Composite dual-electrode plates preparation method of minisize directly connecting methanol fuel battery

A methanol fuel cell and bipolar plate technology, which is applied to fuel cell components, fuel cells, battery electrodes, etc., can solve the problems that the preparation of true three-dimensional microchannels cannot be realized, the processing of true three-dimensional microstructures is difficult, and the production cost is high. , to achieve the effect of light weight, low production cost and small volume

Inactive Publication Date: 2007-09-26
XI AN JIAOTONG UNIV
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Problems solved by technology

However, the method of manufacturing silicon-based bipolar plates based on MEMS technology has the biggest disadvantages of high manufacturing cost and low efficiency, and it is impossible to realize the preparation of true three-dimensional microchannels.
In addition, compared with the existing rectangular, trapezoidal or triangular channel cross-sectional shapes, the curved cross-section channel bipolar plate has better performance. The cu...

Method used

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  • Composite dual-electrode plates preparation method of minisize directly connecting methanol fuel battery
  • Composite dual-electrode plates preparation method of minisize directly connecting methanol fuel battery
  • Composite dual-electrode plates preparation method of minisize directly connecting methanol fuel battery

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Embodiment Construction

[0040] The preparation method of the composite bipolar plate of the miniature direct methanol fuel cell of the present invention uses the modified polymethyl methacrylate spin-coated on the glass substrate as the base material, and deposits high-conductivity copper on the base as the conductive layer. A layer of micro-electroplated nickel or Cr or Ni-50Cr alloy is used as an anti-corrosion protection material, and a composite bipolar plate of a miniature direct methanol fuel cell is prepared by a non-silicon composite manufacturing process. Its preparation method adopts a new non-silicon composite manufacturing process, which combines the advantages of micro-imprinting and micro-electroplating deposition processes, and improves the resistance of the composite bipolar plate by performing nitriding surface modification on the copper-nickel coating. Corrosive, reduces contact resistance.

[0041] See Figure 1 for the technical route of non-silicon composite fabrication of polymer...

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Abstract

The invention discloses a clad plate preparation method of micro methanol battery, the modified polymethyl methacryate is the basis materials, the high conductivity copper is conductive layer, and the nickel is as the anti-corrosion protective material. Adopting non-siliceous composite preparation technology, firstly producing the master mask and silicon rubber soft mould; then adopting the craft of 'inverse autogram' to stamp the micro channel of flow field on the modified polymethyl methacryate whose substrate is glass; then depositing the copper on surface of micro channel with craft of plating, a layer of nickel is plated on the substrate of the copper, then the composite deposite is nitration surface modified treatment; at last, after eliminating the glass substrate, producing the imports and exports of the reactants and resultant by laser micromachining. The polymer/copper nickel base clad plate possesses advantages that the weight is light, the volume is small, performance is well, cost is low, and it fits for batch size production.

Description

technical field [0001] The invention belongs to the technical field of micro fuel cells, and relates to a method for preparing a composite bipolar plate of a micro direct methanol fuel cell (μDMFC). The μDMFC polymer / copper-nickel based composite bipolar plate prepared by the method has the advantages of light weight, small volume, The performance is good, the production cost is low, and it can be suitable for mass production. Background technique [0002] With the continuous emergence of wireless communication equipment and various portable electronic products (such as mobile phones, notebook computers, digital machines, PDA, MP4, etc.) and the continuous improvement of performance, the demand for high-energy, micro-batteries is increasing. The traditional nickel-cadmium, nickel-metal hydride and lithium-ion batteries have been difficult to meet the requirements of these product development. In addition, micro-batteries have been integrated into the...

Claims

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Application Information

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IPC IPC(8): H01M8/02H01M4/88H01M8/0202H01M8/1011
CPCY02E60/50Y02P70/50
Inventor 兰红波丁玉成刘红忠卢秉恒
Owner XI AN JIAOTONG UNIV
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