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Preparation method for (PVC) nontoxic calcium zinc heat stabilizer and uses thereof

A heat stabilizer and main stabilizer technology, which is applied in the field of non-toxic calcium zinc heat stabilizer preparation, can solve the problem that the stability of rare earth heat stabilizers cannot meet the needs well, the product performance is easy to introduce impurities, and the later stability is not ideal To achieve stable and reliable product quality, obvious technical and economic advantages, and low production costs

Inactive Publication Date: 2007-09-26
GUANGDONG GAOKEDA TECH IND +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, lead salt stabilizers are still the main products in China, but non-toxic heat stabilizers have attracted more and more attention, and will replace toxic heat stabilizers such as lead salts. Development is an obvious example, but in general, the stability of rare earth heat stabilizers cannot meet the needs well, and calcium-zinc composite heat stabilizers are considered to be the inevitable development trend of heat stabilizers
So far, the main disadvantage of calcium-zinc composite heat stabilizers is that the stability in the later stage is not ideal, and it needs to be compounded with various auxiliary stabilizers, generally composed of calcium-zinc soap and various additives
The traditional calcium soap and zinc soap production process and cycle are long, energy consumption is high, and impurities are easily introduced to affect product performance. These problems have not been well solved technically.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0011] Example 1: Preparation of Calcium Zinc Primary Stabilizer

[0012] According to calcium (calcium hydroxide) zinc (zinc oxide) ratio (molar ratio) 70:30, stearic acid (C 18 ) and calcium-zinc ratio (molar ratio) 1.0: 1.1, composite catalyst (sulfuric acid+acetic acid+adipic acid) consumption 0.2% (stearic acid quality) weighing, and material mixing, heating and melting, stirring, keep reaction temperature~ 160°C, reacted for about 2 hours, cooled and aged for about 1 hour, after crushing and sieving, the calcium-zinc integrated primary stabilizer A was obtained as a white powder, and the stearic acid conversion rate was 99.8%.

example 2

[0013] Example 2: Preparation of Calcium Zinc Primary Stabilizer

[0014] According to calcium (calcium oxide) zinc (zinc oxide) ratio (molar ratio) 60:40, lauric acid (C 12 ) and calcium-zinc ratio (molar ratio) 1.0: 1.0, composite catalyst (phosphoric acid+propionic acid+adipic acid) consumption 0.5% (lauric acid quality) weighs, and materials are mixed, heated and melted, stirred, keep reaction temperature~ 160°C, reacted for about 2 hours, cooled and aged for about 1 hour, crushed and sieved to obtain calcium-zinc integrated primary stabilizer B as a white powder with a conversion rate of 99.9% for lauric acid.

example 3

[0015] Example 3: Preparation of Calcium Zinc Primary Stabilizer

[0016] According to calcium (calcium hydroxide) zinc (zinc oxide) ratio (molar ratio) 60:40, stearic acid (C 18 ) and calcium-zinc ratio (molar ratio) 1.0: 1.0, composite catalyst (sulfuric acid+acetic acid+succinic acid) consumption 0.1% (stearic acid quality) weighing, and material mixing, heating and melting, stirring, keep reaction temperature~ 160°C, reacted for about 2 hours, cooled and aged for about 1 hour, crushed and sieved to obtain calcium-zinc integrated primary stabilizer C as a white powder with a stearic acid conversion rate of 99.9%.

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PUM

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Abstract

The invention discloses a manufacturing method of composite intoxic Ca-Zn heat stabilizer, which is characterized by the following: fusing high-level aliphatic acid and Ca-Zn oxide or hydroxide without solvent directly to synthesize integral stabilizer; complexing with sodium biphosphate, beta-diketone and bisphenol A; shortening manufacturing period from 15h to 6h; saving cost obviously.

Description

technical field [0001] The invention relates to a preparation method and application of a (PVC) non-toxic calcium-zinc heat stabilizer. Background technique [0002] Polyvinyl chloride (PVC) is the second largest plastic species next to polyethylene. Its most notable features are high strength, good insulation, and good transparency. It is widely used in construction, electrical appliances, packaging and other industries. The biggest disadvantage of PVC is that it will degrade under long-term heating conditions and release hydrogen chloride gas, which will affect the performance of the product. The solution is to add heat stabilizers during PVC processing to prevent or delay this degradation. [0003] PVC heat stabilizers have experienced the development process from lead salts to barium, cadmium, zinc soaps, fatty acid rare earths, and non-toxic calcium-zinc heat stabilizers. So far, domestic heat stabilizers have formed more than 40 conventional varieties. The production ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K5/09C08L27/06C08K3/32C08K5/13
Inventor 陈伟瑜易国斌康正林静川
Owner GUANGDONG GAOKEDA TECH IND
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