Modified chlorinated polypropylene adhesive

A technology of chlorinated polypropylene and adhesives, which is applied in the direction of adhesives, etc., can solve the problems of low grafting rate of polypropylene, difficult control of reaction conditions, complicated reaction process, etc., and achieve the effect of high cost performance, low cost and simple preparation process

Inactive Publication Date: 2006-01-04
HUBEI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The second type is polypropylene melt grafting, whose performance is greatly affected by peroxide initiators. Peroxides can cause polypropylene to undergo reactions such as crosslinking, degradation, and grafting. Due to the high temperature of polypropylene melt grafting, in Under the action of peroxide initiator, it is easy to cause degradation of polypropylene, and polypropylene is also easy to cross-l...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] The weight percent content of chlorine element in chlorinated polypropylene in various formulations in the table is 30%, the initiator is benzoyl peroxide (BPO), and the additive is styrene (St). The reaction temperature is 100-140°C.

[0034] formula

Embodiment 2

[0037] The weight percent content of chlorine element in chlorinated polypropylene in various formulations in the table is 30%, the initiator is benzoyl peroxide, the additive is dimethylacetamide, and the reaction temperature is 100-140°C.

[0038] formula

Embodiment 3

[0040] match

[0041] In the various formulas in the table, the weight percent content of chlorine element in chlorinated polypropylene is 30%, the initiator is benzoyl peroxide, the additive is dimethyl sulfoxide, and the reaction temperature is 100-140°C.

[0042] formula

[0043] It can be seen from Tables 2, 4 and 6 that under the same conditions, the adhesive prepared by adding styrene additives has better adhesion than adding dimethylacetamide or dimethyl sulfoxide additives.

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PUM

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Abstract

The modified chlorinated polypropylene adhesive consists of chlorinated polypropylene 100 weight portions, glycidol acrylate 0.05-0.2 weight portions, additive 0.05-0.4 weight portions, initiator 0.1-0.5 weight portions, and tackifier 5-15 weight portions. The chlorinated polypropylene has chlorine content of 25-45 wt%; the additive is styrene, dimethyl acetamide or dimethyl sulfoxide; the initiator is bibenzoyl peroxide or diisopropyl benzene peroxide; and the tackifier is petroleum resin, rosin ester or terpene. The adhesive is ropy, and may be painted or extruded into film of 0.1-0.5 mm thickness when used. It has excellent adhering performance on metal, non-polar polymer, etc. and may be used widely.

Description

technical field [0001] The invention relates to a modified chlorinated polypropylene adhesive, in particular to a chlorinated polypropylene adhesive with strong adhesion to metal aluminum, steel, etc., and non-polar polymers such as polyethylene and polypropylene. Background technique [0002] Adhesives for metal-metal, aluminum-plastic composite pipes, and aluminum-plastic composite panels often use polyethylene grafts, ethylene-unsaturated acid or ester copolymers, etc. The bonding strength of polymers is not high, and the cost of ethylene-unsaturated acid or ester copolymers is high. More and more companies hope to use a new bonding material with high bonding strength and low price to replace the existing ones. Applications. [0003] Polypropylene materials are used as adhesives, and there are three main types of polypropylene provided: [0004] The first type is random polypropylene, whose properties are greatly affected by molecular weight and cry...

Claims

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Application Information

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IPC IPC(8): C09J123/28
Inventor 黄世强肖汉文孙争光王国成蒋涛余逢远
Owner HUBEI UNIV
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