Dye waste water treatment method based on membrane technology

A dye wastewater and treatment method technology, applied in the direction of adsorption water/sewage treatment, oxidation water/sewage treatment, osmosis/dialysis water/sewage treatment, etc., can solve the problems of long process flow, unstable effluent quality, teratogenicity, etc. To achieve the effect of overcoming the high cost of adsorption treatment

Active Publication Date: 2006-09-06
SANDA FILM SCI & TECH XIAMEN
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Problems solved by technology

The second is that as environmental pollutants, there are many kinds of dyes and complex structures
The third is that most dyes are toxic and refractory organic substances with strong chemical stability and have the "three causes" of carcinogenic, teratogenic and mutagenic
Although electrolysis and oxidation are effective in removing the chroma of dye wastewater, COD often Cr The removal is not ideal, the cost of treatment chemicals is relatively high, and many new oxidation methods are still in the stage of experimental research and have not been industrialized
[0014] In terms of biochemistry, azo dyes are typical fine chemical products. They have the characteristics of small batches and many varieties. Such unit operations should have many by-products, low product yields, and complex organic components in wastewa

Method used

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Embodiment Construction

[0030] The following is combined with the flocculation process figure 1 and figure 2 The present invention is further described.

[0031] First analyze the operation steps and process conditions as a whole

[0032] 1. Comprehensive regulation of filtration and wastewater

[0033] 1.1, filter

[0034] The dye waste water and domestic waste water stored in the waste water storage tank are mixed according to the measured ratio, and then filtered through slag filtration to remove the suspended matter, and the filtrate is stored in the waste water comprehensive pool to obtain comprehensive waste water.

[0035] 1.2. Comprehensive adjustment

[0036] Test the pH and COD value of the comprehensive wastewater. If necessary, add lye or low COD wastewater to adjust the pH value and COD. The pH should be controlled within the range of 6-9, and the COD should be controlled within 4000-8000mg / L. Take an appropriate amount of comprehensive wastewater, mix it with three different flocc...

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Abstract

The present invention discloses a method for treatment of dye waste water based on membrane technique, mainly comprising the part of fore treatment of dye waste water and the part of membrane filtration-seperation system. Fore treatment of dye waste water consists of techniques such as exhaust conditioning, flocculating setting and clarifying. Membrane filtration-seperation system consists of techniques such as hyperfiltration circulation and Na-filtration circulation. The invention is a new treatment of dye waste water based on membrane technique, characterized in that the CODCr and PH of the dye waste water is adjusted in the equalizing tank before it enters the membrane filtration-seperation system. Afterwards, the waste water is uniformly mixed in the flocculation retort and then deposits in the flocculation precipitating tank. The clarified solution is disposed by the treatment of hyperfiltration, the hyperfiltration dislysate is disposed by the treatment of Na-filtration, the Na-filtration dislysate is absorbed by the activated carbon, and as a result the water let meets the sewage discharge standard of two-level GB8978-96. The method is especially suitable for treatment of waste water of azo-dyes which is difficult to meet the discharge standard by the conventional waste treatment.

Description

technical field [0001] The invention relates to a method for treating wastewater, in particular to a method for treating dye wastewater, and belongs to the field of wastewater treatment for environmental protection. Background technique [0002] With the development of dyestuff and printing and dyeing industry, its production wastewater has become one of the most important sources of water pollution. As an important source of environmental pollution, dyes are characterized by a large amount of pollution. At present, the annual output of dyes in the world is about 800,000 to 900,000 tons, and the annual output of dyes in my country is 150,000 tons, ranking among the top in the world. %-15% of the dyes are discharged into the environment with the wastewater. my country's dye industry and textile printing and dyeing industry are developed, and the pollution of dye wastewater to the environment is more serious. According to the data in the Environmental Bulletin in 1998, the cur...

Claims

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Application Information

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IPC IPC(8): C02F1/52C02F1/44C02F1/76C02F1/28B01D61/14
Inventor 蓝伟光黄松青严滨林丽华饶金珠
Owner SANDA FILM SCI & TECH XIAMEN
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