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Improvement of manner for introducing condensation agent into fluidised bed polymerisation reactor and device

A polymerization reactor and fluidized bed technology, which is applied in chemical instruments and methods, chemical/physical processes, etc., can solve the problems of fluid accumulation in the fluidized bed and increase in stream density, so as to improve production capacity, strengthen practical significance and Application value, the effect of avoiding liquid accumulation at the bottom of the fluidized bed

Inactive Publication Date: 2010-02-17
ZHEJIANG UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If the content of condensate in the circulating air stream is further increased, it may cause liquid accumulation at the bottom of the fluidized bed
At the same time, the stream enriched with condensate in this patent returns to the fluidized bed reactor only by the kinetic energy obtained from the compressor. If the amount of condensate in the stream increases, the density of the stream increases and returns to the fluidized bed. The kinetic energy required for the reactor also increases

Method used

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  • Improvement of manner for introducing condensation agent into fluidised bed polymerisation reactor and device
  • Improvement of manner for introducing condensation agent into fluidised bed polymerisation reactor and device
  • Improvement of manner for introducing condensation agent into fluidised bed polymerisation reactor and device

Examples

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Comparison scheme
Effect test

Embodiment 1

[0036] exist figure 1 The linear low density polyethylene (LLDPE) is produced in the fluidized bed polymerization reactor shown, under the action of the Z-N catalyst system, the polymerization reaction temperature is 85°C, the pressure is 2.1MPa, and the superficial velocity of the reactor is 0.68m / s. The circulating gas flow in pipeline 4 includes hydrogen, nitrogen, methane, ethane, ethylene, hexene and hexane, etc., with a pressure of 2.1 MPa and a temperature of 53°C. Contain 20% condensate in the recycle gas flow coming out from the condenser 17, the liquid phase is hexene and hexane, and the density is 618.7kg / m 3 , the gas phase density is 28.8kg / m 3 . After separation and enrichment, the content of the condensate in the pipeline 29 can reach 30% of the total content of the condensate in the circulating air stream, and this stream is sprayed into the fluidized bed from above the distribution plate by the jet pump 24 . In this process, the jet pump uses ethylene as th...

Embodiment 2

[0038] exist figure 1 The linear low density polyethylene (LLDPE) is produced in the fluidized bed polymerization reactor shown, under the action of the Z-N catalyst system, the polymerization reaction temperature is 80°C, the pressure is 2.1MPa, and the superficial velocity of the reactor is 0.72m / s. The circulating gas flow in pipeline 4 includes hydrogen, nitrogen, methane, ethane, ethylene, and isopentane, with a pressure of 2.1 MPa and a temperature of 53°C. Contain 30% condensate in the recirculating airflow from condenser 17, the liquid phase is isopentane, and the density is 656.3kg / m 3 , the gas phase density is 28.8kg / m 3 . After separation and enrichment, the content of the condensate in the pipeline 29 can reach 50% of the total content of the condensate in the circulating air stream, and the stream is sprayed into the fluidized bed from three places above the distribution plate by the jet pump 24 at different heights . In this process, the jet pump uses ethyle...

Embodiment 3

[0040] exist figure 1 The linear low density polyethylene (LLDPE) is produced in the fluidized bed polymerization reactor shown, under the action of the Z-N catalyst system, the polymerization reaction temperature is 85°C, the pressure is 2.5MPa, and the superficial velocity of the reactor is 0.78m / s. The circulating gas flow in pipeline 4 includes hydrogen, nitrogen, methane, ethane, ethylene, hexene and hexane, the pressure is 2.5MPa, and the temperature is 53°C. Contain 40% condensate in the recycle airflow coming out from the condenser 17, the liquid phase is hexene and hexane, and the density is 618.7kg / m 3 , the gas phase density is 28.8kg / m 3 . After gravity separation and enrichment, the content of the condensate in the pipeline 29 can reach 70% of the total content of the condensate in the circulating air flow. in the chemical bed. In this process, the jet pump uses ethylene as the power fluid with a flow rate of 35 tons / hour, a pressure of 3.2 MPa, and a temperat...

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Abstract

The invention discloses an improvement of introducing the way of a condensing agent into a fluidized bed polymerization reactor and a device thereof. The improvement comprises the following steps that: a circulating airstream is exported from the top of the fluidized bed and is compressed as well as condensed and separated to form a main portion and a small portion rich in condensed fluid, the main portion flows back to the bottom of the fluidized bed, a jet pump is adopted, a reaction feed gas is taken as a power airstream, the condensed fluid with a content occupying 30 to 100 weight percentof the total content of the condensed fluid in the circulating airstream and the reaction feed gas are jetted to the upper part of a gas distributing plate inside the fluidized bed, the power of thejet pump is adopted to draw off the condensed fluid effusion at the bottom of the fluidized bed back to the upper part of the gas distributing plate. The improvement can greatly increase the quantityof the condensed fluid which returns to the fluidized bed reactor from the upper part of the distributing plate and avoids the phenomenon of the effusion at the bottom of the fluidized bed; meanwhile,the reaction feed gas is taken as the power fluid body of the jet pump, the energy inside the system is used comprehensively, the production ability is greatly increased, therefore, the improvement has great operation significance and the application value.

Description

technical field [0001] The invention relates to a method and a device for introducing a condensing agent into a fluidized bed polymerization reactor, in particular to an improvement of a method for introducing a condensing agent into a fluidized bed olefin polymerization reactor and the device thereof. Background technique [0002] In modern life, polyolefin resins are inseparable from the basic necessities of human beings. From simple packaging bags to complex aircraft components, polyolefin resins are playing an irreplaceable role, especially polyethylene resins, due to their excellent physical and chemical properties , Simple forming and processing and relatively cheap price, etc., the output and product application consumption are among the best. There are three main methods for industrial production of polyethylene: slurry polymerization, solution polymerization and gas phase polymerization. Among them, the gas phase polyethylene process has the advantages of simple pr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F10/00C08F2/34C08F2/01B01J8/24
Inventor 阳永荣吴文清骆广海王靖岱王树芳韩国栋蒋斌波武锦涛秦伟
Owner ZHEJIANG UNIV
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