91results about How to "Realize deep desulfurization" patented technology

A process for preparing low-sulfur low-arylhydrocarbon clean diesel oil includes such steps as hydrorefining/hydrocracking raw hydrocarbon to obtain intermediate fraction oil, catalytic stripping to separate light fraction from heavy fraction, hydrorefining the light fraction to remove residual S and impurities, and catalytic stripping of heavy fraction for removing sulfure and arylhydrocarbon to obtain final product. Its advantage is cyclic use of two reactino segments for low cost.

The invention provides a gasoline desulfurization method. The gasoline desulfurization comprises the following steps: cutting a gasoline raw material into a light gasoline fraction and a heavy gasoline fraction; performing adsorption desulfurization on the light gasoline fraction to obtain desulfurized light gasoline fraction; and performing selective hydrogenation desulfurization on the heavy gasoline fraction to obtain desulfurized heavy gasoline fraction, wherein the cutting temperature of the light gasoline fraction and the heavy gasoline fraction is 70-110 DEG C. By adopting the gasoline desulfurization method, not only can deep desulfurization of gasoline be realized, but also the octane loss is low.

The invention provides a method used for reducing the content of sulfide in light hydrocarbon oil, which comprises the steps as follows: after being preheated, a hydrocarbon oil raw material containing sulfur, and hydrogen donor enter a reactor filled with a sorbent and a zeolite additive so as to react under the conditions as follows: temperature of 300-500 DEG C, pressure of 0.5-3.5MPa, weight hourly space velocity of raw material oil at 0.5-10h<-1> and weight ratio between total amounts of the sorbent and the hydrocarbon oil raw material at 1-20; the materials are separated after reaction; the reaction products are sent to a subsequent separation system so that the product is separated; the sorbent to be regenerated and the zeolite additive to be regenerated after reaction are stripped, burned and regenerated; and the regenerated sorbent and the zeolite additive are reduced by the hydrogen donor and subsequently returned to the reactor so as to be circularly used. The method adds the zeolite additive during the adsorption desulfurization process, realizes deep desulfurization, leads the removal rate of the sulfur to achieve more than 96wt percent when disposing the gasoline, reduces the olefin of the gasoline, improves the octane number of the outcome gasoline simultaneously, keeps high liquid recovery and has low benzene content in the outcome gasoline.

The invention belongs to the technical field of fuel processing and petroleum chemical engineering, and relates to a novel nano ferrite adsorption desulfurization catalyst MeFe2O4, wherein Me comprises but not the same with Mg, Zn, Ni, Co and Cu. The preparation method comprises the following steps: dissolving transition metal nitrate, Fe-containing nitrate and fuels in water, heating the obtained solution in a microwave furnace rapidly, decomposing so as to generate a great quantity of combustible gases and emit a great amount of heat, and combusting reactants reaching the spontaneous ignition point; and reacting so as to obtain a solid material, namely the novel nano ferrite adsorption desulfurization catalyst. The novel nano ferrite adsorption desulfurization catalyst is relatively high in desulfurization selectivity, can prevent the loss of octane value and cetane value due to olefins hydrogenation while deeply removing sulfocompound in fuel oil, and has relatively good industrial application prospect.

The invention relates to a mesoporous material and particularly relates to a functionalized ordered mesoporous silicon material which is synthesized by taking polyacid-type ionic liquid as a raw material as well as an application of the mesoporous silicon material in oxidation desulfuration of fuel oil. According to the mesoporous silicon material, the polyacid-type ionic liquid is not only used as a template agent of the mesoporous material, but also used as a catalytic activity center, and transition metal is introduced into the mesoporous material structure in situ. A simple and nontoxic synthesis method of the metal-doped green mesoporous material is searched, has a favorable academical research value and also has a wide application prospect in the industrial production. The mesoporous silicon material as well as the preparation method and the application thereof have the advantages that the method is simple in process, and the mesoporous silicon material which is narrow in pore size distribution, regular and ordered in pore duct and good in thermal stability and has the pore size of 2-50nm is self-assembled under the guidance action of inorganic matters and organic matters by adopting a sol-gel method. The purpose of deep desulfuration can be achieved when the mesoporous silicon material is used as a catalyst for an oxidation removing reaction process of organic sulfides.

