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Etchant and etching method

An etchant and etching technology, applied in the manufacture of electrical components, circuits, semiconductor/solid-state devices, etc., can solve the problems of poor insulation resistance, insufficient coverage, increased exposed area, etc., and achieve the effect of improving the etching function

Inactive Publication Date: 2006-07-05
MITSUBISHI CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to this unfavorable etching method, there is such a problem in the portion subjected to undercutting that since the multilayer film has a non-tapered sectional shape after etching, the gate insulating film (for example, SiN x ) insufficient coverage, resulting in poor insulation resistance, etc.
There is also such a problem that when the upper side metal layer is undercut, the exposed area of ​​the lower side metal layer in this part will increase.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~7 and

[0074] Embodiment 1~7 and reference example 1~6

[0075] A molybdenum-niobium alloy layer (with a niobium content of 5% by weight) 3 with a thickness of 50 nm was deposited on the glass substrate by sputtering. AlCu (Al—Cu alloy; copper content: 5% by weight) was formed as an aluminum alloy layer 2 to a thickness of 300 nm by sputtering using argon gas on this layer. After that, the molybdenum-niobium alloy layer 1 having the same composition as above was continuously deposited to a thickness of 50 nm. Thus, forming as Figure 1A , Figure 1B and Figure 1C MoNb / AlCu / MoNb multilayer film shown.

[0076] A positive photoresist resin layer (about 1.5 μm in thickness) was further formed thereon by spin coating, and this layer was processed by photolithography to form a fine wiring pattern. The line width of this photoresist pattern is about 5 μm.

[0077] This substrate was cut into sheets having a width of about 10 mm and a length of 50 mm, and these sheets were used as etc...

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Abstract

Fluorescent probes represented by the general formula (I) wherein R<1> and R<2> are each hydrogen or a substituent for capturing a proton, a metal ion, or an active oxygen species; R<3> is a monovalent substituent except hydrogen, carboxyl, and sulfo; R<4> and R<5> are each hydrogen, halogeno, or alkyl; R<6> to R<9> are each alkyl; R<10> and R<11> are each hydrogen, halogeno, or alkyl; M<-> is a counter ion; and before the capture of a proton, a metal ion, or an active oxygen species, the combination of R<1>, R<2>, and R<3> gives the benzene ring to which they are bonded such a substantially high electron density as to make the compound substantially nonfluorescent, while after the capture of a proton, a metal ion, or an active oxygen species, the combination brings about such a substantial lowering in the electron density of the benzene ring to which they are bonded as to make the compound substantially highly fluorescent.

Description

technical field [0001] The present invention relates to an etchant for forming a pattern on a thin metal film by wet etching and an etching method using the etchant. More specifically, the present invention relates to an etchant and an etching method for etching a multilayer film including an aluminum alloy layer and a molybdenum-niobium alloy layer. Background technique [0002] Recently, electrodes and gate wiring materials used in semiconductor devices such as semiconductor elements and liquid crystal display elements are increasingly required to have a higher degree of microfabrication accuracy. In addition, it has been proposed to use metallic materials with lower electrical resistance. Examples of metal materials having lower resistance include aluminum and aluminum alloys, and these materials are being used more and more. [0003] Examples of techniques used to process thin films of the metal to form microstructures such as wiring include wet etching techniques in w...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23F1/16C23F1/20C23F1/26H01L21/306
CPCH01L21/32134C23F1/16C23F1/20C23F1/26
Inventor 齐藤范之吉田卓司井上和式石川诚上原口好夫
Owner MITSUBISHI CHEM CORP
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