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Inverse Fluidization for Purifying Fluid Streams

a technology of fluid stream and inverse fluidization, which is applied in the direction of multi-stage water/sewage treatment, other chemical processes, separation processes, etc., can solve the problems of reducing efficiency from an energy standpoint, capacity and energy consumption, and adding to overall wastewater treatment costs, etc., to achieve low and constant pressure drop, high removal efficiency, and good mixing

Inactive Publication Date: 2010-05-13
NEW JERSEY INSTITUTE OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0016]The inverse fluidization described herein shows high removal efficiency, low and constant pressure drop (when operating above the minimum fluidization velocity), good mixing between solid particles and the liquid phase, high capacity, and an adjustable voidage in the fluidized bed obtained by changing the velocity of the fluid thus changing the void fraction due to bed expansion.
[0018]The use of materials having high hydrophobicity, high porosity, and large surface area, such as hydrophobic silica aerogels, is particularly well suited for the removal of immiscible organic compounds, e.g., oils, from water. Combining the properties of these materials with the advantageous properties of inverse fluidization can result in large capacity and high removal efficiency, e.g., as high as 99.9%, depending on the operating conditions. Oil-contaminated streams can be purified to levels of 1 part per million (PPM) or lower.

Problems solved by technology

Many water treatment methods, such as, for instance, reverse osmosis or ultrafiltration, require pre-treatment of the contaminated water, adding to overall wastewater treatment costs.
While filtration generally provides good oil removal, capacity and energy consumption have to be considered when designing filtration systems.
As a result, either the amount of water passing through the filter has to be reduced or the pumping power has to be increased leading to a reduction in efficiency from an energy standpoint.
However, purification methods based on adsorption by activated carbon as well as other purification techniques such as reverse osmosis and ultrafiltration strongly depend on temperature and their removal capacities and / or efficiencies may be affected under operating temperatures higher than ambient.

Method used

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  • Inverse Fluidization for Purifying Fluid Streams
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  • Inverse Fluidization for Purifying Fluid Streams

Examples

Experimental program
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Effect test

example 1

[0087]Different amounts of granules of Nanogel® were inversely fluidized in order to study inverse fluidization characteristics of this material. FIG. 6A is a photograph of inverse fluidized bed of 500-850 microns Nanogel® particles (sieved). FIG. 6B is a photograph of inverse fluidized bed of 2.3 mm Nanogel® particles (un-sieved).

[0088]The inversely fluidized bed pressure drop and bed expansion data were collected as a function of fluid velocity; these data are shown in FIGS. 7A through 7C and 8A through 8C, respectively. The data show typical behavior of liquid-solid fluidized beds characterized by a proportional increase in the bed pressure drop at fluid velocities below minimum fluidization velocity, a pressure drop plateau during full fluidization, a minimum fluidization velocity dependant on particle size, a pressure drop dependant on the amount of particles and a bed expansion that starts at the minimum fluidization velocity.

[0089]FIGS. 7A, 7B and 7C indicate that the pressur...

example 2

[0092]Removal of oil from water was studied by injecting oil with a metering pump using an arrangement such as shown in FIG. 4. The oil was mixed with the water by using an in-line static mixer. Water samples, before and after the inverse fluidized bed, were taken for chemical oxygen demand (COD) analysis. COD concentration was found by using the HACH colorimetric method. In these experiments, since oil was added to tap water, the chemical oxygen demand (COD) was roughly proportional to the oil concentration in the water as shown in FIG. 5. Therefore COD levels were used as a reference of oil concentration.

[0093]In one case, 56 grams of Nanogel® granules with sizes from 500 to 850 microns were used to adsorb oil from water. The flow velocity was about 1.07 cm / s. The concentration of oil upstream the fluidized bed was about 450 mg of oil / l of water.

[0094]As shown in FIG. 9, the inverse fluidized bed of Nanogel® is very effective in removing oil from water. There was at least a one or...

example 3

[0098]In another case, 108 grams of Nanogel® granules with sizes from 500 to 850 microns were used to adsorb oil from water. The flow velocity was about 1.02 cm / s. The concentration of oil upstream the fluidized bed was about 470 mg of oil per kg (liter) of water.

[0099]As shown in FIG. 10, the inverse fluidized bed of Nanogel® was very effective on removing oil from water with a reduction in COD concentration from 1400 mg / l down to 40 mg / l, which implies a 97% removal.

[0100]The bed height was also monitored during the removal of oil from water by the inverse fluidized bed as also shown in FIG. 10. It can be clearly seen that the bed reduces as a consequence of the saturation of some of the Nanogel® granules with oil. In this case, because of the initial taller height of the fluidized bed (more particles were used thus increasing the initial bed height), there was an oil concentration gradient, with more oil at the top. This gradient makes particles at the top saturate faster than pa...

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Abstract

A method for removing a contaminant from a fluid system comprises contacting the fluid system with an inversely fluidized material, for example a particulate aerogel, thereby removing at least a portion of the contaminant from the fluid system. The method can be used to remove oil or other organic materials from wastewater streams. It can be conducted in a fluidized bed, which includes nanoporous particles and a fluidizing medium, wherein the nanoporous particles have a density lower than that of the fluidizing medium.

Description

RELATED APPLICATIONS[0001]This application is a Continuation of International Application Number PCT / US2007 / 084070, filed on Nov. 8, 2007, designating the United States, which claims the benefit under 35 USC 119(e) of U.S. Provisional Application No. 60 / 865,259, filed on Nov. 10, 2006. Both applications are incorporated herein by reference in their entirety.BACKGROUND OF THE INVENTION[0002]Existing methods for oil removal are based on techniques such as filtration, gravity separation, biological treatment methods, and induced floatation. Other approaches include API (American Petroleum Institute) separators, developed for handling refinery wastewaters, dissolved air flotation oil-water separators, induced air flotation oil-water separators, carbon adsorption and ultrafiltration treatments.[0003]One existing technique employs a coalescing medium, such as, for instance, that supplied by Lantec Products (www.lantecp.com) under the name of HD Q-PAC. In a specific application for removin...

Claims

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Application Information

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IPC IPC(8): C02F1/28B01D15/02B01D17/022B01J20/06C02F101/32
CPCB01D15/02B01J20/28047B01J20/2808C02F9/00C02F2101/30C02F2101/32C02F1/24C02F1/281
Inventor PFEFFER, ROBERTQUEVEDO, JOSE
Owner NEW JERSEY INSTITUTE OF TECHNOLOGY