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Lithium battery negative electrode slurry formula, lithium battery negative electrode, preparation method of lithium battery negative electrode and lithium battery

A negative electrode slurry, lithium battery technology, applied in battery electrodes, lithium batteries, non-aqueous electrolyte battery electrodes, etc., can solve the problem of reducing the compaction density of graphite negative electrodes, material processing performance, yield and production capacity constraints, and high process equipment requirements. problem, to achieve the effect of reducing the rebound of the pole piece, reducing the internal resistance, and improving the rate performance

Pending Publication Date: 2022-07-29
HIGHPOWER TECH HUIZHOU
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Traditional fast-charging graphite materials generally increase the ionic conductivity by reducing the particle size of the powder, but while the yield and production capacity are limited, the compaction density and material processing performance of the graphite negative electrode are also greatly reduced.
However, the preparation methods of other graphite negative electrodes will reduce the fast charging performance, or require higher process equipment

Method used

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  • Lithium battery negative electrode slurry formula, lithium battery negative electrode, preparation method of lithium battery negative electrode and lithium battery
  • Lithium battery negative electrode slurry formula, lithium battery negative electrode, preparation method of lithium battery negative electrode and lithium battery
  • Lithium battery negative electrode slurry formula, lithium battery negative electrode, preparation method of lithium battery negative electrode and lithium battery

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preparation example Construction

[0030] This embodiment also discloses a method for preparing a negative electrode of a lithium battery, which is applied to the preparation of the negative electrode of a lithium battery as described above, and includes the steps:

[0031] S100: dry mixing hard carbon, graphite and high-pressure compaction aid to obtain a mixture;

[0032] S200: adding water to the mixture and mixing to obtain a pre-slurry, and the solid content is controlled at 50% to 70%;

[0033] S300: Knead the pre-slurry into a spherical shape, add sodium carboxymethyl cellulose for pre-dispersion, then add water to disperse, and add N-methylpyrrolidone;

[0034] S400: Add the binder, vacuum defoaming after stirring, and wait until the negative electrode slurry;

[0035] S500: coating the negative electrode slurry on the negative electrode current collector, and drying the negative electrode of the lithium battery.

[0036] Specifically, in step S100, the hard carbon and the high-pressure compaction aid...

experiment example

[0040] Production of negative electrode:

[0041] According to the lithium battery negative electrode slurry formula of the present invention, each component is mixed with water, stirred and dispersed to prepare negative electrode slurry, and then coated on smooth copper foil or carbon-coated copper foil by extrusion coater or transfer coater, The coating temperature is controlled between 80° C. and 150° C., and the negative electrode of the present invention can be obtained by drying and cold pressing. By changing the ratio of high compaction additive and hard carbon, the numbering relationship of the obtained negative electrode samples is shown in Table 1.

[0042] Negative number hard carbon High compaction additive compaction density Comparative Example A1 0wt.% 0wt.% 1.60g / cc Comparative Example A2 3wt.% 0wt.% 1.55g / cc Comparative Example A3 0wt.% 1wt.% 1.64g / cc Comparative Example A4 3wt.% 2wt.% 1.68g / cc Com...

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Abstract

The invention discloses a lithium battery negative electrode slurry formula, a lithium battery negative electrode and a preparation method thereof, and a lithium battery, the lithium battery negative electrode slurry formula comprises, by mass, 65-80% of graphite, 1-10% of hard carbon, 0.5-5% of a high compaction auxiliary agent, and the balance sodium carboxymethyl cellulose and a binder. According to the invention, the hard carbon and the high-compaction auxiliary agent are added into the negative pole piece, and the high-compaction auxiliary agent is specifically crystalline flake graphite with unequal height, so that the compaction density of the pole piece can be improved while the capacity of the negative pole is not influenced, the rate performance of the battery is improved, and the internal resistance and the rebound of the pole piece are reduced at the same time.

Description

technical field [0001] The invention relates to the technical field of lithium battery production, in particular to a lithium battery negative electrode slurry formulation, a lithium battery negative electrode and a preparation method thereof, and a lithium battery. Background technique [0002] Due to its high voltage, high capacity, long cycle life, low self-discharge efficiency, and good safety performance, lithium-ion batteries are widely used in 3C digital products, electric vehicles, start-stop power supplies, model aircraft, and energy storage. At present, although the vehicle power lithium battery can meet the driving mileage of 500km, it often takes several hours to fully charge, which is far from meeting the needs of customers; at the same time, for digital consumer lithium batteries, consumers are more hopeful to improve On the basis of the capacity, the charging time of lithium batteries is further reduced, and the consumption experience is improved. Therefore, ...

Claims

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Application Information

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IPC IPC(8): H01M4/36H01M4/13H01M4/139H01M4/62H01M10/052
CPCH01M4/36H01M4/625H01M10/052H01M4/13H01M4/139
Inventor 肖资龙史柯彭昌志蒋珊张昌明
Owner HIGHPOWER TECH HUIZHOU