The invention discloses a hydrogenation modification method for coking gasoline and diesel distillates. A coking gasoline and diesel raw material is mixed with heated hydrogen and then introduced to pass through a low-temperature hydrorefining reactor and a hydrogenation modification reactor in sequence; a reaction effluent is separated and modified, and obtained liquid is distilled to obtain gas, gasoline, kerosene and diesel. In the method disclosed by the invention, a process flow of mixing hydrogen behind a furnace is adopted, the heating furnace is only used for heating the hydrogen, the mixed raw material does not pass through the heating furnace, and the temperature of the reactor is controlled based on the quantities of hot hydrogen and cold hydrogen. Compared with the prior art, the hydrogenation modification method disclosed by the invention has the advantage of saving equipment investment and being flexible in production scheme, can be used for flexible production by adjusting process conditions and production distribution according to the differences of raw material properties and product schemes; by implementation of hydrogen mixing behind the furnace, the coking raw material can be effectively prevented from being coked at a furnace tube; and by arrangement of a low-temperature protective agent reactor, olefin saturation is performed at lower temperature so as to reduce coking, meanwhile, coke powder is distributed at a protective agent bed as uniform as possible, so that the long-term operation of a hydrogenation device is ensured.

The invention specifically relates to a high-selectivity compound desulfurizer and a preparation method thereof, belonging to the field of gas purification techniques. The high-selectivity compound desulfurizer comprises the following raw materials by weight: 60-80 parts of N-methyldiethanolamine, 1-3 parts of an eutectic solvent, 10-30 parts of sterically hindered amine, 0.5-1.5 parts of a non-silicon defoaming agent and 4-8 parts of an antioxidant. The compound desulfurizer provided by the invention overcomes the shortcomings of current refinery gas desulfurization processes, and is simple in process and applicable to desulfurization of most refinery acidic gases. According to the invention, N-methyldiethanolamine, the eutectic solvent and sterically hindered amine are compounded, and the supplementation effect and synergism of the above three components enhance the respective desulfurization effect of the components; and the high-selectivity compound desulfurizer has high purification depth, large absorption capacity, low energy consumption for regeneration, environment friendliness and other advantages.

The invention discloses a method for preparing supported molybdenum-oxide-based and tungsten-oxide-based oxidation desulfurization catalysts, belonging to the technical fields of coal processing, petroleum processing and petrochemical industry and relating to a method for preparing catalysts for removing thiophene-type heteroaromatic sulfide-containing solids from distillate oil and chemical materials by oxidation. The method is characterized by preparing the catalysts in a way of implementing plasma treatment on the molybdenum-oxide-based or the tungsten-oxide-based catalyst supported by a porous supporter under a hydrogen or inert gas atmosphere. The method has the effect and the benefit of remarkably enhancing the oxidation desulfurization activity of the supported molybdenum-oxide-based and tungsten-oxide-based catalysts, and has wide application prospect in the field of deep desulfurization.

The present invention provides catalytic oxidizing process for deeply removing sulfide in petrol. The process adopts solid titanium contaniing molecular sieve as catalyst and hydrogen peroxide solution as oxidant to oxidize main sulfide in petrol at 40-80 deg.c and normal pressure without H2 consumption; and the oxidized product is removed via extraction with methanol, acetonitrile, butanol, water or their mixture. The said process can eliminate 80-90% of sulfide from petrol and lower the sulfur content of FCC petrol from 136 ppm to 18 ppm. The process of the present invention has mild reaction condition, simple apparatus and easy-to-recover catalyst and can realize deep desulfurizing.

The invention discloses a method used for catalytic gasoline deep hydrodesulfurization. The method comprises following steps: catalytic gasoline is delivered into a prefrationation tower firstly; an appropriate separation point is adopted, light gasoline fraction and middle gasoline fraction are discharged through the top of the prefrationation tower, and heavy gasoline fraction is discharged through the bottom of the prefrationation tower; the light gasoline fraction and the middle gasoline fraction are subjected to alkali-free deodorization, and are delivered into a hydrogenation prefrationation tower so as to separate light gasoline and middle gasoline, wherein catalytic cracking hot diesel oil extracted from a main fractionate tower side line is also delivered into the hydrogenation prefrationation tower; separated middle gasoline and heavy gasoline are mixed, and are subjected to selective hydrogenation, and an obtained distillate is mixed with light gasoline obtained via alkali-free deodorization so as to obtain clean gasoline products. Compared with existing catalytic gasoline hydrodesulfurization method, the method and equipment of the invention is capable of reducing energy consumption greatly, octane value loss of the gasoline products is less, sulfur content of the gasoline products is less than 10<mu>g/g, and economic benefits of oil refining enterprises are improved.

