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TiC-WC based alloy products

A technology for base alloys and products, applied in the field of TiC-WC base alloy products, can solve the problems of low hardness and high temperature strength, excessive liquid phase, poor wear resistance, etc., and achieve strong corrosion resistance and oxidation resistance, strength And the effect of high hardness and uniform metallographic structure

Active Publication Date: 2006-11-22
ZIGONG CEMENTED CARBIDE CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

First of all, the composition of the binder phase is as high as 40wt% or more. Although the high content of the binder phase can improve the bending strength of the alloy, it also reduces the wear resistance and hardness at the same time. Deformation; Second, adding Mo (molybdenum) element to the alloy composition, although Mo can wet TiC to make sintering densified, but at the same time it will form a brittle phase and wrap around TiC particles to reduce the strength of the alloy, especially the high temperature strength ;Third, there are TiC, TiC-WC, TiC-Mo in the structure of the alloy at the same time 2 C, WC and solid solution bonding are equal to 5 phases, and the phase composition is complex and difficult to control
Therefore, the above background technology has defects such as low hardness and high temperature strength, poor wear resistance, difficult sintering control of products, poor molding accuracy and stability, and short service life.

Method used

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  • TiC-WC based alloy products

Examples

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Effect test

Embodiment 1

[0008] Embodiment 1: the present embodiment is example (by every batch of 100kg batching) with the production of guide rollers for high-speed wire rod rolling:

[0009] A. Wet milling ingredients: put 56.5kgTiC, 18kgWC, 14kgNi, 10kgCo and 1.5kgCr powders that meet the industrial production standards in the ball mill, and after warm milling and mixing for 64 hours, add 2.0kg of paraffin and continue ball milling to mix evenly, and the slurry passes through 320 Mesh sieve, the resulting mixed powder is sent to a vacuum dryer and dried at a temperature of 100°C to remove the wet grinding medium, after cooling, the mixed powder is obtained through homogenization treatment; the wet grinding medium in this embodiment is hexane;

[0010] B. Compression molding and pre-sintering: Put the mixed powder into the mold and press it into the blank of the guide roller; then put it into the vacuum furnace and calcinate it at 500°C for 75 minutes to remove the paraffin and cool it with the furn...

Embodiment 2

[0013] Embodiment 2: Taking the production of wear-resistant and corrosion-resistant ball valve cores and valve seats as an example (by every batch of 100kg ingredients):

[0014] A. Wet grinding ingredients: 30kgTiC, 54kgWC, 7.5kgNi, 7.5kgCo and 1.0kgTa powders for industrial use are placed in the ball mill; the following processes and parameters (including steps B and C) are the same as in Example 1.

[0015] The product of this embodiment is tested: density 9.0g / cm 3 , hardness HRA≥90.5, bending strength 2000N / mm 2 , Porosity A 02 B 00 C 00 .

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Abstract

The invention discloses a TiC-WC base alloy guide roll and spool, valve seat in the metal ceramic and hard alloy manufacturing domain, which comprises the following parts: 30-60 wt percent TiC, 15-55 wt percent WC and 0-3 wt percent Ta as hard phase, 10-30 wt percent Co+Ni as adhesive phase and 0-3.0 wt percent Cr as grain growing inhibitor. The density of product is 0.3-0.5 times as WC base hard alloy density with 2500 N per mm2 anti-bending strength and 87.0-90.5 percent rigidity HRA, which possesses light quality, high rigidity and abrasion-proof property.

Description

technical field [0001] The invention belongs to TiC-WC base alloy products in the field of cermet and cemented carbide production, in particular a guide roller and a spool valve with TiC and WC as the main hard phase and Ni / Co as the bonding phase Seats and other alloy products. Background technique [0002] The guide rollers, guide rollers, pinch rollers and other guide rollers used to transport the rolled red steel of wire and bar to the roll groove on the high-speed wire rolling line to prevent accidents such as steel winding and tail flicking, etc., due to long-term Working under the harsh conditions of high temperature of 900-1100 ℃ and a speed of about 35000 rpm, the requirements for high-temperature strength, high-temperature wear resistance, oxidation resistance and the density (specific gravity) of the components are relatively high. Traditional guide rollers are generally made of cast steel and high-speed steel. Although they have the advantages of wide source of ...

Claims

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Application Information

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IPC IPC(8): C22C29/06
Inventor 于绍武黄宇王晓灵
Owner ZIGONG CEMENTED CARBIDE CORP
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