Etch combination

A composition and etching technology, applied in the preparation of surface etching composition, detergent composition, detergent mixture composition, etc., can solve the problems of large amount of waste liquid, large amount of etchant used, and increased cost. Achieve the effect of simplifying the process and improving the uniformity of etching

Inactive Publication Date: 2010-04-14
DONGJIN SEMICHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the problem is that the equipment is expensive, it is difficult to enlarge the area, and the productivity is lowered due to the slow etching rate.
However, there are problems in that the amount of etchant and pure water used is large, and the amount of waste liquid is large
[0014] However, there is a problem when using the above-mentioned conventional etching composition to etch the Mo film constituting the metal film for the source / drain electrode of the thin-film transistor liquid crystal display device. Poor step coverage of the laminated upper film in the subsequent process
[0015] In addition, if the Al-Nd / Mo double-layer film and the Mo / Al-Nd / Mo three-layer film for the gate electrode of the TFT constituting the thin-film transistor liquid crystal display device are etched with the above-mentioned conventional etchant or etching solution composition , then there is a problem that will produce such as Figure 8 The protrusion phenomenon of the upper Mo film and the undercut phenomenon of the lower Al-Nd or Mo film are shown. The protrusion phenomenon of the upper film must be removed by an additional process, and the undercut phenomenon of the lower film will cause the upper film to be inclined. Disconnection occurs on the surface or the upper and lower metals are short-circuited on the inclined surface
However, if wet etching and dry etching are used at the same time in this way, there are problems of reduced productivity and increased cost due to troublesome processes, which is disadvantageous.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0065] 63% by weight of phosphoric acid, 4% by weight of nitric acid, 17% by weight of acetic acid, 1% by weight of K 3 PO 4 (as a phosphate), 0.005% by weight of sulfonylimide fluoroalkylammonium (as an anionic surfactant), and the remaining amount of water were uniformly mixed to prepare an etching composition.

[0066] Applying the above etching composition to Mo monolayer films, the results are as follows figure 1 As shown, it was confirmed that the profile was excellent, and the profile angle was 50 degrees to 70 degrees.

Embodiment 2 and comparative example 1~2

[0068] Except having used the composition ratio shown in following Table 1 in said Example 1, the method similar to said Example 1 was implemented and the etching composition was manufactured. In this case, the unit in Table 1 below is % by weight.

[0069] [Table 1]

[0070]

[0071] The performance of the etching composition produced by the above-mentioned embodiment 1 or 2 and comparative example 1 or 2 is evaluated by the following conventional method, and the results are shown in the following table 2 and Figure 2 ~ Figure 6 shown.

[0072] At first form Mo / Al-Nd double-layer film, Mo / Al-Nd / Mo three-layer film and Mo single-layer film respectively by sputtering on glass substrate, then coat photoresist, will be by embodiment 1 or 2 and the etching composition produced in Comparative Example 1 or 2 were sprayed on the test piece in which the pattern was formed by development, and an etching process was performed. Next, after etching, the cross-section was observed w...

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PUM

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Abstract

The invention provides a etching compound, using said compound to carry out wet etching for TFT grid wiring material Al-Nd / Mo bilaminar membrane or Mo / Al- Nd / Mo three-layer membrane, which forms film transistor liquid crystal displayer, the wet etching employs single process by way of no undercut by lower membrane Al- Nd or Mo; the taper is good and configuration of Mo monolayer film of source / drain wiring material is outstanding. The etching compound comprises phosphoric acid, aqua fortis, acetic acid, acetic acid surface activator and water.

Description

technical field [0001] The present invention relates to the etching composition of metal film for gate electrode and metal film for source / drain electrode of thin-film transistor liquid crystal display device, more specifically, the present invention relates to following etching composition, adopt described composition, can the following Al-Nd or Mo film Al-Nd / Mo double-layer film or Al-Nd / Mo double-layer film or The Mo / Al-Nd / Mo three-layer film is subjected to wet etching, and excellent taper can be obtained, and at the same time, the source / drain wiring material Mo single-layer film can also form an excellent profile. Background technique [0002] The etching process is a process of forming extremely fine circuits on the substrate, and forms the same metal pattern as the photoresist pattern formed by the development process. [0003] The etching process is roughly divided into wet etching and dry etching according to the method. Wet etching uses acid (acid) chemicals to r...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L21/306C23F1/16
CPCC09K13/04C11D1/02C11D11/0047C23F1/20C23F1/30G02F1/136H01L21/30604H01L21/31111
Inventor 李骐范曺三永申贤哲金南绪
Owner DONGJIN SEMICHEM CO LTD
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