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Fluorosurfactant-free foam fire-extinguisher

A technology of foam fire extinguishing agent and surfactant, which is applied in the field of foam fire extinguishing agent, can solve the problems of poor storage and achieve the effect of improving fluidity and saving storage space

Inactive Publication Date: 2005-03-02
西义之 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] As a conventional foam fire extinguishing agent that can be used for both oil and alcohol, there is also a fluorine-based surfactant added to the hydrolyzed protein, but this fire extinguishing agent has poor storage properties due to the formation of precipitates due to changes in pH. Ineffective fire extinguishing of acidic water-soluble combustible substances such as acetic acid

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0072] The following components 1, 2, and 3 were mixed and stirred to prepare 4900 g of a homogeneous mixed composition.

[0073] (combined ingredient 1)

[0074] Mix 500g of water, 150g of polyethylene glycol 20000, and 500g of polyethylene oxide diamine (Chuanyan Fine Chemicals PEO amine 6000: average molecular weight 8000-8500, amine value 10-15, hydroxyl value below 2) and knead, totaling 1150g As a compounding ingredient 1.

[0075] (combined ingredient 2)

[0076] After kneading with polyoxyethylene alkyl ammonium sulfate: 40wt%, diethylene glycol monobutyl ether: 37wt%, ethylene glycol: 8wt%, lauryl alcohol: 2wt%, water: 13wt%, A total of 3000g was used as compounding component 2.

[0077] (combined ingredient 3)

[0078] 600 g of lauryl amidopropyl dimethylaminoacetate betaine and 150 g of lauryl alcohol were kneaded and a total of 750 g was used as compounding component 3.

[0079] (Fire extinguishing test 1)

[0080] The above-mentioned homogeneous mixture comp...

Embodiment 2

[0091] After mixing and stirring the following components 1, 2, 3, and 4, 5140 g of a homogeneous mixing composition was prepared. Coco fatty acid monoethanolamine phosphate was used instead of the polyethylene oxide diamine in Example 1. In addition, compounding component 4 is added.

[0092] (combined ingredient 1)

[0093] After mixing 500g of water, 150g of polyethylene glycol 20000, and 400g of polyoxyethylene coco fatty acid monoethanolamine phosphate (Chuanyan Fine Chemicals: Amida P52), a total of 1150g is used as compounding component 1.

[0094] (combined ingredient 2)

[0095] After kneading with polyoxyethylene alkyl ammonium sulfate: 40wt%, diethylene glycol monobutyl ether: 37wt%, ethylene glycol: 8wt%, lauryl alcohol: 2wt%, water: 13wt%, A total of 3000g is used as compounding ingredient 2.

[0096] (combined ingredient 3)

[0097] 600 g of lauryl amidopropyl dimethylaminoacetate betaine and 150 g of lauryl alcohol were kneaded, and a total of 750 g was use...

Embodiment 3

[0111] After mixing and stirring the following components 1, 2, 3, and 4, 5240 g of a homogeneous mixing composition was prepared. Increase the amount of polyoxyethylene coco fatty acid monoethanolamine phosphate than embodiment 1, use lauryl amidopropyl hydroxy sultaine to replace lauryl amidopropyl dimethylaminoacetate betaine.

[0112] (combined ingredient 1)

[0113] After mixing 500g of water, 150g of polyethylene glycol 20000, and 500g of polyoxyethylene coco fatty acid monoethanolamine phosphate (Chuanyan Fine Chemicals: Amida P52), a total of 1150g is used as compounding component 1.

[0114] (combined ingredient 2)

[0115] After kneading with polyoxyethylene alkyl ammonium sulfate: 40wt%, diethylene glycol monobutyl ether: 37wt%, ethylene glycol: 8wt%, lauryl alcohol: 2wt%, water: 13wt%, A total of 3000g is used as compounding ingredient 2.

[0116] (combined ingredient 3)

[0117] 600 g of lauryl amidopropyl hydroxy sultaine and 150 g of lauryl alcohol were knea...

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PUM

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Abstract

The present invention provides a foam fire-extinguishing agent devoid of environmentally harmful fluorochemical surfactant. The foam fire-extinguishing agent comprises a foamable synthetic surfactant consisting of (a) polyoxyethylene alkyl sulfate ester salt, and (b) at least either one of lauric acid amide propyldimethyl amino betaine acetate and lauric acid amide propylhydroxy sulfobetaine. This foam fire-extinguishing agent may further include at least either one of (c) polyoxyalkylenediamine having both terminal ends substituted with amino alkyl, and derivatives thereof, (d) polyoxyethylene coconut fatty acid monoethanol amide phosphate ester and (e) dodecyl alcohol. The foam fire-extinguishing agent is usable as both high- and low-expansion foam fire-extinguishing agents and in both seawater-diluted and freshwater-diluted forms while maintaining excellent performances such as water-retentivity within foams, durability to heat, liquid resistance allowing foams to stay on a burning liquid surface over an extended time-period, and flowability capable of covering over the burning liquid surface in a short time-period.

Description

technical field [0001] The present invention relates to a foam fire extinguishing agent that does not contain a fluorine-based surfactant, and in particular relates to a foam with enhanced heat resistance, improved water retention, and excellent fire extinguishing performance of any one of a high foam fire extinguishing agent or a low foam fire extinguishing agent, Synthetic surfactant foam fire extinguishing agent dilutable with both seawater and freshwater. Background technique [0002] In recent years, with the development of the chemical industry, not only non-water-soluble flammable liquids such as gasoline and naphtha, but also water-soluble flammable liquids such as alcohols, ethers, and esters have been increased in production and use. It also tends to be large-scale. Along with this, the risk of disasters such as fires increases, and emergency response at the time of disasters is also considerably difficult. [0003] In the past, as a fire extinguishing agent for ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A62D1/02
CPCA62D1/0071
Inventor 志贺博
Owner 西义之
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