Pigment, process for producing pigment, pigment disperser and powder toner for static charge developing
A technology of pigment dispersion and manufacturing method, which is applied in the direction of pigment slurry, developer, organic dye, etc., and can solve the problems of inability to obtain performance, etc.
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manufacture example 1
[0106] After dispersing 45 parts of 1,2-bis(2-aminophenoxy)ethane in 650 parts of water, add 107.7 parts of 35% hydrochloric acid, then add ice to keep the temperature below 5°C, and drop in 67.4 parts of 40% nitrous acid at the same time Sodium aqueous solution, made of diazo components. Next, after dispersing 93 parts of 5-acetoacetylamino-benzimidazolinone in 675 parts of water, 119 parts of 25% aqueous sodium hydroxide solution were added to dissolve it to obtain a coupling component. Water and ice were added to the diazo component and the coupling component, respectively, and the respective liquid volumes were adjusted to 1300 parts and 900 parts.
[0107] After adding 6 parts of 90% acetic acid and 13.5 parts of polyoxyethylene lauryl ether to 1300 parts of water, the temperature and pH of the solution were adjusted to 20°C and 6.0, respectively. Add the coupling component dropwise to the previously prepared acetic acid solution, and after adjusting the pH to 6.0, start...
manufacture example 2
[0114] Except that the amount of 5-acetoacetylamino-benzimidazolinone was changed from 93 parts to 90 parts, polyoxyethylene lauryl ether was not added to the acetic acid solution, and the pH was adjusted to 12. Otherwise, follow the procedure of Production Example 1 to obtain a water-containing pigment (28% pigment component) and a powdery disazo yellow pigment of the present invention.
[0115] Using the same method as above, the specific surface area of the obtained powder pigment and the absolute intensity ratio (h1 / h2) of the above-mentioned X-ray diffraction were measured, and the results were 76.1m 2 / g and 1.29 / 1.00.
manufacture example 3
[0117] 73.2 parts of 1,2-bis(2-aminophenoxy)ethane were stirred and dispersed in 300 parts of water, while 132.9 parts of 35% hydrochloric acid were added. After stirring for 1 hour, the temperature was adjusted to 0-5° C. with ice, and then 41.8 g of 40% sodium nitrite aqueous solution was added to carry out diazotization reaction. After stirring for more than 1 hour, add 20 parts of sulfamic acid to remove excess nitrite, and stir for more than 10 minutes to adjust the double nitrogen salt solution.
[0118] On the other hand, after dispersing 150.8 parts of 5-acetoacetylamino-benzimidazolinone in 900 parts of water, 198 parts of 25% aqueous sodium hydroxide solution were added to dissolve it. After adjusting the temperature to 5° C. with ice, the pH was adjusted to 5.3 with acetic acid in the presence of 12 parts of dimethyl cocoalanamine oxide (Jimachilkokoalkyluamin Okishito) to form a precipitate.
[0119] For the coupling reaction, the diazonium solution was added to t...
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