Catayst for hydrogenation refining metal sulfer phosphorus compound
A hydrorefining and phosphide technology, applied in the direction of physical/chemical process catalysts, catalyst carriers, chemical/physical processes, etc., can solve the problems of unsatisfactory hydrodesulfurization and denitrification activity, unsatisfactory activity, etc., to achieve economic efficiency The effect of deep desulfurization, high catalytic reactivity, and wide application prospects
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[0012] Specific embodiments of the present invention will be described in detail below in conjunction with technical solutions.
[0013] Preparation of catalyst precursor:
[0014] Taking the preparation of silica-supported molybdenum-sulfur-phosphorus catalyst precursor by co-impregnation method as an example, MoO 3 The loading amount is 40% (mass). Take by weighing 3.65 grams of ammonium molybdate ((NH 4 ) 6 Mo 7 o 24 .4H 2 O) and 2.729 grams of diammonium hydrogen phosphate ((NH 4 ) 2 HPO 4 ), add 10 ml of deionized water, and dissolve to make an impregnation solution. Weigh 3 grams of porous silica, add impregnation solution, and impregnate at room temperature for 12 hours. The slurry was dried at 120°C for 12 hours, and then calcined in air at 500°C for 5 hours to obtain a dark blue solid.
[0015] Catalyst preparation:
[0016] The dark blue catalyst precursor is made into 0.3-0.5 mm particles by tableting, and 0.2 g is weighed and loaded into a fixed-bed rea...
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