19.

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Abstract

The invention relates to a gold and silver bimetal nanocluster and a preparation method and application thereof. The gold and silver bimetal nanocluster is prepared by using a heating reflux method, taking N-acetyl-L-cysteine as a protective agent and a reducing agent, and taking a silver nitrate solution and a chloroauric acid solution as raw materials. In the synthesis process, addition of sodium hydroxide and common reducing agents such as sodium borohydride and hydrazine hydrate is avoided, the synthesis method is simple and convenient, synthesis conditions are mild, and the method is environmentally friendly. The prepared gold-silver bimetallic nanocluster is good in water solubility and stability, and has excellent catalytic performance and luminescence performance. The prepared red fluorescent gold and silver bimetallic nanocluster can be used for constructing a detection method of vitamin B6 and can also be applied to a catalyst for reducing nitrophenol isomers.

Description

Technical field [0001] The present invention relates to the preparation of metal nanoclusters, in particular, to a gold and silver bimetallic nanocluster and preparation method and application thereof. Background [0002] When the size of the metal nanoparticles is reduced to the level of the electron Fermi wavelength, the plasma absorption disappears completely, and molecular-like properties in discrete electronic states are formed, and these ultra-small metal nanoparticles are called metal nanoclusters. Metal nanoclusters have unique advantages as catalysts due to their high specific surface area, enhanced charge carrier mobility, and unique surface electron structure. By changing the properties and size of the end-terminated ligand can change the properties of the precious metal nanotubusters, more and more attention is that the metal nanoclusters are "doped" with a metal atom, which can control or improve the electronic structure and photophysical properties of the metal nano...

Claims

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Application Information

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IPC IPC(8): B01J23/52C07C213/02C07C215/76C09K11/58B82Y20/00B82Y40/00G01N21/31G01N21/64
CPCB01J23/52C07C213/02C09K11/58B82Y20/00B82Y40/00G01N21/31G01N21/6428G01N2021/6432C07C215/76Y02P20/55
Inventor 张彦苏艳高鹏飞伍建林张国梅董川双少敏
Owner SHANXI UNIV