Anionic dysprosium chain complex taking organic tertiary ammonium as counter ion as well as preparation method and application of anionic dysprosium chain complex

An anionic and complex technology, applied in the fields of magnetism of organic materials/organic magnetic materials, compounds containing elements of group 3/13 of the periodic table, organic chemistry, etc., can solve the undiscovered anionic chain rare earth coordination polymerization The problem of molecular magnets and other problems, to achieve the effect of high universality, mild synthesis conditions, and simple synthesis steps

Pending Publication Date: 2022-08-09
GUILIN UNIVERSITY OF TECHNOLOGY
View PDF0 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In particular, there have been no reports on molecular magnets based o

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Anionic dysprosium chain complex taking organic tertiary ammonium as counter ion as well as preparation method and application of anionic dysprosium chain complex
  • Anionic dysprosium chain complex taking organic tertiary ammonium as counter ion as well as preparation method and application of anionic dysprosium chain complex
  • Anionic dysprosium chain complex taking organic tertiary ammonium as counter ion as well as preparation method and application of anionic dysprosium chain complex

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0025] 1. Example [Et 3 NH] n [Dy(hfac) 3 (OAc)] n the preparation method of

[0026] Weigh Dy(hfac) 3 ·2H 2 O (0.05 mmol, 41.1 mg) was placed in a 100 mL round-bottomed flask, 20 mL of n-heptane was added, refluxed at 85 °C for 1.5 h, and then cooled to 40 °C. 5mL of dichloromethane solution containing 3μL of glacial acetic acid was slowly added dropwise to the above solution and stirred for 10min, then 0.5mL of acetone was added to react for 30min, cooled to room temperature and then added with triethylamine, filtered, and the filtrate was evaporated at room temperature for about 1 week. Colorless needle-like crystals were obtained. Yield 51% (based on glacial acetic acid).

[0027] 2. Example [Et 3 NH] n [Dy(hfac) 3 (OAc)] n Crystallographic tests and crystallographic parameters of

[0028] Crystal data were collected using an Agilent G8910A CCD single crystal diffractometer at 293 K with Scanning method using a graphite monochromatic Mo-Kα ray diffraction sou...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses an anionic dysprosium chain complex taking organic ammonium as a counter ion as well as a preparation method and application of the anionic dysprosium chain complex. The general formula of the complex is [AH] n [Dy (L1) 3 (L2)] n, [AH] < + > is an organic tertiary ammonium cation, L1 is a beta-diketone derivative, and L2 represents an acetic acid or formate ion. Wherein the [Dy (L1) 3] module is bridged through L2 to form an anionic dysprosium chain complex structure, and the organic tertiary ammonium cation [AH] < + > is connected with a dysprosium chain through a hydrogen bond and plays a role of a counter ion of the whole complex. The complex is prepared through a conventional volatilization method, the preparation method is simple, and reaction conditions are mild; and meanwhile, the material shows a single-molecule magnet behavior with slow magnetic relaxation, and has potential application value in the field of molecule-based magnetic materials. Particularly, the anionic dysprosium chain complex can derive other compounds with various structures through changes of [AH] < + >, L1, L2 and a rare earth center, is very beneficial to regulation and control of molecular magnetism, and has not been reported in previous literatures.

Description

technical field [0001] The invention relates to the preparation and application of novel molecular-based materials, in particular to a class of anionic dysprosium-based chain complexes with organic tertiary ammonium counterions, and a preparation method and application thereof. technical background [0002] Molecular-based magnetic materials use a single molecule as a magnetic domain unit, and have the advantages of flexible structure, low density, easy tailoring, easy regulation and modification, etc., and are expected to replace the existing traditional macroscopic magnetic materials. In the future, ultra-high-density storage, quantum play an important role in computing and spintronic devices. In particular, the dysprosium complexes have become one of the ideal targets for the development of molecular-based magnetic materials, benefiting from the excellent single-ion magnetic anisotropy of dysprosium ions. However, the currently reported dysprosium complexes are mostly di...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C07F5/00C08G83/00H01F1/42
CPCC07F5/003C08G83/008H01F1/42C07B2200/13Y02P10/20
Inventor 王凯罗学晶郭柯柯梁福沛
Owner GUILIN UNIVERSITY OF TECHNOLOGY
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap