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Hydrophobic and oleophobic polyethylene master batch, preparation method thereof and polyethylene pipeline material

A hydrophobic and oleophobic polyethylene technology, applied in the field of polyethylene, can solve the problems of low concentration of dispersed carbon nanotubes, harsh processing conditions, and the use of solvents, etc., and achieve a green and environmentally friendly preparation method, good surface lubrication performance, and strong practicability Effect

Pending Publication Date: 2022-07-08
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The concentration of dispersed carbon nanotubes in organic solvents is low, and it is difficult to obtain high-concentration carbon nanotube dispersions. At the same time, the large amount of volatile solvents used is not only not conducive to environmental protection, but also brings huge safety hazards to large-scale production.
[0010] Traditional polyethylene masterbatches are difficult to improve the surface oil and hydrophobic properties of products, and the above methods have defects such as the use of solvents and harsh processing conditions.

Method used

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  • Hydrophobic and oleophobic polyethylene master batch, preparation method thereof and polyethylene pipeline material
  • Hydrophobic and oleophobic polyethylene master batch, preparation method thereof and polyethylene pipeline material
  • Hydrophobic and oleophobic polyethylene master batch, preparation method thereof and polyethylene pipeline material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] The raw materials of the hydrophobic and oleophobic polyethylene master batch of this embodiment 1 include metallocene polyethylene powder, polyperfluoroethylene propylene micropowder, multi-wall carbon nanotube XFM03 and antioxidant, and the consumption of each component of the above-mentioned raw materials is : 30 parts by mass of metallocene polyethylene powder, 0.1 part by mass of polyperfluoroethylene propylene micropowder, 1 part by mass of multi-walled carbon nanotubes, and 0.5 part by mass of antioxidant.

[0045] The metallocene polyethylene powder in this embodiment is DQDN3711 of Daqing Petrochemical Company.

[0046] In this example, the particle size of the polyperfluoroethylene propylene micropowder is 300 nm, the weight-average molecular weight is 30,000, and the content of hexafluoropropylene is 17%.

[0047] In this embodiment, the diameter of the multi-walled carbon nanotube is 5 nm-15 nm, and the length of the multi-walled carbon nanotube ranges from ...

Embodiment 2

[0056] The raw materials of the hydrophobic and oleophobic polyethylene masterbatch of this embodiment 2 include metallocene polyethylene powder, polyperfluoroethylene propylene micropowder, multi-wall carbon nanotube XFM03 and antioxidant, and the weight components of each component of the above-mentioned raw materials It is: 30 parts by mass of metallocene polyethylene powder, 3 parts by mass of polyperfluoroethylene propylene micropowder, 5 parts by mass of multi-walled carbon nanotubes, and 2 parts by mass of antioxidant.

[0057] The metallocene polyethylene powder in this embodiment is DQDN3711 of Daqing Petrochemical Company.

[0058] In this example, the particle size of the polyperfluoroethylene propylene micropowder is 300 nm, the weight-average molecular weight is 30,000, and the content of hexafluoropropylene is 19%.

[0059] In this embodiment, the diameter of the multi-walled carbon nanotube is 5 nm-15 nm, and the length of the multi-walled carbon nanotube ranges...

Embodiment 3

[0068] The raw material of the hydrophobic and oleophobic polyethylene master batch of this embodiment 3 includes metallocene polyethylene powder, polyperfluoroethylene propylene micropowder, multi-wall carbon nanotube XFM03 and antioxidant, and the consumption of each component of the above-mentioned raw material is: 30 parts by mass of metallocene polyethylene powder, 3 parts by mass of polyperfluoroethylene propylene micropowder, 1 part by mass of multi-walled carbon nanotubes, and 0.5 part by mass of antioxidant.

[0069] The metallocene polyethylene powder in this embodiment is DQDN3711 of Daqing Petrochemical Company.

[0070] In this example, the particle size of the polyperfluoroethylene propylene micropowder is 300 nm, the weight-average molecular weight is 40,000, and the content of hexafluoropropylene is 16%.

[0071] In this embodiment, the diameter of the multi-walled carbon nanotube is 5 nm-15 nm, and the length of the multi-walled carbon nanotube ranges from 10 ...

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Abstract

The invention relates to a hydrophobic and oleophobic polyethylene master batch which comprises the following raw materials: metallocene polyethylene, fluorinated ethylene propylene, multi-walled carbon nanotubes and an antioxidant, the particle size of the fluorinated ethylene propylene is 200-400 nm, the diameter of the multi-walled carbon nanotubes is 5-15 nm, and the length of the multi-walled carbon nanotubes is 10-30 [mu] m; the dosage of each component of the raw materials is as follows: 30 parts by mass of metallocene polyethylene, 0.1-3 parts by mass of fluorinated ethylene propylene, 1-5 parts by mass of multiwalled carbon nanotubes and 0.5-2 parts by mass of an antioxidant. The invention also relates to a preparation method of the hydrophobic and oleophobic polyethylene master batch and a polyethylene pipeline material. The polyethylene master batch and the polyethylene pipe prepared by adopting the formula provided by the invention have better effects in the aspects of scaling and wax precipitation resistance, and are convenient to popularize and use in oil fields.

Description

technical field [0001] The invention relates to the field of polyethylene, in particular to a hydrophobic and oleophobic polyethylene master batch and a preparation method thereof, and a polyethylene pipe material comprising the polyethylene master batch. The polyethylene pipe prepared from the polyethylene pipe material is particularly suitable for use in For oil field pipelines. Background technique [0002] In recent years, with the increasingly harsh environment of oilfield medium, water content and temperature have gradually increased, and Cl - , CO 2 The content of other corrosive media increases, and even H appears in oil and gas wells in some areas. 2 S, brings a great risk to the application of metal pipes. Severe corrosion, scaling, waxing or leakage of steel pipelines has become one of the key bottleneck technologies restricting oilfield development. Leakage accidents also bring serious safety and environmental risks. Every year, plugging and replacing pipeline...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L27/18C08K3/04C08J3/22
CPCC08J3/226C08L23/06C08J2423/06C08J2427/18C08K3/041C08J2323/06C08K2201/003C08K2201/004C08L2203/18C08L27/18
Inventor 孙彬彬王华张瑞宋磊高宇新王立娟王文燕杨国兴杨琦牛娜
Owner PETROCHINA CO LTD