Method for preparing lamella silicate modified ethylene-vinyl acetate copolymer
A technology of vinyl acetate copolymerization and layered silicate, which is applied in the field of manufacturing layered silicate modified ethylene-vinyl acetate copolymer, and achieves the effects of simple and reasonable process, low cost and improved thermal deformation
Inactive Publication Date: 2008-09-17
NINGBO NENGZHIGUANG NEW MATERIALS TECH
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[0026] The present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments.
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Abstract
A manufacturing method for a kind of copolymer of laminated silicate and modified ethylene-vinyl acetate characterizes that the organic clay and polyethylene-vinyl acetate are melted and extruded out on the screw extruder according to the mass ratio of 1~10:99~90, the polyethylene-vinyl acetate contains vinyl acetate 5~28% and its melt index is 1~120g / 10min, extrusion temperature is 160-180 deg.C, screw speed is 160~300rpm, mean detention time is 2 ~ 10min, the interaction between EVA and the laminated silicates is promoted through the grafting of the EVA, then the nano-EVA is inserted between the layers of molten state silicates and the silicate layers begin swelling until they are scattered as single nano-layer state in the EVA-base, then the laminated structure is realized.
Description
technical field [0001] The invention relates to a preparation method of layered silicate modified ethylene-vinyl acetate copolymer. Background technique [0002] Nano layered silicate modified plastic is a kind of nanocomposite material prepared by intercalation compounding of layered silicate and plastic. This new type of nano-modified material perfectly combines the rigidity, dimensional stability and thermal stability of inorganic substances with the toughness and processability of polymers, showing excellent hybrid performance. Compared with ordinary plastics, this nano-modified plastic has high elastic modulus and strength, high barrier and flame retardancy, good thermal stability, etc. Nanoplastics have become a hotspot in the field of new materials research and development in recent years because they can be applied practically and have the most industrialization prospects in nanomaterial technology. [0003] Layered silicates are clay minerals widely distributed in...
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Patent Type & Authority Patents(China)
IPC IPC(8): C08F210/02C08K3/34B29C47/38B29C48/395
CPCB29C2947/92704B29C2947/92561B29C2947/9259B29C2948/92561B29C2948/9259B29C2948/92704
Inventor 张发饶
Owner NINGBO NENGZHIGUANG NEW MATERIALS TECH
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