Method for supplying oxygen to hydrocarbon oil

A technology of hydrocarbon oil and oxygen supplementation, which is applied in the direction of refining with oxygen-containing compounds, etc., can solve the problems of low mercaptan efficiency and inability to convert mercaptans well, and achieve convenient operation, increased effective oxygen content, and simple process Effect

Inactive Publication Date: 2007-12-05
BEIJING SJ ENVIRONMENTAL PROTECTION & NEW MATERIAL CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When converting mercaptans, the fixed-bed deodorization process is still used, which can only be used to convert mercaptans in catalytic gasoline, and cannot convert mercaptans well for hydrogenated gasoline.
[0010] Chinese patent application 00109631.1 discloses a method for converting mercaptans contained in light oil products, which also uses a fixed-bed catalytic oxidation method to make light oil products mixed with air or oxygen pass through a fixed-bed reactor Catalyst bed, under the action of the catalyst, oxygen reacts with the mercaptan contained in the light oil to generate disulfides. The active components of the catalyst are nanoscale transition metal element oxides, perovskite type rare earth composites Oxides or spinel oxides; although this method injects 1.5 to 2 times the theoretical amount of air or oxygen into the light oil, it can prevent the problem of excess air or oxygen taking away part of the oil and gas, but if The shorter the contact time of the light oil with the catalyst bed, the less efficient the conversion of mercaptans

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  • Method for supplying oxygen to hydrocarbon oil
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Examples

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manufacture example 1 to manufacture example 3

[0032] Cylindrical catalyst A1 whose active component is manganese dioxide, the catalyst A1 is entirely composed of manganese dioxide. The manufacturing method is as follows: Each manufacturing example takes a certain weight of powdered manganese dioxide respectively, and uses a tablet machine or a tablet press to press the powdered manganese dioxide under corresponding pressure into a cylindrical shape with a certain lateral pressure strength. The finished catalyst A11 of Production Example 1, the finished catalyst A12 of Production Example 2, and the finished catalyst A13 of Production Example 3 were obtained respectively. The diameters of these finished catalysts are all 6.5 mm, and the heights are all 6.2 mm to 6.5 mm. See Table 1 for the relevant parameters of the specifications and properties of the catalysts of each manufacturing example. In Manufacturing Example 1 to Manufacturing Example 3, the manufacturers of the powdery manganese dioxide used in different manufact...

manufacture example 4 to manufacture example 6

[0034]Cylindrical catalyst A2 whose active component is manganese carbonate, the catalyst A2 is entirely composed of manganese carbonate. The manufacturing method is as follows: Each manufacturing example weighs a certain weight of powdered manganese carbonate respectively, and presses the powdered manganese carbonate under corresponding pressure into a cylindrical solid with a certain lateral pressure strength by using a tablet machine or a tablet press. The finished catalyst product A21 of Production Example 4, the finished catalyst product A22 of Production Example 5, and the finished catalyst product A23 of Production Example 6 were respectively obtained from the molded products. The diameters of these finished catalysts are all 6.5 mm, and the heights are all 6.2 mm to 6.5 mm. See Table 1 for the relevant parameters of the specifications and properties of the catalysts of each manufacturing example. In manufacturing example 4 to manufacturing example 6, the manufacturers...

manufacture example 7 to manufacture example 9

[0036] Cylindrical catalyst A3 whose active component is trimanganese tetraoxide, the catalyst A3 is entirely composed of trimanganese tetraoxide. The manufacturing method is as follows: Each manufacturing example weighs a certain weight of powdered trimanganese tetroxide, respectively, and presses the powdered trimanganese tetraoxide under corresponding pressure with a tablet machine or a tablet press to form a tablet with a certain lateral pressure strength. The finished catalyst A31 of Production Example 7, the finished catalyst A32 of Production Example 8, and the finished catalyst A33 of Production Example 9 were respectively obtained as cylindrical solid moldings. The diameters of these finished catalysts are all 6.5 mm, and the heights are all 6.2 mm to 6.5 mm. See Table 1 for the relevant parameters of the specifications and properties of the catalysts of each manufacturing example. In Manufacturing Example 7 to Manufacturing Example 9, the manufacturers of the powder...

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Abstract

The present invention relates to a method for supplementing oxygen into hydrocarbon oil. Said method is characterized by that in the hydrocarbon oil a liquid oxygen-supplementing agent using tert-butyl hydroperoxide as effective component can be added, and in the flowing process the tert-butyl hydroperoxide in the oxygen-supplementing agent can be dissolved in the hydrocarbon oil, and when the hydrocarbon oil in which the tert-butyl hydroperoxide is dissolved in passed through the catalyst bed layer which is placed in the fixed bed reactor and has catalytic property of decomposing tert-butyl hydroperoxide, under the action of catalyst the tert-butyl hydroperoxide in the hydrocarbon oil can be decomposed, and can release out nascent active oxygen. The active component or said catalyst is compound of manganese.

Description

technical field [0001] The invention belongs to the field of refined processing of petroleum products, and in particular relates to a method for supplementing oxygen into hydrocarbon oil. Background technique [0002] The hydrocarbon oil referred to in the present invention includes refined petroleum products including liquefied petroleum gas, naphtha, gasoline, aviation kerosene, lamp kerosene and diesel oil. Naphtha, gasoline, aviation kerosene, lamp kerosene and diesel oil can be collectively referred to as light oil products. In petroleum refining, crude oil can be divided into light distillate oil, heavy distillate oil and vacuum oil residue through atmospheric and vacuum distillation. Light distillate oil includes gasoline, kerosene, diesel oil, etc., and heavy distillate oil includes various A lubricating oil fraction, cracking feedstock (i.e. vacuum distillate or wax oil). In order to obtain more light oil products, heavy distillate oil and residual oil are further...

Claims

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Application Information

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IPC IPC(8): C10G27/12
Inventor 刘振义李瑞秋苏立鹏汪祥胜
Owner BEIJING SJ ENVIRONMENTAL PROTECTION & NEW MATERIAL CO LTD
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