Directly combined magnesia alumina spinel carbon brick and its preparing process

An aluminum-magnesium spinel and carbon brick technology, which is applied in the field of carbon-containing refractories, can solve the problems of low thermal conductivity, shortened production cycle, poor thermal shock resistance, etc., so as to improve the service life, shorten the production cycle and reduce the production cost. Effect

Inactive Publication Date: 2006-02-15
陈忠贵
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to provide a direct composite aluminum-magnesium spinel carbon brick, which effectively solves the shortcomings of traditional aluminum-magnesium spinel carbon bricks with poor thermal shock resistance and has good Anti-erosion, anti-slag corrosion performance, good thermal shock stability, low thermal conductivity, this invention selects high-quality magnesia, aluminum material, natural flake graphite and compound organic binder, adopts unique production process to form at one time, utilizes smelting Temperature sintering, good overall performance, completely changed the traditional production process, no heat treatment and other processes are needed after pressing and forming, which is not only beneficial to environmental protection, but also can greatly shorten the production cycle, save energy, work efficiency, and reduce production costs. At the same time, its unique production process makes it unnecessary to add aluminum-magnesium spinel, and the raw materials are directly compounded through a special process, and the aluminum-magnesium spinel is naturally generated by using the smelting temperature. The amount of spinel produced increases with the change of the smelting temperature. This technology can greatly reduce the production cost and increase the service life of the product, and has significant economic and social benefits. It can be widely used in thermal equipment such as ladles and refining furnaces, and is widely applicable.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] A direct composite aluminum-magnesium spinel carbon brick, characterized in that it includes the following raw materials and their weight ratios: 37 kilograms of aluminum material with a particle size of 2-5 mm, and aluminum with a particle size of 0.088-2 mm. 20 kg of material, 5 kg of magnesia with a particle size of 2-5 mm, 3 kg of magnesia with a particle size of 0.088-2 mm, 25 kg of aluminum-magnesium mixed grinding powder with a particle size of less than 0.088 mm, and graphite with a particle size of less than 100 mesh 10 kg, binder 5 kg.

[0044] The composition of the aluminum material of the present invention includes Al 2 O 3 ≥83.7%, SiO 2 ≤11.2%, Fe 2 O 3 ≤1.09%, TiO 2 ≤3.54%, CaO≤0.61%, MgO≤0.21%, K 2 O≤0.18%, Na 2 O≤0.06%, water absorption rate≤5%, bulk density≥2.90g / cm 3 .

[0045] The composition of the magnesia of the present invention includes MgO≥95.1%, CaO≤1.28%, SiO 2 ≤2.01%, Fe 2 O 3 ≤0.65%, Al 2 O 3 ≤0.69%, loss on ignition ≤0.17%, b...

Embodiment 2

[0062] Thermal shock resistance, peeling test

[0063] 1. After the various indicators of the trial product reached the expected index, a small batch of products were produced according to the above process, and they were tested at the bottom of a 10-ton electric furnace ladle in Chengdu Sanyi Special Steel Co., Ltd.; a total of 3 ladles were tested and the effect was good. ;

[0064] 2. Partial trial was carried out directly at the bottom of the 40-ton LF refining ladle of Chengdu Sanyi Special Steel Co., Ltd.; satisfactory results were obtained. Compared with traditional aluminum-magnesium spinel carbon bricks used in other parts, the protruding thickness is about 15mm.

[0065] 3. Take the overall trial at the bottom of the 40tLF refining ladle; the effect is remarkable, without pits, protrusions, and peeling off; it ensures the simultaneous loss of the bottom of the ladle, the molten pool, and the slag line.

[0066] 4. The overall trial was adopted at the bottom of the ...

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Abstract

The invention discloses a magnesium aluminate spinel carbon brick capable of direct recombination and process for preparation, wherein the brick comprises the raw materials of aluminium, magnesite, magnesium-aluminium milled powder, graphite, and chelating agent,By adopting the unique one-shot forming manufacturing technique, the invention changes the conventional process, wherein no heat treatment procedures are needed after press forming, thus facilitating environmental protection and substantially shortening period of production, thus can be widely applied for thermal equipment such as refined-smelting ladle furnace.

Description

Technical field: [0001] The invention relates to a carbon-containing refractory material, in particular to a direct composite aluminum-magnesium spinel carbon brick. Background technique: [0002] The production process of the existing aluminum-magnesium spinel carbon brick is as follows: the product is formed and pressurized, naturally dried for 24 hours, or firstly dried at 40-60 DEG C for 8 hours, and then enters the drying kiln, and is heated under the flame at 250- It is baked at 300°C for 72-76 hours, and due to uneven heating or cooling of each part, the reaction is not sufficient and thorough, which affects the structure and performance of the finished product. At the same time, it is necessary to add aluminum-magnesium spinel when the raw materials are mixed In order to increase the spinel content of the product, this technology not only has high production cost and complicated process, but also increases the thermal expansion and residual expansion of the product a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/10C04B35/04C04B35/103C04B35/622C04B35/443C04B35/66
Inventor 陈忠贵
Owner 陈忠贵
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