The invention provides an MOF supported metal peroxide catalyst. The catalyst comprises a metal organic skeleton carrier and a metal peroxide species MO(O2)2, wherein M represents Mo6 or W6+. The catalyst is prepared in the mode that in the metal organic skeleton material synthesizing process, MO(O2)2 with catalytic oxidation activity is anchored to a metal organic skeleton material through a pre-modification or post-modification method. According to the catalyst, metal peroxide is highly dispersed on a crystal skeleton, and the metal peroxide species is coordinated with organic ligand based on dipyridyl chelation locus, so that high stability is kept; when applied to an oxidation sweetening reaction, high activity and stability are kept, and the catalyst has important industrial application value.

The invention provides a circulating fluidized bed boiler and a desulfurization method. The circulating fluidized bed boiler comprises an in-furnace desulfurization system and an out-furnace desulfurization system which are communicated in sequence, wherein the in-furnace desulfurization system comprises a hearth; the hearth is provided with a first inlet, the circulating fluidized bed boiler further comprises a limestone conveying pipeline and a quicklime conveying pipeline, and the limestone conveying pipeline and the quicklime conveying pipeline are communicated with the first inlet. In thewhole process of starting the circulating fluidized bed boiler, when the boiler does not reach the optimal temperature range of the limestone reaction, quicklime (calcium oxide) as a desulfurizing agent is first directly adopted for directly reacting with sulfur dioxide in flue gas in the hearth for desulfurization reaction; when the optimal reaction temperature range of the in-furnace limestonedesulfurization system reaches in the boiler, an out-furnace circulating fluidized bed ash circulation system is established, limestone is fed into by the limestone conveying pipeline for desulfurization of sulfur-containing flue gas, high calcium oxide content in the hearth can be kept all the time so as to achieve the efficient desulfurization effect in the furnace.

The invention discloses a preparation and application method of an oil-soluble oil product oxidation desulfurizing agent, relating to a preparation and application method of an oil product desulfurizing agent, and solving the problems of poor intermiscibility of a traditional diesel oil oxidation desulfurizing agent with diesel oil and complex desulfurizing process. The preparation method of the oil-soluble oil oxidation desulfurizing agent comprises the step of leading low-carbon aldehyde compound and oxygen into a trickle bed reactor for reaction under trace amount of catalyst to obtain the oxidation desulfurizing agent which is structurally an organic peroxide, wherein the molar ratio of the low carbon aldehyde compound to the oxygen is 2:1-1:10. The desulfurizing method comprises the following steps of: under normal pressure and temperature, directly adding the oxidation desulfurizing agent into an oil product; stirring for reacting for 5-100 minutes; and then extracting sulphone and/or sulfoxide which are generated from the reaction by using a polar extracting agent. By using the oil-soluble oil oxidation desulfurizing agent, a deep desulfurization of the oil product can be realized and sulphur content in the oil product is reduced below 10 mg/g.

The invention discloses a preparation method for titanium-containing hierarchical porous structure mesoporous molecular sieve catalyst. The preparation method for the titanium-containing hierarchical porous structure mesoporous molecular sieve catalyst uses peroxotitauium acid as titanium source and uses mesoscopic compound composed of cationic surface active agent-hexadecyl trimethyl ammonium bromide (CTAB) and anionic polyelectrolyte (PAA) as a dynamic template to synthesize to form a hierarchical porous structure mesoporous titanium silicalite molecular sieve; the prepared titanium-containing hierarchical porous structure mesoporous molecular sieve catalyst is used for the oxidative desulfurization reaction which uses dibenzothiophene (DBT) as model sulfide. The preparation method for the titanium-containing hierarchical porous structure mesoporous molecular sieve catalyst has advantages that the catalyst is capable of catalyzing the oxidizing reaction of the thiophene sulfur compound under a low temperature and realizing deep desulfurization; the catalyst preparation method is simple in technique, easy to implement and good for industrial production.

The invention discloses a method for producing ultralow-sulfur steel by using an LF and VD duplex technology. The method comprises the following steps: carrying out desulfurization and slagging-off pretreatment on molten iron to obtain pretreated molten iron; smelting the pretreated molten iron, low-sulfur waste steel and auxiliary materials to obtain smelted molten steel; carrying out tapping of the smelting molten steel to obtain the tapped molten steel; adding refining slag into the tapped molten steel for LF furnace refining to obtain refined molten steel and first refined final slag; controlling the first refining final slag, wherein W (FeO + MnO) is less than or equal to 1.5%, and the binary alkalinity R = CaO/SiO2 = 5.0-8.0; and subjecting he refined molten steel to VD vacuum refining to obtain ultralow-sulfur molten steel and second refined final slag, wherein the vacuum treatment time is 12-20 min, the bottom blowing flow of a steel ladle is 50-150 NL/min, and the vacuum degree is controlled to be less than or equal to 100 Pa; Stable control of ultralow sulfur less than or equal to 0.0010% is achieved by using the LF and VD duplex technology.

