Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Secondary cell electrode and fabrication method, and secondary cell, complex cell, and vehicle

a technology of secondary cells and electrodes, applied in the field of secondary cells, can solve problems such as the reduction of cell performance such as charge or discharge capacity

Inactive Publication Date: 2009-07-09
NISSAN MOTOR CO LTD
View PDF10 Cites 22 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention provides a secondary cell electrode that works even at a high current rate by using an electrode active material layer low of the resistance to diffusion of Li ions supplied from an electrolyte layer, with a changed constitution of electrolyte in a patterning of the layer. This results in a three-dimensional uniformly concentrated electrode with improved performance such as charge or discharge capacity. The invention also provides a fabrication method for the electrode and a secondary cell, complex cell, and vehicle employing the secondary cell.

Problems solved by technology

As will be discussed later, such a laminate cell suffers an unfavorable tendency for Li ions to be exhausted in a charge or discharge at a high current rate, resulting in a reduced cell performance such as charge or discharge capacity.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Secondary cell electrode and fabrication method, and secondary cell, complex cell, and vehicle
  • Secondary cell electrode and fabrication method, and secondary cell, complex cell, and vehicle
  • Secondary cell electrode and fabrication method, and secondary cell, complex cell, and vehicle

Examples

Experimental program
Comparison scheme
Effect test

first embodiment

3.1 Examples of First Embodiment

[0459]The first embodiment is exemplified below.

3.1.1 Example-1

3.1.1a Preparation of positive electrode ink

[0460]A quantity (90 g in weight) of spinel structure LiMn2O4 (particle size: 0.6 μm in average) as a positive electrode active material, a quantity (5 g in weight) of acetylene black as an electrically conductive material, and a quantity (5 g in weight) of polyvinylidene fluoride as a binder were mixed, and as a solvent to this mixture a quantity (300 g in weight) of acetonitrile was admixed, thereby preparing a kind of slurry as a positive electrode ink-1. The positive electrode ink-1 had a viscosity of 3 cP at a temperature of 25° C.

[0461]Next, the positive electrode active material, electrically conductive material, and binder were mixed in the same amounts as those of the positive electrode ink-1, and as a solvent to this mixture a quantity (500 g in weight) of acetonitrile was admixed, thereby preparing another kind of slurry as a positive ...

second embodiment

3.2 Examples of Second Embodiment

[0489]The second embodiment is exemplified below.

3.2.1 Example-2

3.2.1a Preparation of Positive Electrode Ink

[0490]A quantity (90 g in weight) of spinel structure LiMn2O4 (particle size: 0.6 μm in average) as a positive electrode active material, a quantity (5 g in weight) of acetylene black as an electrically conductive material, a quantity (5 g in weight) of polyvinylidene fluoride as a binder, a quantity (40 g in weight) of LiBETl as an electrolyte salt, a quantity (40 g in weight) of macromer of ethylene oxide and propylene oxide as an electrolyte polymer synthesized in accordance with a method described in Japanese Patent Application Laid-Open Publication No. 2002-110239, and a quantity (0.1 mass % of the electrolyte polymer) of benzyldimethyl-ketal as a photochemical polymerization initiator were mixed, and as a solvent to this mixture a quantity (820 g in weight) of acetonitrile was admixed, thereby preparing a kind of slurry as a positive elec...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
thicknessaaaaaaaaaa
thicknessaaaaaaaaaa
thicknessaaaaaaaaaa
Login to View More

Abstract

In a nonaqueous electrolyte cell-oriented electrode (10), an electrode active material layer (12) formed on a collector (1) has a density gradient developed with a gradient of a varied concentration of a solid along a thickness from a surface of the electrode active material layer (12) toward the collector (1), and in a gel electrolyte cell-oriented electrode (30), an electrode active material layer (32) formed on a collector (1) has a density gradient developed with (a) gradient(s) of (a) varied concentration(s) of one or both of an electrolyte salt and a film forming material along a thickness from a surface of the electrode active material layer (32) toward the collector (1).

Description

[0001]The present application is a divisional of U.S. application Ser. No. 10 / 565,171, filed Jan. 19, 2006, which is the national stage entry of PCT / JP2004 / 011021, filed Jul. 27, 2004, which in turn claims benefit of priority to Japanese application Nos. 2003-283974 and 2003-283975, both filed Jul. 31, 2003, the entire contents of which are incorporated herein by reference.TECHNICAL FIELD[0002]The present invention relates to a secondary cell electrode, and particularly, to a nonaqueous electrolyte electrode and a gel electrolyte electrode, and further to a fabrication method of the same, as well as to a secondary cell employing the secondary cell electrode, a complex cell employing the secondary cell, and a vehicle employing the secondary cell or the complex cell.BACKGROUND ART[0003]Recent years have observed, on the background with a rising trend for environmental protection, demands for a promoted introduction of an electric vehicle (EV), a hybrid vehicle (HEV), and a fuel cell p...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(United States)
IPC IPC(8): C25B11/00C25D21/14H01M4/02H01M4/04H01M4/08H01M4/36H01M6/18H01M8/02H01M8/10H01M10/0525H01M10/36H01M50/543
CPCH01M2/021H01M4/02H01M4/0404Y02E60/122H01M10/0525H01M2300/0022H01M2300/0085H01M4/366Y02E60/10H01M50/543H01M4/08H01M4/04
Inventor NAGAYAMA, MORISAITO, TAKAMISTUSHIMAMURA, OSAMU
Owner NISSAN MOTOR CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products