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Self wetting micro high efficiency thermal self circulation cooling proton exchange fuel cell system

A fuel cell system and proton exchange membrane technology, which is applied in the field of self-humidifying micro-high-efficiency thermal self-circulating cooling proton exchange membrane fuel cell system, can solve the problems of less heat in air cooling, decreased electrical performance of the stack, complex volume and the like, Achieve the effect of improving use efficiency, simple and compact structure, and good flexibility

Inactive Publication Date: 2007-10-10
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 1. For a proton exchange membrane fuel cell that uses air at atmospheric pressure as an oxygen source, if air extraction or blowing is used as its power, when the air passes through the through-type flow channel of the bipolar plate of the stack, the water will flow from the cathode to the anode. The reverse osmosis phenomenon is weakened. If the hydrogen gas in the anode is not humidified, the membrane on the anode side will be dehydrated, thereby further reducing the electrical performance of the originally low-power stack.
[0005] 2. The proton exchange membrane fuel cell system that uses an external humidification system and a compressor to provide a high-pressure oxygen source is bulky, heavy, and not compact in structure, and is not suitable for use as a mobile power source, especially as a mobile vehicle Power supply
If the heat energy generated during operation cannot be released in time, the temperature of the battery stack will be too high, which will lead to dehydration of the membrane, the proton conductivity of the membrane will decrease, and the performance of the battery will deteriorate.
[0007] 4. The traditional water cooling system contains a circulation pump. Since it is only liquid-phase heat transfer, the temperature difference between the inlet and outlet is not large. When there is more heat, more water is needed, which makes the whole system too complicated and bulky; It dissipates less heat and cannot solve the problem of dehydration of the anode side membrane well, so it is not suitable for power sources with high heat generation
[0008] 5. The working temperature of the air-cooled stack is low (about 40°C), the catalytic activity of the electrode electrocatalyst is low, and the output power of the stack is also very low

Method used

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  • Self wetting micro high efficiency thermal self circulation cooling proton exchange fuel cell system
  • Self wetting micro high efficiency thermal self circulation cooling proton exchange fuel cell system
  • Self wetting micro high efficiency thermal self circulation cooling proton exchange fuel cell system

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Experimental program
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Embodiment 1

[0030] As shown in Figure 1, the self-humidification miniature high-efficiency thermodynamic self-circulation cooling proton exchange membrane fuel cell system is composed of a stack module I and a microchannel circulating cooler II, and the stack module I is connected with the microchannel The recirculating cooler II is an integrated arrangement: as shown in Figure 2, the stack module I is formed by interconnecting an end plate 7, a current collecting metal plate 9, and single battery units, and the end plate 7 has a fuel inlet , outlets 5 and 6; two end plates 7 are respectively located at the two ends of the stack module 1, and the inner sides of the two end plates 7 are fitted with two current-collecting metal plates 9 through rubber pads 8 respectively, and the two current-collecting Two groups of single battery units are attached between the metal plates 9, and the single battery units are composed of graphite bipolar plates 10 and self-humidifying membrane electrodes 11;...

Embodiment 2

[0035] The structure of this self-humidifying miniature high-efficiency thermodynamic self-circulation cooling proton exchange membrane fuel cell system is basically the same as that of Embodiment 1, but there are two electric stack modules 1, and the two electric stack modules 1 are arranged in parallel, and the electric stack module 1 Seal them with a polyester plastic plate with a higher hardness or general-purpose hot-melt adhesive 18, and each graphite bipolar plate 10 has a large number of air flow channels 17, and the distance between each two air flow channels is 10 mm to 10 mm. These air channels 17 can not only provide oxidant oxygen, but also take away part of the waste heat; the inner cavity of the graphite bipolar plate 10 has a microchannel 12, and most of the heat generated during battery operation is cooled by the microchannel 12. The working medium 20 is brought out in circulation, and the pipeline of the microchannel 12 adopts serpentine soft plastic capillari...

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Abstract

The fuel cell system is composed of integrative galvanic pile module and recirculation cooler of micro channel (RCMC). The galvanic pile includes terminal plates, afflux metal plate, and single cell units (SCU) connected to each other. Fuel inlet and outlet are made on terminal plates. Two terminal plates are positioned on two ends of the galvanic pile module. Through rubber pads, inner sides of two terminal plates are jointed to two pieces of afflux metal plate. One or more SCU are jointed between two pieces of afflux metal plate. SCU consists of jointed bipolar plate of graphite and electrode of self-humidified membrane. RCMC includes condenser tube, micro channel built in bipolar plate of graphite, and tiny check valve at entrance. Through tiny check valves at entrance and exit, two ends of condenser tube are connected to micro channel. Features are: preventing membrane from dehydration, discharging quantity of heat effectively so as to keep electrical property in good state.

Description

technical field [0001] The invention relates to fuel cell technology, in particular to a self-humidification miniature high-efficiency thermodynamic self-circulation cooling proton exchange membrane fuel cell system. Background technique [0002] Proton exchange membrane fuel cell is the fifth generation fuel cell which is developing rapidly after alkaline fuel cell, phosphoric acid fuel cell, molten carbonate fuel cell and solid oxide fuel cell. It has the advantages of cleanliness, low noise, low operating temperature, high current density, high energy conversion efficiency, and environmental friendliness. It is the most promising power source for pollution-free and zero-emission electric vehicles. In addition to the fuel cell stack, this fuel cell system also needs auxiliary systems such as fuel and oxidant supply systems, electronic intelligent control, and heat dissipation devices. The fuel hydrogen supply generally has a hydrogen humidificat...

Claims

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Application Information

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IPC IPC(8): H01M8/24H01M8/10H01M8/02H01M8/04119H01M8/2483
CPCY02E60/521Y02E60/50
Inventor 周震涛樊孝红于非
Owner SOUTH CHINA UNIV OF TECH