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Environment protecting type coal surface solidifying agent and preparation process thereof

An environmentally friendly, curing agent technology, applied in chemical instruments and methods, other chemical processes, loading/unloading, etc., can solve problems such as discharge, physical health hazards, deterioration of the environment of employees and passengers, achieve huge economic benefits, and avoid dust. The effect of pollution, environmental protection and social benefits

Inactive Publication Date: 2007-07-18
BEIJING JIAOTONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

And it also produces serious pollution to the body of other vehicles passing by.
Secondly, it has a great impact on the equipment
Coal dust has seriously polluted the track bed of railway lines, aggravating the degree of compaction. In heavily polluted sections, coal dust has buried fasteners, sleeper plates and other parts, which has brought considerable difficulties to the daily maintenance of the engineering department. Serious corrosion on rails and fasteners, causing safety hazards
Due to the pollution of coal dust, the daily maintenance of signal communication equipment is very difficult
It often causes short circuit and discharge of power supply insulators, which shortens the service life and brings great inconvenience to daily maintenance operations
Third, it poses a threat to driving safety
The thickness of coal particles increases at a rate of about 20cm per month at the entrance of the tunnel. The concentration of coal dust in the tunnel is suffocating and the visibility is less than 10m. The temperature of the working environment of electrical equipment in the locomotive rises, which often causes equipment failure, reduces its integrity rate and safety, and seriously threatens the safety of train operation
Fourth, it seriously deteriorates the environment for employees and passengers
A large amount of coal dust in the tunnel invaded the locomotive crew room, deteriorating the working environment of the crew, and the raised coal dust caused dust pollution to the roadside stations, crossings and other environments, especially for the public works, electricity and power supply workers who often work in the tunnel serious harm to the health of
For some ordinary vehicles that are not well sealed, coal dust flies into the vehicle, which poses a serious threat to the health of passengers
Fifth, there are potential serious security risks
However, in an environment with extremely dry natural conditions, due to rapid evaporation, frequent spraying, time-consuming and labor-consuming, and a large amount of water, not only the cost is high, but it is also difficult to continuously meet the requirements of environmental quality

Method used

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  • Environment protecting type coal surface solidifying agent and preparation process thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Raw material ratio:

[0034] Raw material ratio (wt%) Raw material ratio (wt%)

[0035] Polyvinyl alcohol 1 10wt% hydrogen peroxide solution 0.3

[0036] Starch 5 5wt% borax or boric acid solution 2

[0037] Ferrous sulfate 0.005 10wt% caustic soda solution 4

[0038] water 87.695

[0039] Operation process:

[0040]As shown in Figure 1, according to the proportion of raw materials, add 50% of the total water into the reactor, then add 1% polyvinyl alcohol, stir, heat up to 99°C to completely dissolve the polyvinyl alcohol, cool down to 60°C, add 5% corn starch, stirred and kept for 1 hour for graft modification; after modification, the material was cooled to 35°C, 0.005% ferrous sulfate was added to the reaction kettle, stirred evenly, and then 0.3% hydrogen peroxide solution was added to catalyze Oxidation reaction 1h. After the catalytic oxidation reaction, raise the temperature to 40°C to decompose the excess or unreacted hydrogen peroxide; then slowly add 4% ...

Embodiment 2

[0042] Raw material ratio:

[0043] Raw material ratio (wt%) Raw material ratio (wt%)

[0044] Polyvinyl alcohol 2 10wt% hydrogen peroxide solution 0.6

[0045] Starch 7 5wt% borax or boric acid solution 5

[0046] Ferrous sulfate 0.01 10wt% caustic soda solution 8

[0047] water 77.399

[0048] Operation process:

[0049] As shown in Figure 1, according to the proportion of raw materials, add 50% of the total water into the reaction kettle, then add 2% polyvinyl alcohol, stir, heat up to 99°C to completely dissolve the polyvinyl alcohol, cool down to 60°C, add 7% corn starch, stirred and kept for 1 hour for graft modification; after modification, the material was cooled to 35°C, 0.01% ferrous sulfate was added to the reaction kettle, stirred evenly, and then 0.6% hydrogen peroxide solution was added to catalyze Oxidation reaction 1h. After the catalytic oxidation reaction, raise the temperature to 60°C to decompose the excess or unreacted hydrogen peroxide; then slowly ...

Embodiment 3

[0051] Raw material ratio:

[0052] Raw material ratio (wt%) Raw material ratio (wt%)

[0053] Polyvinyl alcohol 1.5 10wt% hydrogen peroxide solution 0.5

[0054] Starch 6 5wt% borax or boric acid solution 4

[0055] Ferrous sulfate 0.0075 10wt% caustic soda solution 6

[0056] water 81.9925

[0057] Operation process:

[0058] As shown in Figure 1, according to the proportion of raw materials, add 50% of the total water into the reaction kettle, then add 1.5% polyvinyl alcohol, stir, raise the temperature to 99°C to completely dissolve the polyvinyl alcohol, cool down to 60°C, add 6% corn starch, stirred and kept for 1 hour for graft modification; after modification, the material was cooled to 35°C, 0.0075% ferrous sulfate was added to the reaction kettle, stirred evenly, and then 0.5% hydrogen peroxide solution was added to catalyze Oxidation reaction 1h. After the catalytic oxidation reaction, raise the temperature to 60°C to decompose the excess or unreacted hydrogen...

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Abstract

The present invention relates to one kind of environment friendly coal surface curing agent and its preparation process. The coal surface curing agent consists of PVA 1-2 wt%, 10 wt% concentration hydrogen peroxide solution 0.3-0.6 wt%, starch 5-7 wt%, 5 wt% concentration borax or boric acid solution 2-5 wt%, ferrous sulfate 0.005-0.01 wt%, 10 wt% concentration sodium hydroxide solution 4-8 wt% and water for the rest. It is sprayed to the surface of coal under transportation so as to form one curing layer avoiding dust pollution and coal loss. It has no influence on coal quality and is environment friendly.

Description

technical field [0001] The invention relates to an environment-friendly coal surface curing agent and a preparation method thereof. The curing agent is mainly used for railway coal transportation to prevent coal loss and environmental pollution during transportation. Background technique [0002] At this stage, China's coal is generally transported by open car in railway transportation. During the transportation process, due to the bumps caused by the roadbed, turnouts and rail facilities, coupled with the wind force, especially when the train enters the tunnel, due to the "piston wind" effect, it will form an instant strong disturbance air flow, and the fine coal powder on the surface will The particles are blown away from the vehicle body, fall onto the road surface, and then be rolled by subsequent vehicles to form secondary dust with smaller particle size and higher concentration. As a result, the coal dust on the surface of the coal seam in the vehicle is scattered, re...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K3/00B65G69/18
Inventor 朱红李伟申闫春王芳辉刘凤月
Owner BEIJING JIAOTONG UNIV
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