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Engine antifreeze composition

a technology of composition and engine, applied in the direction of heat exchange elements, chemical instruments and processes, etc., can solve the problems of loss of efficacy, inability to access suitable water for cooling system use, and inability to achieve the effects of reducing corrosion of metal surfaces

Inactive Publication Date: 2006-02-16
FLEETGUARD INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention provides novel coolant compositions for engines that can reduce corrosion and improve cooling efficiency. The coolant compositions include an organic acid component, an anti-corrosion additive, and a buffer agent. The organic acid component can be a mixture of a C4-C6 dicarboxylic acid and at least one of benzoic acid or a C9-C12 aliphatic dicarboxylic acid. The anti-corrosion additive can include molybdate, and the buffer agent can be a sodium salt of at least one of a borate salt or a phosphate salt. The coolant compositions can also include hard water. The invention also provides a method for reducing corrosion of metal surfaces in a cooling system by adding the coolant composition described herein.

Problems solved by technology

Despite the specificity which these coolant compositions are formulated, the benefits associated with many of the additives can be thwarted because a large percentage of operators include hard water in the cooling system.
In many parts of the world, there is no ready access to suitable water for use in cooling system.
These minerals may contribute to loss of efficacy and reduce the usable lifetime of the coolant composition.
This loss can be particularly detrimental to heavy duty diesel trucks that can cover over 10,000 miles a month.
An ineffective coolant composition can shorten engine life, allow internal passageways in the cooling system to clog, contribute to cylinder liner pitting and water pump cavitation all which result in costly engine overhauls.

Method used

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Examples

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example

[0036] Five coolant compositions listed as Examples 1-5 in Table 1 were prepared by combining the specific indicated components listed in the table in a fully formulated base antifreeze solution that included, in percent by weight based on the final total weight of the final antifreeze formulation, 95% ethylene glycol, sodium borate (0.20%); sodium molybdate (0.30%); mercaptobenzothiazole (MBT) (0.40%, 50% active); tolyltriazole (0.20%); sodium silicate (0.10%) as well as surfactants, scale inhibitors and defoamers (0.05%) to provide a concentrated coolant composition. Each of the concentrated coolant compositions was then diluted with water having a hardness of about 300 ppm and a pH between about 8.3 and about 8.5 to provide the coolant compositions listed as examples 1-5. These coolant compositions were then evaluated according to ASTM D-2809 Standard Text Method for Cavitation Corrosion and Corrosion and Erosion-Corrosion Bench Test described below.

TABLE 1*Concentrated Coolant...

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Abstract

In general this invention relates to an antifreeze composition that can be used in the cooling systems of internal combustion engines, for example, in heavy-duty diesel engines, light duty trucks and cars. The antifreeze composition can be added to water or other suitable liquid coolant in the cooling system, to lower the freezing point temperature of the coolant and inhibit corrosion of metallic components associated with the cooling system. The antifreeze composition is particularly well suited, although not exclusively, for use with hard water. The antifreeze composition includes an organic acid component comprising adipic acid and at least one of benzoic acid and one or more C9-C12 dicarboxylic acid—or salts of these acids. The antifreeze composition also includes other anti-corrosive additive, for example, molybdate, nitrite, nitrate silicate azoles and a variety of buffer agents.

Description

FIELD OF THE INVENTION [0001] In general, this invention is related to a coolant composition. More specifically, but not exclusive, this invention is directed to a coolant composition that includes anti-corrosion additives for use in combustion engines and a method of inhibiting the corrosion of components in cooling systems. BACKGROUND OF THE INVENTION [0002] Typically coolant compositions are specifically formulated with ethylene glycol or propylene glycol or their derivatives and include specific additives that inhibit and reduce corrosion of coolant systems. Specific coolant formulations are desired because with the advent of higher performance engines, particularly heavy-duty diesel engines, increasing more components of these engines are manufactured from a wide variety of materials to reduce weight and increase efficiency. Similarly, the coolant coursing through these engines contact a variety of materials. Typically additives are selected to impart particular benefits, such ...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C09K5/00C09K5/08C09K5/20C23F11/08C23F11/16
CPCC23F11/08C09K5/20
Inventor HUDGENS, R. DOUGLAS
Owner FLEETGUARD INC
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