The invention provides a quality upgrading method for high olefin catalytic cracking gasoline. The method includes the steps of: conducting prehydrogenation on catalytic cracking gasoline to obtain prehydrogenated catalytic cracking gasoline; cutting the prehydrogenated catalytic cracking gasoline into light fraction, medium fraction and heavy fraction; conducting etherification or catalytic cracking on the light fraction; subjecting the medium fraction to solvent extraction to obtain olefin-rich raffinate oil and aromatic hydrocarbon-rich extracted oil; conducting light olefin recovery on theextracted oil to obtain light olefin and sulfur-rich oil; returning at least a part of the light olefin to the solvent extraction system for backwashing; conducting mitigated aromatization on at least one of the raffinate oil and the other part of the light olefin; and subjecting the heavy fraction and sulfur-rich oil to selective hydrodesulfurization, thus obtaining desulfurized heavy fraction.The method provided by the invention can improve the octane number of gasoline products while lowering the sulfur content and olefin content.

The invention discloses slag for controlling the impurities of pipeline steel. The slag comprises the following components in weight percentage: 50-62% of CaO, 3.2-6.0% of SiO2, 24-30% of Al2O3, 3-8% of CaF2, 3-6% of MgO, 0.3-2.0% of FeO+MnO, and the balance of unavoidable impurities; and the ratio of CaO/SiO2 is 9-16. The slag for controlling the impurities of the pipeline steel is the slag for refining a steel ladle, which has a high basicity, low aluminum oxide content, low oxidability and good fluidity; the slag can control the basicity of steel ladle slag and the content of the components including the Al2O3 and the like, and reduces the oxidability, so that the steel ladle slag has the functions of improving liquid steel cleanness and controlling the impurities in the steel; the desulfuration and the deoxygenation of the liquid steel, and the control of the impurities are realized; and the quality of the liquid steel is improved.

The invention provides a method for upgrading high-olefin FCC (fluid catalytic cracking) gasoline. The method comprises the following steps: prehydrogenating FCC gasoline to obtain prehydrogenated FCCgasoline; cutting the prehydrogenated FCC gasoline into light fraction, medium fraction and heavy fraction; performing etherification or catalytic cracking on the light fraction; performing solvent extraction on the medium fraction to obtain olefin-rich raffinate and arene-rich extracted oil; recovering light olefins from the extracted oil to obtain light olefins and sulfur-rich oil; returning one part of light olefins to a solvent extraction system for backwashing, and performing catalytic cracking reprocessing or selective hydrodesulfurization on the other part of light olefins; performingselective hydrodesulfurization on the heavy fraction and the sulfur-rich oil to obtain desulfurized heavy fraction. With adoption of the method, octane number of a gasoline product can be increased while sulfur content and olefin content are reduced.

The invention provides a deoxidizing alloying agent capable of purifying molten steel and a preparation method thereof. The components of the deoxidizing alloying agent include, by weight percentage,30-50% of aluminum, 2-6% of silicon carbide, 2-6% of calcium aluminate, and 5-45% of one or more of niobium, vanadium, titanium, manganese, nickel, chromium, copper, molybdenum and silicon; and particle sizes are 5-50 mm. During preparation, metal aluminum and industrial pure iron can be melted in an induction furnace crucible according to the finished product content; the metal niobium, vanadium,titanium, manganese, nickel, chromium, copper, molybdenum and silicon can be added; spiral electromagnetic stirring can be simultaneously applied, the current of the spiral electromagnetic stirring is 150-250 A, and the frequency is 2.5-4 Hz; the silicon carbide and calcium aluminate fine powder can be added after the added metal is completely melted; the power supply of the induction furnace canbe stopped after 5-10 min of stirring; the spiral electromagnetic stirring can be continued until alloy is solidified; and a crusher can be utilized to crush alloy ingots into small pieces with a particle size of 5-50 mm, and packaging can be performed for later use. The full uniformization of the alloy and the silicon carbide and calcium aluminate fine powder can be guaranteed by adopting a spiral electromagnetic stirring technology; the full purifying molten steel of the calcium aluminate can be guaranteed; and deoxidizing alloying time can be saved.