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Method for recovering and reutilizing industrial waste salt and apparatus thereof

A technology of industrial waste salt and industrial salt, applied in the direction of alkali metal chloride, etc., can solve the problems of open-air stacking or direct discharge into rivers, waste of resources, environmental pollution, etc. The effect of improving the decomposition rate

Inactive Publication Date: 2005-09-21
HUNAN CHEM RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In some organic chemical production, a large amount of waste salt will be produced, such as producing 1 ton of hydrazine hydrate to produce about 3 tons of waste salt, which contains a large amount of sodium chloride, sodium carbonate, and sodium hydroxide, but contains a small amount of amine; the production of 1 ton of furan phenol is about Produce 0.8 tons of waste salt. The waste salt mainly contains sodium chloride, but contains a small amount of organic impurities such as phenol and ether. These waste salts cannot be directly used in the chlor-alkali industry. At present, the factory can only store such waste salt in the open air for a long time or Direct discharge into rivers not only wastes a lot of resources, but also causes serious pollution to the environment
There are reports in the literature on the use of water washing to treat waste salt and the use of rotary kilns to treat waste salt, but they have not been industrialized due to high cost or impurity content after treatment that meets the requirements of the chlor-alkali industry.

Method used

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  • Method for recovering and reutilizing industrial waste salt and apparatus thereof

Examples

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Comparison scheme
Effect test

example 1

[0006] Example 1: 100Kg of by-product salt (ammonium content 5800ppm) of the hydrazine hydrate production plant is continuously fed into the heating furnace, and the material stays for 4-8 hours. The furnace is maintained at 400-500 ° C, and hot air at 400-500 ° C is introduced. The product salt contains Ammonium 12.3ppm.

example 2

[0007] Example 2: 50Kg of by-product salt (ammonium content 5600ppm) of the hydrazine hydrate production plant is continuously fed into the heating furnace, the material stays for 6-12 hours, the furnace is maintained at 500-600 ° C, and hot air at 500-600 ° C is introduced, and the product salt contains Ammonium 9.1ppm.

example 3

[0008] Example three: 50Kg of by-product salt (phenol, ether content 2%) of furan phenol production plant, continuous feed into the heating furnace, the material stays for 8-12 hours, maintains 450-550 ° C in the furnace, feeds hot air at 450-550 ° C, the product The content of phenol and ether in the salt is 7.8ppm.

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PUM

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Abstract

The invention discloses an art method and corresponding device for reclaiming and utilizing the industry waste salt within some easy volatile or dissociated organic impurity such as amine, phenols and ether. The harmful impurities such as amine, phenols and ether in the industrial waste can be thermal dissociated or volatilized using the multiple-layers disk heating-furnace with the heating arrangement and the corresponding art process, to reach the requirement of industrial salt. This method provides a effective approach for reclaiming and utilizing the industry waste salt within some easy volatile or dissociated organic impurity such as amine, phenols and ether.

Description

technical field [0001] The invention relates to a method and equipment for treating industrial waste salt containing harmful impurities such as amines, phenols, ethers, etc. The harmful impurities in the treated industrial waste salt can meet the requirements of industrial salt and achieve the purpose of recycling. Background technique [0002] In some organic chemical production, a large amount of waste salt will be produced, such as producing 1 ton of hydrazine hydrate to produce about 3 tons of waste salt, which contains a large amount of sodium chloride, sodium carbonate, and sodium hydroxide, but contains a small amount of amine; the production of 1 ton of furan phenol is about Produce 0.8 tons of waste salt. The waste salt mainly contains sodium chloride, but contains a small amount of organic impurities such as phenol and ether. These waste salts cannot be directly used in the chlor-alkali industry. At present, the factory can only store such waste salt in the open air...

Claims

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Application Information

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IPC IPC(8): C01D3/06
Inventor 皮银安贺周初郑贤福彭爱国刘昱霖余长艳
Owner HUNAN CHEM RES INST
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