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Chemical modulatory agent for harnessing soil pollution and its preparing method

A technology of chemical regulation and regulation agent, which is applied in the restoration of polluted soil and other directions, can solve the problems of unsatisfactory substances and methods of heavy metal contaminated soil, limiting the large-scale application of artificial chelating agents, and plant metal stress, etc. Application, low cost, effect of promoting plant growth

Inactive Publication Date: 2006-10-25
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The disadvantage of the former is that there is still a potential threat in the treated soil, because the total amount of heavy metals it contains has not been reduced, so its activity may still be released under certain conditions, and these conditions have yet to be determined. However, these methods are not reliable because they are limited to research; the disadvantage of the latter is that if the chelating agent is not applied properly, it may lead to potential environmental risks, such as soil element leaching, water pollution, and chelating residues. Volatilization will cause metal stress to plants, thus limiting the large-scale application of artificial chelating agents
In short, the existing two types of substances and methods for treating heavy metal-contaminated soil are not ideal.

Method used

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  • Chemical modulatory agent for harnessing soil pollution and its preparing method
  • Chemical modulatory agent for harnessing soil pollution and its preparing method
  • Chemical modulatory agent for harnessing soil pollution and its preparing method

Examples

Experimental program
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Effect test

Embodiment 1

[0024] Embodiment 1. The chemical regulator for controlling soil pollution in this embodiment is a non-toxic, biodegradable, highly water-soluble chitosan substance with a strong metal complexing ability and a molecular weight lower than 2000. The reasons are: 1) from figure 2 See on the Fourier infrared spectrum, curve I in the figure represents chitosan, curve II represents the chemical regulator of this embodiment, the sugar ring characteristic absorption peak of existing chitosan is at 1154cm -1 and 900cm -1 Nearby, while the chemical regulator of this embodiment and chitosan before degradation have two groups of similar absorption peaks (894.9,1154) Such as figure 1 The sugar ring structure of its raw material chitosan shown is a kind of chitosan material, so it is nontoxic, biodegradable, and has strong metal complexing ability; 2) its molecular weight can be obtained from Fig. 3 grape Estimated in the glycan gel chromatography and listed in Table 1, this is the meas...

Embodiment 2

[0033] Embodiment 2. is different from the preparation method of the chemical regulator in embodiment 1: the present embodiment adopts a group of seven examples (I, II, III, IV, V, VI, VII) with different microwave firepower (700W Low, medium, high, extremely high power) and corresponding reaction time, all can make the chemical regulator of the present invention. The microwave firepower of each example and its corresponding response time are listed in the following table 2:

[0034] I

Embodiment 3

[0035] Embodiment 3 is the application example of the chemical regulator of this embodiment, the example of its use steps and its efficacy:

[0036] 1. For the leaching treatment of phytoremediation of contaminated soil, a liquid chemical regulator can be directly used, and its water content is 0 to 10 times its weight, that is, it can be diluted without water or diluted with 1 to 10 times of water. ; If it is a solid chemical regulator, it can be made into a 0.5-5% solution.

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Abstract

A chemical regulator for controlling soil pollution and a preparation method thereof. A substance that can strongly complex copper and zinc and is used to treat soil polluted by heavy metals. The chemical regulating agent of the present invention is a large water-soluble chitosan substance with a molecular weight lower than 2000. Its preparation method: take polymer chitosan and add distilled water 10 to 20 times its weight and 30% H 2 o 2 , to make the concentration reach 2-5 (% by weight), stir until fully swollen; place in a microwave oven for 2-5 minutes on high heat and take it out from the microwave oven after standing for 5-10 minutes; add distilled water to make it return to the original Then place it in an ultrasonic cleaning machine for intermittent ultrasonication for no less than 5 hours; filter with a Buchner funnel and dilute 1-50 times with water in the transparent solution obtained by filtering to be the liquid chemical regulator of the present invention . It is non-toxic, biodegradable and can be directly used for leaching treatment of heavy metal-contaminated soil or repairing polluted soil with plant extraction.

Description

technical field [0001] The invention relates to a substance for controlling soil pollution and a preparation method thereof, in particular to a chemical regulator capable of strongly complexing heavy metals copper and zinc and being used for leaching treatment or phytoremediation of heavy metal polluted soil. Background technique [0002] As we all know, heavy metals are pollutants that will continue to accumulate and remain. Due to metal mining, smelting, and sewage irrigation, the area of ​​soil polluted by heavy metals is constantly expanding; therefore, the restoration and improvement of polluted soil has become It has become a major scientific issue in our country and even in the world. [0003] At present, the soil treatment methods polluted by heavy metals can be classified into two categories: one is to stabilize the heavy metals in the soil to reduce its activity in the soil, and its related patents, such as the Chinese patent 02125605. Heavy metal chelating agent ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L5/08B09C1/00
Inventor 林琦陈英旭石伟勇王兆炜吴龙华
Owner ZHEJIANG UNIV
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