Processing of titanium-aluminum-vanadium alloys and products made thereby

a technology of titanium alloy and titanium alloy, which is applied in the direction of metal rolling arrangement, etc., can solve the problems of high energy input requirements, high cost of finished ballistic plate, and high cost of production process for producing ballistic armor plate from above titanium alloys

Inactive Publication Date: 2004-11-11
ATI PROPERTIES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

0013] Certain methods described in the present disclosure incorporate the use of cold working techniques, which were not heretofore believed suitable for processing the Kosaka alloy. In particular, it was conventionally believed that the Kosaka alloy's resistance to flow at temperatures significantly below the .alpha.-.beta. hot rolling temperature range was too great to allow the alloy to be worked successfully at such temperatures. With the present inventors' unexpected discovery that the Kosaka alloy may be worked by conventional cold working techniques at temperatures less than about 1250.degree. F. (about 677.degree. C.), it becomes possible to produce myriad product forms that are not possible through hot rolling and / or are significantly more expensive to produce using hot working techniques. Certain methods described herein are significantly less involved than, for example, the conventional pack rolling technique described above for producing sheet from Ti-6Al-4V. Also, certain methods described herein do not involve the extent of yield losses and the high energy input requirements inherent in processes involving high temperature working to finished gauge and / or shape. Yet an additional advantage is that certain of the mechanical properties of embodiments of the Kosaka alloy approximate or exceed those of Ti-6Al-4V, which allows for the production of articles not previously available from Ti-6Al-4V, yet which have similar properties.

Problems solved by technology

Moreover, the process for producing ballistic armor plate from the above titanium alloys can be involved and expensive.
This complicates the fabrication process, results in yield losses, and increases the cost of the finished ballistic plate.
However, it is generally believed that it is not possible to readily apply fabrication techniques other than simple hot rolling to many of these high-strength titanium alloys.
The process is expensive and may have a low yield given the necessity to grind and pickle the surfaces of the individual sheets.
In particular, it was conventionally believed that the Kosaka alloy's resistance to flow at temperatures significantly below the .alpha.-.beta. hot rolling temperature range was too great to allow the alloy to be worked successfully at such temperatures.
), it becomes possible to produce myriad product forms that are not possible through hot rolling and / or are significantly more expensive to produce using hot working techniques.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0036] 0 Seamless pipe was prepared by extruding tubular hollows from a heat of the Kosaka alloy having the nominal composition Ti-4Al-2.5V-1.5Fe-0.25O.sub.2. The actual measured chemistry of the alloy is shown in Table 4 below:

4 TABLE 4 Alloying Element Content Aluminum 4.02-4.14 wt. % Vanadium 2.40-2.43 wt. % Iron 1.50-1.55 wt. % Oxygen 2300-2400 ppm Carbon 246-258 ppm Nitrogen 95-110 ppm Silicon 200-210 ppm Chromium 210-240 ppm Molybdenum 120-190 ppm

[0037] The alloy was forged at 1700.degree. F. (about 927.degree. C.), and then rotary forged at about 1600.degree. F. (about 871.degree. C.). The calculated T.sub.62 of the alloy was approximately 1790.degree. F. (about 977.degree. C.). Two billets of the hot forged alloy, each having a 6 inch outer diameter and 2.25 inch inner diameter, were extruded to tubular hollows having 3.1 inch outer diameter and 2.2 inch inner diameter. The first billet (billet #1) was extruded at about 788.degree. C. (about 1476.degree. F.) and yielded abou...

example 2

[0041] Additional billets of the hot-forged Kosaka alloy of Table 5 described above were prepared and successfully extruded to tubular hollows. Two sizes of input billets were utilized to obtain two sizes of extruded tubes. Billets machined to 6.69-inch outer diameter and 2.55-inch inner diameter were extruded to a nominal 3.4-inch outer diameter and 2.488-inch inner diameter. Two billets machined to 6.04-inch outer diameter and 2.25-inch inner diameter were extruded to a nominal 3.1-inch outer diameter and 2.25-inch inner diameter. The extrusion occurred at an aimpoint of 1450.degree. F. (about 788.degree. C.), with a maximum of 1550.degree. F. (about 843.degree. C.). This temperature range was selected so that the extrusion would take place at a temperature below the calculated T.sub..beta. (about 1790.degree. F.) but also sufficient to achieve plastic flow.

[0042] The extruded tubes exhibited favorable surface quality and surface finish, were free from visible surface trauma, were...

example 3

[0043] Several coupons of the .alpha.-.beta. titanium alloy of Table 5 hot forged as described in Example 1 above were rolled to about 0.225-inch thick in the .alpha.-.beta. range at a temperature of 50-15.sup.0.degree. F. (about 28.degree. C. to about 83.degree. C.) below the calculated T.sub..beta.. Experimentation with the alloy indicated that rolling in the .alpha.-.beta. range followed by a mill anneal produced the best cold rolling results. However, it is anticipated that depending on the results desired, the rolling temperature might be in the range of temperatures below T.sub.62 down to the mill anneal range.

[0044] Prior to cold rolling, the coupons were mill annealed, and then blasted and pickled so as to be free of a case and oxygen-enriched or stabilized surface. The coupons were cold rolled at ambient temperature, without application of external heat. (The samples warmed through adiabatic working to about 200-300.degree. F. (about 93.degree. C. to about 149.degree. C.), ...

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Abstract

A method of forming an article from an alpha-beta titanium including, in weight percentages, from about 2.9 to about 5.0 aluminum, from about 2.0 to about 3.0 vanadium, from about 0.4 to about 2.0 iron, from about 0.2 to about 0.3 oxygen, from about 0.005 to about 0.3 carbon, from about 0.001 to about 0.02 nitrogen, and less than about 0.5 of other elements. The method comprises cold working the alpha-beta titanium alloy.

Description

FIELD OF THE INVENTION[0001] The present invention relates to novel methods of processing certain titanium alloys comprising aluminum, vanadium, iron, and oxygen, to articles made using such processing methods, and to novel articles including such alloys.DESCRIPTION OF THE INVENTION BACKGROUND[0002] Beginning at least as early as the 1950's, titanium was recognized to have properties making it attractive for use as structural armor against small arms projectiles. Investigation of titanium alloys for the same purpose followed. One titanium alloy known for use as ballistic armor is the Ti-6Al-4V alloy, which nominally comprises titanium, 6 weight percent aluminum, 4 weight percent vanadium and, typically, less than 0.20 weight percent oxygen. Another titanium alloy used in ballistic armor applications includes 6.0 weight percent aluminum, 2.0 weight percent iron, a relatively low oxygen content of 0.18 weight percent, less than 0.1 weight percent vanadium, and possibly other trace ele...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C22C14/00C22F1/18
CPCC22C14/00C22F1/183B21B1/26C22F1/18
Inventor HEBDA, JOHN J.HICKMAN, RANDALL W.GRAHAM, RONALD A.
Owner ATI PROPERTIES
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